한국결정학회지 (Korean Journal of Crystallography)

한국결정학회 (Korean Crystallographic Association)
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2차원 격자 형태의 구리 배위 고분자: Bromo(pyrazine)copper(I), [CuBr(pyz)]의 합성 및 구조

A Two-dimensional Grid of Copper (I) Coordination Polymer: Preparation and Structure of Bromo(pyrazine)copper(I), [CuBr(pyz)]

  • Baeg, Jee-Young (Department of Chemistry (BK21), Sungkyunkwan University) ;
  • Kim, Han-Na (Department of Chemistry (BK21), Sungkyunkwan University) ;
  • Lee, Yeon-Kyoung (Department of Chemistry (BK21), Sungkyunkwan University)
  • 발행 : 2004.01.01
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초록

Copper(I) bromide(CuBr) 와 pyrazine($C_4H_4N_2$, pyz)의 수열 반응으로 2차원 배위 고분자 [CuBr(pyz)] (1)이 얻어졌다. X-ray 구조 결정 결과, 고분자 1은 4.0${\times}$5.7 ${\AA}$ 크기를 갖는 직사각형 격자들을 토대로 한 2차원 그물 망 구조를 갖고 있었다. 고분자 1은 b-축 방향으로 통로(channel)를 갖고 있다.

The hydrothermal reaction of copper(I) bromide (CuBr) and pyrazine ($C_4H_4N_2$, pyz) gave a 2-D corrdination polymer [CuBr(pyz)] (1). X-ray structure determination revealed that polymer 1 has a 2-D network based on rectangular grids, each of which has the dimensions of 4.0${\times}$5.7 ${\AA}$. Polymer 1 has channels along the b-axis.

키워드

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