하수 염소 소독시 소독부산물 발생 특성

Formation Characteristics of Disinfection By-Products using Chlorine Disinfection in Sewage Effluent

  • 백영석 ((재)한국환경수도연구소) ;
  • 송민형 ((재)한국환경수도연구소) ;
  • 정경훈 ((재)한국환경수도연구소) ;
  • 권동식 ((재)한국환경수도연구소) ;
  • 이기공 ((재)한국환경수도연구소)
  • 투고 : 2004.03.12
  • 심사 : 2004.03.26
  • 발행 : 2004.05.30

초록

This study was performed to investigate the disinfection efficiency and the formation characteristics of disinfection by-products(DBPs) by chlorination in the sewage effluent. The effluent was sampled from the sewage treatment plants operated in the activated sludge process and the advanced sewage process. The type of DBPs investigated were Trihalomethanes(THMs), Dichloroacetonitrile(DCAN), Chloral hydrate(CH), Dichloroacetic acid(DCAA), Trichloroacetic acid(TCAA). Major findings are as follows. First, the optimum injection concentration for chlorination in sewage effluent were found to be in the range $0.5{\sim}1.0mg\;cl_2/L$. Also, It was found that the chlorine dosage in the effluent of activated sludge process was higher than in the effluent of advanced sewage process. Second, the maximum formation concentration of THMs were $12.7{\mu}g/L$. The THMs formation reaction was finished in a short time of several seconds and chloroform was mainly formed. Also, it was found that the concentration of ammonium nitrogen is higher, the concentration of THMs is lower. Third, it was found that DCAA and TCAA were mainly formed as DBPs by disinfection.

키워드

참고문헌

  1. 환경부, 환경부통계자료 (2003)
  2. Geo. Clifford White, Handbook of chlorination and alternative disinfectants - Third Edition, pp 479-482 (1992)
  3. 환경부, 수질오염공정시험법 (2003)
  4. EPA Method - 551.1, Determination of Chlorination Disinfection By-products, Chlorinated solvents, and Halogenated pesticides/herbicides in drinking water by Liquid-Liquid Extraction and Gas Chromatography with Electron-Capture Detection (1990)
  5. EPA Method - 524.2, Measurement of Purgeable Organic Compounds in water by Capillary Column Gas Chromatography/Mass Spectrometry (1992)
  6. EPA Method - 552, Determination of Haloacetic Acids in drinking water by Liquid-Liquid Extraction, Derivatization, and Gas Chromatography with Electron Capture Detection (1990)
  7. Christopher J. peters, Robert J. young and Roger Perry, Factors Influencing the Formation of Haloforms in the Chlorination of Humic Materials, Envir. Sci. & Tech., 14(11), pp 1391-1395 (1979)
  8. 한기복, 염소소독에 따른 오수 . 분료 처리시설의 THM 발생실태 조사 연구, 창원대학교 산업대학원 석사 논문 (1999)
  9. Anderson DR & Lusty EW., Acute toxicity and bioaccumulation of chloroform to 4 species of freshwater fish. Richland, WA, Battelle Pacific North West Laboratory (NUREG/CR-0893) (1980)
  10. EPA, National Toxizs Rule Criteria (2000)
  11. Zok S., J.C. Boutonnet, C. de Rooij, V. Grany, A. Lecoloux, R. Papp, R.S. Thompson, D. van Wijk, Euro Chlorine risk assessment for the marine environmenta OSPARCOM Region:North Sea - Chloroform, Env. Mon. and Assessment, 52, pp 401-424 (1998)
  12. Rook J.J., Chlorination Reaction of Fulvic Acids in Natural Water, Envir. Sci. & Tech., 11(5), pp 478-482 (1977)
  13. Pourmoghaddas H., and Stevens A.A, Relationship between Trihalomethanes and Haloacetic acids with Total Organic Halgen during Chlorination, Wat. Res., 29(9), pp 2059-2063 (1995)