Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

La(III) Selective Membrane Sensor Based on a New N-N Schiff's Base

  • Published : 2005.01.20
Download PDF
⟨ Previous Next ⟩

Abstract

Bis(2-methylbenzaldehyde)butane-2,3-dihydrazone(TDSB) was used as new N-N Schiff's base which plays the role of an excellent ion carrier in the construction of a La(III) membrane sensor. The best performance was obtained with a membrane containing, 30% poly(vinyl chloride), 60% benzyl acetate, 6% TDSB and 4% sodium tetraphenyl borate. This sensor reveals a very good selectivity towards La(III) ions over a wide variety of cations, including alkali, alkaline earth, transition and heavy metal ions. The proposed electrode exhibits a Nernstian behavior (with slope of 19.8 mV per decade) over a wide concentration range (1.0 ${\times}$ 10$^{-5}$-1.0 ${\times}$ 10$^{-1}$ M). The detection limit of the sensor is 7.0 ${\times}$ 10$^{-6}$ M. It has a very short response time, in the whole concentration range ($\sim$5 s), and can be used for at least twelve weeks in the pH range of 3.0-9.4. The proposed sensor was successfully applied as an indicator electrode for the potentiometric titration of a La(III) solution, with EDTA. It was also successfully applied in the determination of fluoride ions in three mouth wash preparations.

Keywords

References

  1. Buhlman, P.; Pretsch, E.; Bakker, E. Chem. Rev. 1998, 98, 1539
  2. Harrel, J. B.; Jones, A. D.; Choppin, G. R. Anal. Chem. 1969, 41, 1459 https://doi.org/10.1021/ac60280a026
  3. Szczepaniak, W.; Ren, M. Talanta 1994, 41, 1393 https://doi.org/10.1016/0039-9140(93)E0002-U
  4. Pan, E.; Xuemei, Z.; Huang, Z. Yingyong. Huaxie 1994, 11, 20
  5. Amarchand, S.; Menon, S. K.; Agarwal, Y. K. Electroanalysis 2000, 12, 522 https://doi.org/10.1002/(SICI)1521-4109(200005)12:7<522::AID-ELAN522>3.0.CO;2-D
  6. Shamsipur, M.; Yousefi, M.; Ganjali, M. R. Anal. Chem. 2000, 72, 2391 https://doi.org/10.1021/ac991155w
  7. Ganjali, M. R.; Qomi, M.; Daftari, A.; Norouzi, P.; Salavati-Niasari, M.; Rabbani, M. Sens. Actuators B 2004, 98, 92 https://doi.org/10.1016/j.snb.2003.09.028
  8. Ganjali, M. R.; Kiani-Anbouhi, R.; Shamsipur, M.; Poursaberi, T.; Salavati-Niasari, M.; Talebpour, Z.; Emami, M. Electroanalysis 2004, 15, 1038
  9. Ganjali, M. R.; Pourjavid, M. R.; Rezapour, M.; Haghgoo, S. Sens. Actuators B 2003, 89, 21 https://doi.org/10.1016/S0925-4005(02)00422-7
  10. Ganjali, M. R.; Tahami, M.; Shamsipur, M.; Poursaberi, T.; Haghgoo, S.; Hosseini, M. Electroanalysis 2003, 15, 1038 https://doi.org/10.1002/elan.200390125
  11. Ganjali, M. R.; Naji, L.; Poursaberi, T.; Shamsipur, M.; Haghgoo, S. Anal. Chim. Acta 2003, 475, 59 https://doi.org/10.1016/S0003-2670(02)01226-6
  12. Bush, D. H.; Bailar, J. C. J. Am. Chem. Soc. 1965, 78, 1137
  13. Ganjali, M. R.; Daftari, A.; Mizani, F. Bull. Korean Chem. Soc. 2003, 24, 23 https://doi.org/10.5012/bkcs.2003.24.1.023
  14. Ganjali, M. R.; Pourjavid, M. R.; Muradzadegan, A.; Hosseini, M.; Mizani, F. Bull. Korean Chem. Soc. 2003, 24, 1585 https://doi.org/10.5012/bkcs.2003.24.11.1585
  15. Bakker, E. Electroanalysis 1997, 9, 7 https://doi.org/10.1002/elan.1140090103
  16. Ganjali, M. R.; Emami, M.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2002, 23, 1394 https://doi.org/10.5012/bkcs.2002.23.10.1394
  17. Rosatzin, T.; Bakker, E.; Suzuki, K.; Simon, W. Anal. Chim. Acta 1993, 280, 197 https://doi.org/10.1016/0003-2670(93)85122-Z
  18. Gehring, P. M.; Morf, W. E.; Welti, N.; Simon, W. Helv. Chem. Acta 1990, 73, 203 https://doi.org/10.1002/hlca.19900730124
  19. Ganjali, M. R.; Rahimi-Nasrabadi, M.; Maddah, B.; Moghimi, A.; Borhany, S. Talanta 2004, 63, 899 https://doi.org/10.1016/j.talanta.2003.12.052
  20. Ganjali, M. R.; Daftari, A.; Rezapour, M.; Poursaberi, T.; Haghgoo, S. Talanta 2003, 59, 613 https://doi.org/10.1016/S0039-9140(02)00573-8
  21. Ammann, D.; Pretsch, E.; Simon, W.; Lindner, E.; Bezegh, A.; Pungor, E. Anal. Chim. Acta 1985, 171, 119 https://doi.org/10.1016/S0003-2670(00)84189-6
  22. Bailey, P. L. Analysis with Ion-Selective Electrodes; Heyden: London, 1996
  23. Shamsipur, M.; Yousefi, M.; Hosseini, M.; Ganjali, M. R. Anal. Chem. 2002, 74, 5538 https://doi.org/10.1021/ac0110451

