Macromolecular Research

  • 제12권1호
  • /
  • Pages.11-21
  • /
  • 2004
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Rubber Toughened Epoxy

  • Ratna, D. (Naval Materials Research Laboratory, Chickloli, Anandanugar P.O Addl Ambernath (E)) ;
  • Banthia, Ajit K. (Materials Science Centre, I.I.T.)
  • 발행 : 2004.02.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Toughening of epoxy resins for improvement of crack resistance has been the subject of intense research interest during the last two decades. Epoxy resins are successfully toughened by blending with a suitable liquid rubber, which initially remains miscible with epoxy and undergoes a phase separation in the course of curing that leads to the formation of a two-phase microstructure, or by directly blending preformed rubbery particle. Unlike the situation for thermoplastics, physical blending is not successful for toughening epoxy resins. Recent advances in the development of various functionalized liquid rubber-based toughening agents and core-shell particles are discussed critically in this review.

키워드

참고문헌

  1. Epoxide Resins W.G.Potter
  2. Epoxy Resin Chemistry and Technology C.A.May;G.Y.Tanka
  3. Advances in Chemistry Series v.114 Epoxy Resin Chemistry R.S.Bouer
  4. Rapra Review Report v.38 K.A.Hodd
  5. Advances in Chemistry Series v.222 Robber Toughened Plastics W.D.Bascom;D.L.Hunston https://doi.org/10.1021/ba-1989-0222.ch008
  6. R 68-8, MIT Toughening of an Epoxy Resin by an Elastomer Second Phase F.J.McGarry;A.M.Willner
  7. Polym. Eng. Sci. v.13 J.N.Sultan;F.J.McGarry https://doi.org/10.1002/pen.760130105
  8. Org. Coat. Plast. Chem. v.44 J.E.Sohn
  9. Polymer v.22 J.Daly;R.A.Pethrick;P.Fuller;A.V.Cunliffe;P.K.Dutta https://doi.org/10.1016/0032-3861(81)90073-2
  10. Adhesive Chemistry:Developments and Trends N.Xuzong;W.Lijuan;X.Rulian;L.Yiming;Y.Yunchao;;L.H.Lee(ed.)
  11. J. Adhesion v.22 H.Dodiuk;S.Kenig;I.Liran https://doi.org/10.1080/00218468708071245
  12. Org. Coat. Plast. Chem. v.31 A.R.Siebert;C.K.Riew
  13. Org. Coat. Plast. Chem. v.39 W.D.Bascom;R.J.Moulton;E.J.Rowe;A.R.Siebert
  14. Adv. Chem. Ser. v.221 Epoxy Resins Chemistry Ⅱ W.A.Romanchick;J.E.Sohn;J.F.Gaibel;R.S.Bauer(ed.)
  15. Polymer v.18 N.C.Paul;H.D.Richards;D.Thomson https://doi.org/10.1016/0032-3861(77)90140-9
  16. Polym. Eng. Sci. v.26 C.B.Bucknall;I.K.Partridge https://doi.org/10.1002/pen.760260109
  17. Polymer-Polymer Miscibility O.Olabisi;L.M.Robeson;M.T.Shaw
  18. Principles of Polymer Chemistry P.J.Flory
  19. Macromolecules v.7 S.Visconti;R.H.Marchessault https://doi.org/10.1021/ma60042a040
  20. J. Adhesion v.13 J.L.Bitner;J.L.Rushford;W.S.Rose;D.L.Hunston;C.K.Riew https://doi.org/10.1080/00218468108073171
  21. J. Appl. Polym. Sci v.31 H.N.Nae https://doi.org/10.1002/app.1986.070310103
  22. J. Appl. Polym. Sci. v.30 P.Bartlet;J.P.Pascault;H.Sautereau https://doi.org/10.1002/app.1985.070300719
  23. Am. Chem. Soc. Div. Org. Coat. Plast. Chem. v.37 J.K.Gillham;C.A.Glandt;C.A.McPherson
  24. J. Appl. Polym. Sci. v.42 D.Verchere;J.P.Pascault;H.Sautereau;S.M.Moschair;C.C.Riccardi;R.J.J.Williams https://doi.org/10.1002/app.1991.070420315
  25. Transport Phenomena R.B.Bird;W.E.Stewart;E.N.Lightfoot
  26. J. Appl. Polym. Sci v.26 L.T.Manzione;J.K.Gillham https://doi.org/10.1002/app.1981.070260313
  27. J. Appl. Polym. Sci. v.26 L.T.Manzione;J.K.Gillham
  28. Polym. Eng. Sci. v.29 J.F.Hwang;J.A.Manson;R.W.Hertzberg;G.A.Miller;H.L.Sperling https://doi.org/10.1002/pen.760292008
  29. Adv. Chem. Ser. v.222 Rubber Toughened Plastics S.Manternal;J.P.Pascault;H.Sautereau;C.K.Riew(ed.) https://doi.org/10.1021/ba-1989-0222.ch008
  30. Adv. Chem. Ser. v.208 Rubber Modified Themoset Resins R.J.J.Williams;J.Borrajo;H.E.Adabbo;A.J.Rojas;C.K.Riew(ed.);J.K.Gillham(ed.) https://doi.org/10.1021/ba-1984-0208.ch013
