Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Synthesis of Fullerene Oxides [$C_{70}O_n$] ($n=1{\sim}3$ or n=1) under Microwave Irradiation

마이크로파 조건에서 풀러렌 산화물 [$C_{70}O_n$ ($n=1{\sim}3$ or n=1)의 합성

  • Ko, Weon-Bae (Department of Chemistry, Sahmyook University) ;
  • Ahn, Ju-Hyun (Department of Chemistry, Sahmyook University) ;
  • Lim, Young-A (Department of Chemistry, Sahmyook University) ;
  • Han, Ji-Yeon (Department of Chemistry, Sahmyook University) ;
  • Han, Dong-Sul (Department of Chemistry, Mokpo National University)
  • Published : 2004.12.31
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Abstract

Synthesis of fullerene oxides [$C_{70}O_n$] ($n=1{\sim}3$ or n=1) in solid state by fullerene [$C_{70}$] and several oxidants such as 3-chloroperoxy benzoic acid, chromium(VI) oxide, benzoyl peroxide, and trichloroisocyanuric acid was taken place under microwave irradiation. The reactivity in solid state oi fullerene [$C_{70}$] with various oxidants under same microwave condition increased in the order of 3-chloroperoxy benzoic acid > chromium(VI) oxide > trichloroisocyanuric acid ${\simeq}benzoyl$ peroxide. The MALDI-TOF-MS, UV-visible spectra and HPLC analysis confirmed that the products of fullerene oxidation were [$C_{70}O_n$] ($n=1{\sim}3$ or n=1).

풀러렌[$C_{70}$]을 3-chloroperoxy benzoic acid, chromium (VI) oxide, benzoyl peroxide, trichloroisocyanuric acid 등의 산화제를 사용하여 마이크로파 조건에서 반응시켜 풀러렌 난화물[$C_{70}O_n$] ($n=1{\sim}3$ or n=1)을 합성하였다. 동일한 마이크로파 조건에서 여러가지 산화제와 풀러렌[$C_{70}$]의 고체상태 반응성은 3-chloroperoxy benzoic acid > chromium(VI) oxide > trichloroisocyanuric acid $\simeq$ benzoyl peroxide 순으로 증가함을 나타냈다. MALDI-TOF-MS, UV-visible, 그리고 HPLC를 사용하여 분석한 결과 생성된 풀러렌 산화물은 [$C_{70}O_n$] ($n=1{\sim}3$ or n=1)임을 알 수 있었다.

Keywords

References

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