Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Synthesis of Fullerene Oxide by Fullerene ($C_{70}$) and Various Amino N-Oxides under Ultrasonic Irradiation

초음파 조건에서 여러가지 아민 N-옥시드와 풀러렌($C_{70}$)를 이용한 풀러렌 산화물의 합성

  • Ko, Weon-Bae (Department of Chemistry, Sahmyook University) ;
  • Han, Ji-Yeon (Department of Chemistry, Sahmyook University) ;
  • Lim, Young-A (Department of Chemistry, Sahmyook University) ;
  • Shin, Won-Jic (Department of Chemistry, Sahmyook University) ;
  • Yu, Gu-Yong (Department of Chemistry, Sahmyook University)
  • Published : 2004.06.30
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Abstract

Fullerene oxides were synthesized by fullerene ($C_{70}$) and several amine N-oxides such as 3-picoline N-oxide, pyridine N-oxide hydrate, quinoline N-oxide, and isoquinoline N-oxide under ultrasonic condition at $25{\sim}43^{\circ}C$. The reactivity of fullerene ($C_{70}$) with various amine N-oxides undo, ultrasonic irradiation showed the same in all of the proceeding experiments; 3-picoline N-oxide : pyridine N-oxide hydrate : quinoline N-oxide : isoquinoline N-oxide. The MALDI-TOF MS, UV-vis spectrophotometer and HPLC analysis confirmed that the products of fullerene oxidation are [$C_{70}(O)n$] (n=1).

풀러렌($C_{70}$)을 3-picoline N-oxide, pyridine N-oxide hydrate, quinoline N-oxide, isoquinolne N-oxide의 여러가지 아민 N-옥시드를 사용하여 $25{\sim}43^{\circ}C$, 초음파 조건에서 반응시켜 풀러렌 산화물을 합성 하였다. 동일한 초음파 조건에서 여러가지 아민 N-옥시드에 대한 풀러렌 ($C_{70}$)의 반응성은 3-picoline N-oxide : pyridine N-oxide hydrate : quinoline N-oxide : isoquinoline N-oxide 처럼 동일하게 나타났다. MALDI -TOF MS, UV-vis 그리고 HPLC를 사용하여 생성된 풀러렌 산화물을 분석한 결과 [$C_{70}(O)n$] (n=1) 임을 알 수 있었다.

Keywords

References

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