  31. New Polymeric Materials R.J.J.Williams;H.E.Adabbo;A.J.Rojas;J.Borrajo;E.Martuscelli(ed.);C.Marchetta(ed.)
  32. Polymer v.28 A.Vazquez;A.J.Rojas;H.E.Adabbo;J.Borrajo;R.J.J.Williams https://doi.org/10.1016/0032-3861(87)90259-X
  33. Polym. Int. v.26 R.V.Villiani;N.Bianchi;R.Braglia https://doi.org/10.1002/pi.4990260203
  34. J. Appl. Polym. Sci. v.41 D.Verchere;H.Sautereau;J.P.Pascault;S.M.Moschiar;C.C.Riccardi;R.J.J.Williams https://doi.org/10.1002/app.1990.070410303
  35. Polym. Eng. Sci. v.26 E.Butta;G.Lavita;A.Marchetti;A.Lazzeri https://doi.org/10.1002/pen.760260111
  36. J. Mater. Sci. Lett. v.6 A.J.Kinloch;D.L.Hunston https://doi.org/10.1007/BF01728961
  37. Macromolecules v.23 D.Verchere;H.Sautereau;J.P.Pascault;S.M.Moschair;C.C.Riccardi;R.J.J.Williams https://doi.org/10.1021/ma00205a006
  38. Polym. Sci. USSR v.25 G.F.Roginskya;V.P.Volkov;L.M.Vogdanova;A.Y.Chalykh;B.A.Rosenberg https://doi.org/10.1016/0032-3950(83)90431-8
  39. Polym. Eng. Sci. v.30 H.S.Y.Hsich https://doi.org/10.1002/pen.760300902
  40. J. Mater. Sci. v.26 H.S.Y.Hsich https://doi.org/10.1007/BF01124665
  41. Polymer v.30 K.Yamanka;T.Takagi;T.Inoue https://doi.org/10.1016/0032-3861(89)90355-8
  42. Polym. Eng. Sci. v.34 D.S.Kim;S.C.Kim https://doi.org/10.1002/pen.760342104
  43. Rubber Chem. Technol. v.58 C.K.Riew https://doi.org/10.5254/1.3536081
  44. Eur. Polym. J. v.31 M.E.Frigione;L.Mascia;D.Acierno https://doi.org/10.1016/0014-3057(95)00091-7
  45. Int. J. Adhesion & Adhesives v.14 A.H.Rezaiford;K.A.Hodd;D.A.Tod;J.M.Barton https://doi.org/10.1016/0143-7496(94)90011-6
