Study on Gas Hydrates for the Solid Transportation of Natural Gas

  • Kim, Nam-Jin (Mechanical Engineering Research Institute, Inha University) ;
  • Kim, Chong-Bo (Department of Mechanical Engineering, Inha University)
  • Published : 2004.04.01

Abstract

Natural gas hydrate typically contains 85 wt.% water and 15 wt.% natural gas, and commonly belongs to cubic structure I and II. When referred to standard conditions, 1 ㎤ solid hydrate contains up to 200㎥ of natural gas depending on pressure and temperature. Such the large volume of natural gas hydrate can be utilized to store and transport a large quantity of natural gas in a stable condition. In the present investigation, experiments were carried out for the formation of natural gas hydrate governed by pressure, temperature, gas compositions, etc. The results show that the equilibrium pressure of structure II is approximately 65% lower and the solubility is approximately 3 times higher than structure I. It is also found that for the sub-cooling of structure I and II of more than 9 and 11 K respectively, the hydrates are rapidly being formed. It is noted that utilizing nozzles for spraying water in the form of droplets into the natural gas dramatically reduces the hydrate formation time and increases its solubility at the same time.

Keywords

References

  1. Chang, D. G., Kim, N. J., Lee, J. Y. and Kim, C. B., 2000, 'Simulation of two Phase Flow in Porous Media After Dissociation of Methane Hydrate,' Proceeding of the KSME 2000 Fall Annual Meeting, pp. 241-246
  2. Englezos, P., Kalogerakis, N., Dholabhai, P.D. and Bishnoi, P. R., 1987, 'Kinetics of Fortion of Mathane and Ethane Gas Hydrate,' Chemical Engineering Sciecne, Vol. 42, No. 11, pp. 2647-2658 https://doi.org/10.1016/0009-2509(87)87015-X
  3. Gudmundsson, J. S., Andersson, V. and Levik, O. I., 1997, 'Gas Storage and Transport Using Hydrates,' Offshore Mediterranean Conference
  4. Hammerschmidt, E. G., 1934, 'Formation of Gas Hydrates in Natural Gas Transmission Lines,' Int. Eng. Chem., Vol. 26, pp. 851-855 https://doi.org/10.1021/ie50296a010
  5. Kim, N. J., Lee, J. Y., Seo, T. B. and Kim, C. B., 2000, 'Dissolution Characteristics of Liquid $CO_2$ Injected at the Intermediate Depth of the Ocean,' KSME Int. J., Vol. 14, No. 11, pp. 1276-1285
  6. Kuhs, W. F., Chazallon, B., Radaelli, G. and Pauer, F., 1997, 'Cage Occupancy and Compressibility of Deuterated N2-Hydrate by Neutron Diffraction,' J. Incl. Phenom. Vol. 29, pp. 65-77 https://doi.org/10.1023/A:1007960217691
  7. Kvenvolden, K. A., 1988, 'Methane Hydrate-a Major Reservoir of Carbon in the Shallow Geosphere?,' Chem. Geol., Vol. 71, pp. 41-51 https://doi.org/10.1016/0009-2541(88)90104-0
  8. Okuda, Y., 1996, 'Exploration Research on Gas Hydrates in Japan,' 5th Petroleum Exploration and Development Symposium, pp. 62-98
  9. Sloan, E.D., 1998, Clathrate hydrates of natural gases, Marcel Dekker, inc., New York, pp. 1-318
  10. Youslf, M. H., 1994, 'The Kinetics of Hydrate Formation,' SPE 28479, pp. 169-177