Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Nonequilibrium Distribution Function Theory of Many-Particle Effects in the Reversible Reactions of the Type A+B ↔ C+B

  • Lee, Jin-Uk (Department of Chemistry, Seoul National University) ;
  • Uhm, Je-Sik (Department of Chemistry, Seoul National University) ;
  • Lee, Woo-Jin (Department of Chemistry, Seoul National University) ;
  • Lee, Sang-Youb (Department of Chemistry, Seoul National University) ;
  • Sung, Jae-Young (Department of Chemistry, Chung-Ang University)
  • Published : 2005.12.20
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Abstract

We study the relaxation kinetics of reversible reactions of the type A + B $^\leftarrow_\rightarrow$ C + B by applying the manyparticle kernel theory, which we have developed to investigate many particle effects on general diffusioninfluenced reactions. It is shown that for the target model, where A and C molecules are immobile and their interconversion is induced by the encounter with the B molecules that are present in much excess, the manyparticle kernel theory gives a result that coincides with the known exact result.

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References

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