  46. Advances in Chemistry Series v.92 Epoxy Resins R.Slysh
  47. Polymer v.33 T.J.Kemp;A.Wilford;O.W.Howarth;T.C.P.Lee https://doi.org/10.1016/0032-3861(92)90485-F
  48. J. Mater. Sci. v.28 K.Mizutani https://doi.org/10.1007/BF00367580
  49. Polym. Mater. Sci. Eng. v.65 I.Frischinger;S.K.Dirlikov
  50. Polym. Mater. Sci. Eng. v.70 I.Frischinger;S.K.Dirlikov
  51. J. Adhesion Sci. Technol. v.14 D.Ratna;A.K.Banthia https://doi.org/10.1163/156856100742087
  52. Adhesion and Adhesive:Science and Technology A.J.Kinloch
  53. Polym. Eng. Sci. v.23 Y.Okamoto https://doi.org/10.1002/pen.760230411
  54. Adv. Chem. Ser. v.208 Rubber Modified Themoset Resins K.Duseck;F.Lendnicky;S.Lunak;M.Mach;D.Duskova;C.K.Riew(ed.)
  55. Polym. Mater. Sci. Eng. v.63 S.J.Jin;A.F.Yee
  56. Polym. Mater. Sci. Eng. v.63 J.C.Hedric;J.E.MaGrath
  57. Polymer v.36 J.Z.Shao;S.Li https://doi.org/10.1016/0032-3861(95)92019-B
  58. J. Appl. Polym. Sci. v.54 L.Konczol;W.Doll;V.Buchholz;R.Mulhaupt https://doi.org/10.1002/app.1994.070540612
  59. Polymer Preper.(ACS) v.33 U.Buchholz;R.Mulhaupt
  60. J. Appl. Polym. Sci. v.52 J.D.Tong;R.K.Bai;Y.F.Zou;C.Y.Pan;S.Ichimura https://doi.org/10.1002/app.1994.070521003
  61. J. Appl. Polym. Sci. v.57 J.D.Tong;R.K.Bai;C.Y.Pan;E.J.Goethals https://doi.org/10.1002/app.1995.070570801
  62. Org. Coat. Plast. Chem. v.42 J.Riffle;I.Yilgor;A.K.Banthia;G.L.Wilkes;J.E.McGrath
  63. ACS Symp. Series v.221 Epoxy Resin Chemistry Ⅱ J.Riffle;I.Yilgor;C.Trans;G.L.Wilkes;J.E.McGrath;A.K.Banthia https://doi.org/10.1021/bk-1983-0221.ch002
  64. Kobunsi Ronbunghu v.49 M.Ochi;H.Yamana https://doi.org/10.1295/koron.49.499
  65. J. Mater. Sci. v.27 N.P.Laurienzo;M.Malinconico;E.Martuscelli;G.Rongosta;M.G.Valpe https://doi.org/10.1007/BF02403897
  66. J. Appl. Polym. Sci. v.48 M.B.Jackson;L.N.Edmond;R.J.Varley;P.G.Warden https://doi.org/10.1002/app.1993.070480714
  67. J. Appl. Polym. Sci. v.42 P. Sasidharan Achary;C.Gouri;R.Ramanurty https://doi.org/10.1002/app.1991.070420318
  68. J. Appl. Polym. Sci. v.41 P. Sasidharan Achary;P.B.Latha;R.Ramaswamy https://doi.org/10.1002/app.1990.070410113
  69. J. Appl. Polym. Sci. v.44 H.B.Wang;S.J.Li;J.Y.Ye https://doi.org/10.1002/app.1992.070440506
  70. ACTA Polym. v.46 J.Laeuger;P.Albert;J.Kressler;W.Grouski;R.Muelhaupt https://doi.org/10.1002/actp.1995.010460110
  71. J. Appl. Polym. Sci. v.44 H.B.Wang;S.J.Li;J.Y.Ye https://doi.org/10.1002/app.1992.070440506
  72. J. Appl. Polym. Sci. v.32 Yu-Der Lee;S.K.Wang;W.K.Chin https://doi.org/10.1002/app.1986.070320813
  73. Advances in Chemistry Series v.222 Rubber Toughened Plastics A.K.Banthia;P.N.Chaturvedi;V.N.S.Pendyala;V.Jha https://doi.org/10.1021/ba-1989-0222.ch016
  74. Polym. Int. v.49 D.Ratna;A.K.Banthia https://doi.org/10.1002/(SICI)1097-0126(200003)49:3<281::AID-PI353>3.0.CO;2-F
  75. J. Appl. Polym. Sci. v.78 D.Ratna;A.K.Banthia;P.C.Deb https://doi.org/10.1002/1097-4628(20001024)78:4<716::AID-APP40>3.0.CO;2-B