Cited by

  1. A Selective Membrane Electrode for Lanthanum(III) Ion Based on a Hexaaza Macrocycle Derivative as Ionophore vol.22, pp.10, 2006, https://doi.org/10.2116/analsci.22.1339
  2. Supramolecular Based Membrane Sensors vol.6, pp.8, 2006, https://doi.org/10.3390/s6081018
  3. Lanthanide Recognition: an Asymetric Erbium Microsensor Based on a Hydrazone Derivative vol.7, pp.12, 2007, https://doi.org/10.3390/s7123119
  4. Lanthanide Recognition: Monitoring of Praseodymium(III) by a Novel Praseodymium(III) Microsensor Based on N$'$-(Pyridin-2-Ylmethylene)Benzohydrazide vol.7, pp.8, 2007, https://doi.org/10.1109/JSEN.2007.897950
  5. ′‐bis(2‐Pyridinecarboxamide)‐1,3‐benzene as a Sensing Material vol.41, pp.1, 2008, https://doi.org/10.1080/00032710701746824
  6. Lanthanide Recognition: Determination of Thulium(III) Ions in Presence of Other Rare Earth Elements by a Thulium(III) Sensor Based on 4-Methyl-1,2-Bis(2-Pyridinecarboxamido)benzene as a Sensing Material vol.41, pp.13, 2008, https://doi.org/10.1080/00032710802350484
  7. Lanthanide Recognition: Development of an Asymetric Gadolinium Microsensor Based on N-(2-pyridyl)-N′-(4-nitrophenyl)thiourea vol.41, pp.16, 2008, https://doi.org/10.1080/00032710802440525
  8. Schiff's Bases and Crown Ethers as Supramolecular Sensing Materials in the Construction of Potentiometric Membrane Sensors vol.8, pp.3, 2008, https://doi.org/10.3390/s8031645
  9. Developments in the Field of Conducting and Non-conducting Polymer Based Potentiometric Membrane Sensors for Ions Over the Past Decade vol.8, pp.4, 2008, https://doi.org/10.3390/s8042331
  10. Bach Adsorption Study for the Extraction of Silver Ions by Hydrazone Compounds from Aqueous Solution vol.2012, pp.1537-744X, 2012, https://doi.org/10.1100/2012/351967
  11. Lanthanum-selective sensors based on 3-amino-2-mercapto-3H-quinazolin-4-one in PVC matrix vol.10, pp.1, 2013, https://doi.org/10.1007/s13738-012-0136-x
  12. Development of Pr(III) Selective Electrode Using 1,6,7,12-Tetramine-2,5,8,11-tetraoxo-1(12),6(7)-di(biphenyl)-dodecane (TATODBDD) as a Neutral Carrier vol.28, pp.5, 2010, https://doi.org/10.1002/cjoc.201090154
  13. A sensitive nano-sensor based on synthetic ligand-coated CdTe quantum dots for rapid detection of Cr(III) ions in water and wastewater samples vol.296, pp.9, 2018, https://doi.org/10.1007/s00396-018-4375-y
  14. Electrochemical Sensors Containing Schiff Bases and their Transition Metal Complexes to Detect Analytes of Forensic, Pharmaceutical and Environmental Interest. A Review pp.1547-6510, 2019, https://doi.org/10.1080/10408347.2018.1561242
