Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Step-wise Anion-Exchange in Layered Double Hydroxide Using Solvothermal Treatment

  • Lee, Jong-Hyeon (Department of Chemistry-BK21, Institute of Basic Science, Sungkyunkwan University) ;
  • Rhee, Seog-Woo (Department of Chemistry-BK21, Institute of Basic Science, Sungkyunkwan University) ;
  • Jung, Duk-Young (Department of Chemistry-BK21, Institute of Basic Science, Sungkyunkwan University)
  • Published : 2005.02.20
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Abstract

Synthetic layered double hydroxides (LDHs), [$Mg_4Al_2(OH)_{12}]CO_3{\cdot}nH_2O$, were prepared in the submicron size of plate-like polycrystals. Anion-exchange reactions with various linear dicarboxylic acids were performed to produce LDH/organic hybrid materials by solvothermal treatment in toluene. X-ray powder diffraction spectra for the products indicated that the interlayer spacings of LDHs remarkably changed, up to 20 $\AA$ when 1,10-decanedicarboxylic acid anions were intercalated as an organic guest. Dicarboxylates-LDHs samples could be also re-exchanged consecutively with other dicarboxylic acids or carbonate without serious destruction of layer structure under the scanning electron microscopic observation.

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