  76. J. Appl. Polym. Sci. v.80 D.Ratna;A.K.Banthia;P.C.Deb https://doi.org/10.1002/app.1275
  77. Polymer v.42 D.Ratna https://doi.org/10.1016/S0032-3861(00)00798-9
  78. Eur. Polym. J. v.26 T.Iijima;M.Tomoi;J.Yamasaki;H.Kakiuchi https://doi.org/10.1016/0014-3057(90)90179-8
  79. Angew. Makromolek. Chem. v.163 M.Tomoi;H.Yamazaki;H.Akada;H.Kakiuchi https://doi.org/10.1002/apmc.1988.051630106
  80. Polymer v.40 L.Boogh;B.Pettersson;E.J.Manson https://doi.org/10.1016/S0032-3861(98)00464-9
  81. J. Appl. Polym. Sci. v.72 H.Wu;J.Xu;Y.Liu;P.A.Heiden https://doi.org/10.1002/(SICI)1097-4628(19990411)72:2<151::AID-APP1>3.0.CO;2-0
  82. J. Polym. Mater. v.19 D.Ratna;G.P.Simon
  83. Polym. Eng. Sci. v.41 D.Ratna;G.P.Simon https://doi.org/10.1002/pen.10878
  84. Polymer v.42 D.Ratna;G.P.Simon https://doi.org/10.1016/S0032-3861(01)00341-X
  85. J. Mater. Sci. v.38 D.Rratna;R.Varley;R.K.Singh;G.P.Simon https://doi.org/10.1023/A:1021182320285
  86. J. Polym. Sci. Polym. Phys. v.38 R.Mezzenga;L.Boogh;E.J.Manson https://doi.org/10.1002/1099-0488(20000715)38:14<1883::AID-POLB70>3.0.CO;2-M
  87. Polym. Eng. Sci. v.31 H.J.Sue https://doi.org/10.1002/pen.760310410
  88. J. Mater. Sci. v.31 H.J.Sue;R.J.Young
  89. Polym. Bull. v.33 A.Maazouz;H.Santerean;J.F.Genard https://doi.org/10.1007/BF00313475
  90. J. Appl. Polym. Sci. v.32 Y.Nakamura;H.Tabata;H.Sujuki;K.Iko;M.Ocubo;T.Matsumoto https://doi.org/10.1002/app.1986.070320509
  91. Polym. Bull. v.33 A.Maazouz;H.Sautareau;J.F.Gerard https://doi.org/10.1007/BF00313475
  92. Polym. Mater. Sci. Eng. Prep. v.54 J.W.Vanderhoff;M.S.El-Aasser;F.J.Micale;E.D.Sudol;C.M.Tseng;A.Silwanowicz;H.R.Shew;D.M.Kornfeld
  93. Adv. Colloid Interface Sci. v.13 J.Ugelstad;P.C.Mork;K.H.Kaggund;T.Ellingsen;A.Berge https://doi.org/10.1016/0001-8686(80)87003-5
  94. Disperson Polymerization in Organic Media K.E.J.Barret
  95. J. Polym. Sci., Part A:Polym. Chem. v.32 S.Shen;E.D.Sudol;M.S.El-Aasser
  96. J. Polym. Sci., Part A:Polym. Chem. v.25 M.P.Markel;V.L.Dimonie;M.S.El-Aasser;J.W.Vanderhoff https://doi.org/10.1002/pola.1987.080250503
  97. ACS. Sym. Ser. v.165 D.L.Lee
  98. Macromolecules v.24 J.L.Jhonson;H.Hassander;L.H.Jansson;B.Tornwell https://doi.org/10.1021/ma00001a021
  99. ACS Symp. Series v.492 Polymer Letex Preparation, Characterization and Applications S.Lee;A.Rudin;E.S.Daniels(ed.);E.D.Sudol(ed.);M.S.El-Aasser(ed.) https://doi.org/10.1021/bk-1992-0492.ch015
  100. Polym. Mater. Sci. Eng. v.76 K.F.Lin;Y.D.Shieh
  101. J. Polym. Sci. Polym. Phys. Ed. v.31 H.J.Sue;E.L.Garcia-Maitin;N.A.Orchard https://doi.org/10.1002/polb.1993.090310511
  102. J. Appl. Polym. Sci. v.58 J.Y.Qian;R.A.Person;V.L.Dimonie;M.S.El-Aasser
  103. J. Appl. Polym. Sci. v.70 K.F.Lin;Y.D.Shieh https://doi.org/10.1002/(SICI)1097-4628(19981219)70:12<2313::AID-APP2>3.0.CO;2-P
  104. J. Appl. Polym. Sci. v.69 K.F.Lin;Y.D.Shieh https://doi.org/10.1002/(SICI)1097-4628(19980906)69:10<2069::AID-APP18>3.0.CO;2-X
