Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
권호 표지

Novel Macromonomer as a Reactive Stabilizer in the Dispersion Polymerization of Methylmethacrylate

  • Jung, Hye-Jun (Department of Chemical Engineering, Inha University) ;
  • Lee, Kang-Seok (Department of Chemical Engineering, Inha University) ;
  • Shim, Sang-Eun (Department of Chemical Engineering, Inha University) ;
  • Yang, Sun-Hye (Department of Chemical Engineering, Inha University) ;
  • Lee, Jung-Min (Department of Chemical Engineering, Inha University) ;
  • Lee, Hui-Je (Department of Chemical Engineering, Inha University) ;
  • Choe, Soon-Ja (Department of Chemical Engineering, Inha University)
  • Published : 2004.10.01
Download PDF
⟨ Previous Next ⟩

Abstract

We have synthesized a novel macromonomer of vinyl-terminated bifunctional polyurethane having a molecular weight of 37,000 g/mol and successfully applied it to the dispersion polymerization of methylmethacrylate(MMA). We verified the presence of the vinyl terminal group and the macromonomer grafted onto the poly(ethylene glycol)(PEG) block in the PMMA particles by using $^1$H and $\^$13/C NMR spectroscopies. Monodisperse PMMA microspheres that have good uniformity of 1.01 were prepared at 20 wt% macromonomer content; we investigated the characteristics of the PMMA particles in terms of their molecular weight, molecular weight distribution, size of the particles, thermal properties, and glass transition temperature. We have found that the synthesized polyurethane macromonomer is an effective stabilizer.

Keywords

References

  1. Vysok. Soed. Seriya A v.33 E. B. Malyukova;S. V. Naumova;I. A. Gritskova;A. N. Bondarev;V. P. Zubov
  2. J. Appl. Polym. Sci. v.66 S. Lam;A. C. Hellgren;M. Sjoberg;K. Holmberg;H. A. S. Schoonbrood;M. J. Unzue;J. M. Asua;K. Tauer;D. C. Sherrington https://doi.org/10.1002/(SICI)1097-4628(19971003)66:1<187::AID-APP22>3.0.CO;2-Y
  3. Polym. Int. v.43 A. Duchesne;B. Gerharz;G. Liester https://doi.org/10.1002/(SICI)1097-0126(199706)43:2<187::AID-PI752>3.0.CO;2-H
  4. Prog. Org. Coat. v.20 J. B. Werner https://doi.org/10.1016/0033-0655(92)80017-Q
  5. J. Oil Colour Chem. Assoc. v.54 F. A. Waite
  6. Dispersion Polymerization in Organic Media J. L. Cawse
  7. Macromol. Reports v.A32 M. Nugroho;S. Kawaguchi;K. Ito
  8. Macromolecules v.28 S. Kawaguchi;M. A. Winnik;K. Ito https://doi.org/10.1021/ma00108a051
  9. Chem. Lett. H. Uyama;Y. Matsumoto;S. Kobayashi
  10. J. Polym. Sci.: Part A : Polym. Chem. v.31 H. Uyama;Y. Honda;S. Kobayashi https://doi.org/10.1002/pola.1993.080310114
  11. J. Polym. Sci.: Part A: Polym. Chem. v.27 M. Akashi;T. Yanagi;E. Yashima;N. Miyauchi https://doi.org/10.1002/pola.1989.080271029
  12. Acta Polym. v.49 J. M. Asua;H. A. S. Schoonbrood https://doi.org/10.1002/(SICI)1521-4044(199812)49:12<671::AID-APOL671>3.0.CO;2-L
  13. Polym. Advan. Technol. v.6 F. Vidal;A. Guillot;A. Guyot https://doi.org/10.1002/pat.1995.220060708
  14. Macromol. Res. v.11 Y. Choe https://doi.org/10.1007/BF03218369
  15. Polymer. v.41 I. Capek;S. H . Nguyen;D. Berek https://doi.org/10.1016/S0032-3861(00)00053-7
  16. Colloid Polym. Sci. v.275 E. Bourgeat-Lami;A. Guyot https://doi.org/10.1007/s003960050140
  17. C. R. Chimie v.6 R. Shen;C. Akiyama;T. Senyo;K. Ito https://doi.org/10.1016/j.crci.2003.09.001
  18. J. Polym. Sci.; Part A : Polym. Chem. v.31 K. Li;H. D. H. Stover https://doi.org/10.1002/pola.1993.080311007
  19. J. Appl. Polym. Sci. v.77 H. M. Ghazaly;E. S. Daniels;V. L. Dimonie;M. S. ElAasser;A. Klein https://doi.org/10.1002/1097-4628(20000808)77:6<1362::AID-APP23>3.0.CO;2-Q
  20. J. Appl. Polym. Sci. v.81 H. M. Ghazaly;E. S. Daniels;V. L. Dimonie;M. S. ElAasser;A. Klein https://doi.org/10.1002/app.1604
  21. Colloid Polym. Sci. v.282 S. M. Klein;V. N. Manoharan;D. J. Pine;F. F. Lange https://doi.org/10.1007/s00396-003-0915-0
  22. Polymer v.44 Q. Dai;D. Wu;Z. Zhang;Q. Ye https://doi.org/10.1016/S0032-3861(02)00728-0
  23. Polymer v.34 B. Charleux;C. Pichot;M. F. Llauro
  24. Macromolecules v.33 J. S. Shay;R. J. English;R. J. Spontak;C. M. Balik;S. A. Khan https://doi.org/10.1021/ma992152o
  25. Macromolecules v.23 A. J. Paine;W. Luymens;J. McNulty https://doi.org/10.1021/ma00214a012