  15. Novel Triiodide PVC-Based Membrane Sensor Based on a Charge Transfer Complex of Iodine and Bis(2-hydroxyacetophenone)butane-2,3-dihydrazone vol.26, pp.11, 2005, https://doi.org/10.5012/bkcs.2005.26.11.1738
  16. A Highly Selective and Sensitive Calcium(II)-Selective PVC Membrane Based on Dimethyl 1-(4-Nitrobenzoyl)-8-oxo-2,8-dihydro-1H-pyrazolo[5,1-a]isoindole-2,3-dicarboxylate as a Novel Ionophore vol.27, pp.6, 2006, https://doi.org/10.5012/bkcs.2006.27.6.835
  17. Novel Tm(III) Membrane Sensor Based on 2,2'-Dianiline Disulfide and Its Application for the Fluoride Monitoring of Mouth Wash Preparations vol.27, pp.9, 2006, https://doi.org/10.5012/bkcs.2006.27.9.1418
  18. A Highly Selective and Sensitive Barium(II)-Selective PVC Membrane Based on Dimethyl 1-Acetyl-8-oxo-2,8-dihydro- 1H-pyra-zolo[5,1-a]isoindole-2,3-dicarboxylate vol.18, pp.9, 2006, https://doi.org/10.1002/elan.200503472
  19. A New Europium(III) PVC Membrane Potentiometric Sensor Based on 4-(2-Hydroxybenzylideneamino)-6-methyl-3-thioxo-3,4-dihydro-1,2,4-triazin-5(2H)-one vol.80, pp.1, 2005, https://doi.org/10.1246/bcsj.80.172
  20. Synthesis of a New Hexadendates Schiff's Base and Its Application in the Fabrication of a Highly Selective Mercury(II) Sensor vol.28, pp.1, 2005, https://doi.org/10.5012/bkcs.2007.28.1.068
  21. Construction of a highly selective PVC-based membrane sensor for Ce(III) ions vol.120, pp.2, 2007, https://doi.org/10.1016/j.snb.2006.03.013
  22. Thulium(III) Ions Monitoring by a Novel Thulium(III) Microelectrode Based on a S-N Schiff Base vol.19, pp.11, 2005, https://doi.org/10.1002/elan.200603833
  23. Ytterbium-selective polymeric membrane electrode based on substituted urea and thiourea as a suitable carrier vol.597, pp.2, 2005, https://doi.org/10.1016/j.aca.2007.06.052
  24. Polymeric membrane neodymium(III)-selective electrode based on 11,13-diaza-4,7,12-trioxo-2(3),8(9)-dibenzoyl- cyclotetridecane-1,11-diene vol.502, pp.1, 2005, https://doi.org/10.1016/j.msea.2008.10.014
  25. Investigation of Yb(III)-PVC membrane interfacial interaction by semiempirical PM6/SPARKLE method based on 1,10-phenanthroline-5,6-dione as a suitable neutral ionophore vol.354, pp.1, 2005, https://doi.org/10.1016/j.jcis.2010.09.064
  26. Graphite disk Lanthanum(III)-selective electrode based on Kryptofix-22DD vol.99, pp.14, 2005, https://doi.org/10.1080/03067319.2019.1625338