  105. Polymer v.35 D.Tompas;G.Groeninckx https://doi.org/10.1016/0032-3861(94)90727-7
  106. Polymer v.35 D.Tompas;G.Groeninckx
  107. ACS Advances in Chemistry Series v.233 Toughened Plastics Ⅰ C.K.Riew(ed.);A.J.Kinloch(ed.)
  108. ACS Advances in Chemistry Series v.252 Toughened Plastic Ⅱ C.K.Riew(ed.);A.J.Kinloch(ed.)
  109. Int. J. Fracture v.14 H.Yamamoto https://doi.org/10.1007/BF00015989
  110. J. Mater. Sci. v.29 D.Li;A.F.Yee;I.W.Chen;S.C.Chang;K.Takahashi https://doi.org/10.1007/BF01154701
  111. Advances in Chemistry Series v.208 Rubber Modified Themoset Resins J.A.Clarke;C.K.Riew(ed.);J.K.Gillham(ed.) https://doi.org/10.1021/ba-1984-0208.ch005
  112. Natl. SAMPE, Tech. Conference v.12B B.L.Lee;C.M.Lizak;C.K.Riew;R.J.Moulton
  113. SAMPA Q. v.16 J.Diamant;R.J.Moulton
  114. Eur. Polym. J. v.28 T.Iijima;N.Yoshioka;M.Tomi https://doi.org/10.1016/0014-3057(92)90025-W
  115. J. Appl. Polym. Sci. v.65 D.Ratna;M.Patri;B.C.Chakraborty;P.C.Deb https://doi.org/10.1002/(SICI)1097-4628(19970801)65:5<901::AID-APP7>3.0.CO;2-R
  116. J. Polym. Mater. v.14 D.Ratna;B.C.Chakrabarty;P.C.Deb
  117. Adv. Polym. Sci. v.78 J.D.Lemay;F.N.Kelley https://doi.org/10.1007/BFb0035359
  118. J. Mater. Sci. v.16 B.W.Cherry;K.W.Thomson https://doi.org/10.1007/BF00540640
  119. Polym. Mater. Sci. Eng. Prepr. v.186 R.A.Pearson;A.F.Yee
  120. J. Polym. Commun. v.28 C.A.Finch;S.Hashemi;A.J.Kinloch
  121. J. Mater. Sci. v.26 G.Levita;S.Depetris;A.Marchetti;A.Lazzeri https://doi.org/10.1007/BF01130180
  122. Advances in Chemistry Series v.222 Rubber Toughened Plastics G.Levita;C.K.Riew(ed.) https://doi.org/10.1021/ba-1989-0222.ch004
  123. Polym. Comm. v.29 P.J.Pearce;B.C.Ennis;C.E.M.Morris https://doi.org/10.1016/0032-3861(88)90205-4
  124. Polymer v.37 P.J.Pearce;C.E.M.Morris;B.C.Ennis https://doi.org/10.1016/0032-3861(96)80840-8
  125. J. Mater. Sci. v.29 K.Fulin;U.L.Chung https://doi.org/10.1007/BF00975064
  126. Advances in Chemistry Series v.208 Rubber Modified Thermoset Resins A.R.Siebert;C.K.Riew(ed.);J.K.Gillham(ed.) https://doi.org/10.1021/ba-1984-0208.ch012
  127. Polymer v.37 A.Lowe;O.H.Kwon;Y.H.Mai https://doi.org/10.1016/0032-3861(96)83142-9
  128. J. Mater. Sci. v.15 S.Kunz-Douglass;P.W.R.Beamont;M.F.Ashby https://doi.org/10.1007/BF00551799
  129. J. Mater. Sci. v.16 S. Kunz-Douglass;P.W.R.Beamont https://doi.org/10.1007/BF00540323
  130. Adv. Chem. Ser. v.208 Rubber Modified Thermoset Resins L.C.Chen;J.K.Gillham;A.J.Kinloch;S.T.Shaw;C.K.Riew(ed.);J.K.Gillham(ed.) https://doi.org/10.1021/ba-1984-0208.ch015
  131. J. Appl. Polym. Sci. v.42 Y.B.Zeng;L.Z.Zang;W.Z.Peng;Q.Yu https://doi.org/10.1002/app.1991.070420713
  132. J. Mater. Sci. v.26 R.A.Pearson;A.F.Yee https://doi.org/10.1007/BF01184979
  133. Polymer v.31 S.Wu;A.Mongolina https://doi.org/10.1016/0032-3861(90)90068-A
  134. PhD thesis, The University of Michigan R.A.Pearson
  135. J. Mater. Sci. Lett. v.6 A.J.Kinloch;D.L.Hunston https://doi.org/10.1007/BF01728963
  136. Polymer v.23 S.C.Kunz;J.A.Sayre;R.A.Assink https://doi.org/10.1016/0032-3861(82)90215-4
  137. J. Mater. Sci. v.24 R.A.Pearson;A.F.Yee https://doi.org/10.1007/BF01174528
  138. Adv. Chem. Ser. v.233 Toughened Plastics H.J.Sue;E.I.Garcia-Meitin;D.M.Pickelman;P.C.Yang;C.K.Riew(ed.);A.J.Kinloch(ed.) https://doi.org/10.1021/ba-1993-0233.ch010
  139. J. Appl. Polym. Sci. v.58 R.Bagheri;R.A.Pearson https://doi.org/10.1002/app.1995.070580221