Bulletin of the Korean Chemical Society

  • 제26권3호
  • /
  • Pages.440-446
  • /
  • 2005
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Determination of Dibutyltin in Sediments Using Isotope Dilution Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry

  • Yim, Yong-Hyeon (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • Park, Ji-Youn (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • Han, Myung-Sub (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • Park, Mi-Kyung (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • Kim, Byung-Joo (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • Lim, Young-Ran (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • Hwang, Eui-Jin (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science) ;
  • So, Hun-Young (Division of Chemical Metrology and Materials Evaluation, Korea Research Institute of Standards and Science)
  • 발행 : 2005.03.20
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

A method is described for the determination of dibutyltin (DBT) in sediment by isotope dilution using liquid chromatography inductively-coupled plasma/mass spectrometry (LC-ICP/MS). To achieve the highest accuracy and precision, special attentions are paid in optimization and evaluation of overall processes of the analysis including extraction of analytes, characterization of the standards used for calibration and LC-ICP/MS conditions. An approach for characterization of natural abundance DBT standard has been developed by combining inductively-coupled plasma/optical emission spectrometry (ICP/OES) and LC-ICP/MS for the total Sn assay and the analysis of Sn species present as impurities, respectively. An excellent LC condition for separation of organotin species was found, which is suitable for simultaneous DBT and tributyltin (TBT) analysis as well as impurity analysis of DBT standards. Microwave extraction condition was also optimized for high efficiency while preventing species transformation. The present method determines the amount contents of DBT in sediments with expanded uncertainty of less than 5% and its result shows high degree of equivalence with reference values of an international inter-comparison and a certified reference material (CRM) within stated uncertainties.

키워드

참고문헌

  1. Lobinski, R.; Szpunar, J. Anal. Chim. Acta 1999, 400, 321 https://doi.org/10.1016/S0003-2670(99)00628-5
  2. Hill, S. J.; Pitts, L. J.; Fisher, A. S. Trends Anal. Chem. 2000, 19, 97 https://doi.org/10.1016/S0165-9936(99)00199-5
  3. Ruiz-Encinar, J.; Garcia-Alonso, J. I.; Sanz-Medel, A. J. Anal. At. Spectrom. 2000, 15, 1233
  4. Kannamkumarath, S. S.; Wrobel, K.; Wrobel, K.; Hymer, C. B.; Caruso, J. A. J. Chromatogr. A 2002, 975, 245 https://doi.org/10.1016/S0021-9673(02)01218-9
  5. Looser, P. W.; Berg, M.; Fent, K.; Muhlemann, J.; Schwarzenbach, R. P. Anal. Chem. 2000, 72, 5136 https://doi.org/10.1021/ac0005520
  6. McSheehy, S.; Szpunar, J.; Haldys, V.; Tortajada, J. J. Anal. At. Spectrom. 2002, 17, 507 https://doi.org/10.1039/b201015c
  7. Pellegrino, C.; Massanisso, P.; Marobito, R. Trends Anal. Chem. 2000, 19, 97 https://doi.org/10.1016/S0165-9936(99)00199-5
  8. Ruiz Encinar, J.; Rodriguez Gonzalez, P.; Garcia Alonso, J. I.; Sanz-Medel, A. Anal. Chem. 2002, 74, 270 https://doi.org/10.1021/ac010551n
  9. Yang, L.; Mester, Z.; Sturgeon, R. E. Anal. Chem. 2002, 74, 2968 https://doi.org/10.1021/ac011280j
  10. Ruiz-Encinar, J.; Rodriguez-Gonzalez, P.; Garcia-Alonso, J. I.; Sanz-Medel, A. Trends Anal. Chem. 2003, 22, 108 https://doi.org/10.1016/S0165-9936(03)00204-8
  11. Rodriguez-Gonzalez, P.; Ruiz-Encinar, J.; Garcia Alonso, J. I.;Sanz-Medel, A. Analyst 2003, 128, 447 https://doi.org/10.1039/b212785g
  12. Yang, L.; Mester, Z.; Sturgeon, R. E. J. Anal. At. Spectrom. 2003, 18, 1365 https://doi.org/10.1039/b304705a
  13. Monperrus, M.; Zuloaga, O.; Krupp, E.; Amouroux, D.; Wahlen, R.; Fairman B.; Donard, O. F. X. J. Anal. At. Spectrom. 2003, 18, 247 https://doi.org/10.1039/b203242m
  14. Wahlen, R.; Catterick, T. Rapid Comm. Mass Spectrom. 2004, 18, 211 https://doi.org/10.1002/rcm.1315
  15. Chiron, S.; Roy, S.; Cottier, R.; Jeannot, R. J. Chromatogr. A 2000, 879, 137 https://doi.org/10.1016/S0021-9673(00)00383-6
  16. White, S.; Catterick, T.; Fairman, B.; Webb, K. J. Chromatogr. A 1998, 794, 211 https://doi.org/10.1016/S0021-9673(97)00805-4
  17. CCQM-P43: Tributyltin and dibutyltin in sediment. Draft B report
  18. Ruiz Encinar, J.; Rodriguez Gonzalez, P.; Rodriguez Fernandez, J.; Garcia Alonso, J. I.; Diez, S.; Bayona, J. M.; Sanz-Medel, A. Anal. Chem. 2002, 74, 5237 https://doi.org/10.1021/ac025717e
  19. Fairman, B.; Wahlen, R. Spectroscopy Europe 2001, 13, 16
  20. Salit, M. L.; Turk, G. C. Anal. Chem. 1998, 70, 3184 https://doi.org/10.1021/ac980095b
  21. Salit, M. L.; Vocke, R. D.; Kelly, W. R. Anal. Chem. 2000, 72, 3504 https://doi.org/10.1021/ac0000877
  22. Yang, I. C.; Han, M. S.; Yim, Y.-H.; Hwang, E.; Park, S. R. Anal. Biochem. 2004, 335, 150 https://doi.org/10.1016/j.ab.2004.08.038
  23. Won, Y.; Chung, M.; Kim, B.; Yim, Y.-H.; So, H.-Y.; Kim, Y. S. Bull. Korean Chem. Soc. 2004, 25, 1508 https://doi.org/10.5012/bkcs.2004.25.10.1508

피인용 문헌

  1. Development of an Arsenobetaine Standard Solution with Metrological Traceability to the SI by an Arsenic-specific Mass Balance Method vol.38, pp.2, 2017, https://doi.org/10.1002/bkcs.11072
  2. Pressurized liquid extraction in environmental analysis vol.386, pp.4, 2006, https://doi.org/10.1007/s00216-006-0648-2
  3. An HPLC Method for Determination of a New Diorganotin(IV)Benzohydroxamate in Rat Plasma and Its Application to Pharmacokinetic Studies vol.26, pp.9, 2008, https://doi.org/10.1002/cjoc.200890294
  4. Current literature in mass spectrometry vol.41, pp.2, 2005, https://doi.org/10.1002/jms.949
  5. Atomic spectrometry update. Environmental analysis vol.21, pp.2, 2006, https://doi.org/10.1039/b516025c