Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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UV-Vis Spectra of N, N'-Bis(4′-Aminophenyl)-1,4-quinonenediimine Doped With $H_{4}SiW_{12}O_{40}$

  • Jian Gong (Department of Chemistry, Northeast Normal University) ;
  • Cui, Xiu-Jun (Department of Chemistry, Northeast Normal University) ;
  • Chen, Ya-Guang (Department of Chemistry, Northeast Normal University) ;
  • Xie, Zhong-Wei (Department of Chemistry, Northeast Normal University) ;
  • Qu, Lun-Yu (Department of Chemistry, Northeast Normal University)
  • Published : 2004.02.01
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Abstract

We have synthesized aniline oligomer composites by using heteropoly acid (H$_4$SiW$_{12}$O$_{40}$ ) as a dopant. The doping and dedoping processes of the aniline oligomer composites were investigated with the aid of UV- Vis spectra. The bands of the aniline oligomer at 572 nm weakened or disappeared, and the bands at 268, 412, and 771 nm appeared, after the aniline oligomer was doped. When the solution of the aniline oligomer doped with H$_4$SiW$_{12}$O$_{40}$ was kept at lower values of pH, the aniline oligomer could not be dedoped by dilution. The turning point of doping and dedoping occurred at pH 5.5. The band at 771 nm shifted towards longer wavelengths when the aniline oligomer composites were synthesized using acetone as the solvent. This observation indicates that the molecular chain became stretched. In addition, we also investigated the change of the electronic absorption spectra of the composites with respect to the time laid up.id up.

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