Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Asphalt Sealant Containing the Waste Edible Oil

폐식용유를 이용한 아스팔트 실란트

  • Kim, Seong-Jun (School of Material Science & Chemical Engineering, Kunsan National University)
  • 김석준 (군산대 재료.화학공학부)
  • Published : 2004.03.31
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Abstract

This work is about the development or asphalt sealant using the waste edible oil. Asphalt sealant has been used for crack filler and bridge deck joint sealer Several plasticizers such as aromatic or paraffin process oils, DOP, Bunker C fuel oil, and waste edible oil were compounded with the basic components such as asphalt(AP-5), a thermoplastic elastomer(SBS triblock copolymer), a tackifying agent(petroleum resin), and stabilizers. Penetration, softening point, ductility, and elongation by tensile adhesion of those asphalt sealant compounds were measured. Their properties were changed largely depending on both the type and content of plasticizers. Waste edible oil and DOP were the best plasticizers for the low temperature tensile adhesion characteristics. Penetration and elongation by tensile adhesion of asphalt sealant compounds increased with the increase of waste edible oil content and decreased with the increase of talc content. The manufacture of asphalt sealant with low penetration and excellent low temperature tensile adhesion was possible by the recipe optimization.

본 연구는 폐식용유를 이용하여 아스팔트계 봉함재(sealant)를 제조하는 것이다. 아스팔트계 봉함재는 포장도로의 균열 봉함재 및 교량 조인트용 봉함재로 사용되는 재료이다. 아스팔트(AP-5), 열가소성 고무(SBS triblock copolymer), 점착제(tackifier) 및 안정제를 기본 성분으로 하여 연화제로 방향족계 또는 파라핀계 공정유, DOP(dioctyl phthalate), 벙커 C유 또는 폐식용유와 혼합하여 침입도, 연화점, 신도 및 인장 접착 신율(상온 및 저온)을 측정하였다. 연화제의 종류 및 함량에 따라 봉함재의 물성이 크게 변화하였다. 폐식용유 또는 DOP를 사용한 경우가 저온 인장 접착 특성이 가장 우수하였다. 폐식용유 함량이 증가함에 따라 아스팔트 봉함재의 침입도는 및 인장 접착 신율은 증가하였고 증량제로 탈크를 첨가할 경우 함량에 비례하여 침입도 및 저온 인장 신율은 감소하였다. 배합비를 최적화하여 침입도가 낮으면서도 저온 인장 접착성이 우수한 아스팔트 봉함재를 제조할 수 있었다.

Keywords

References

  1. F. R. Davis, US Patent 4485201 (1984)
  2. R. L. Cottingham, D. J. Thorpe, and E. Bickerstaff, US Patent 4324504 (1982)
  3. R. F. Ju, Y. L. Lee, S. H. Lin, and W. J. Burke, 'Surface Modification of Aggregate in Asphalt Concrete', Colloids and Surfaces, 49, 395 (1990) https://doi.org/10.1016/0166-6622(90)80120-S
  4. F. J. Navarro, P. Partal, F. Martinez-Boza, C. Valencia, and C. Gallegos, 'Rheological Characteristics of Ground Tire Rubber-Modified Bitumens', Chemical Engineering Journal, 89, 53 (2002) https://doi.org/10.1016/S1385-8947(02)00023-2
  5. F. C. Miknis and L. C. Michon, 'Some Applications of Nuclear Magnetic Resonance Imaging to Crumb Rubber Modified Asphalts', Fuel, 77, 393 (1998)
  6. G. Kraus, 'Modification of Asphalt by Block Polymers of Butadiene and Styrene', Rubber Chem. Technol., 55, 1389 (1982)
  7. M. G. Bouldin, J. H. Collins, and A. Berker, 'Rheology and Microstructure of Polymer/Asphalt Blend', Rubber Chem. Technol., 64, 577 (1991)
  8. L. H. Lewandowski, 'Polymer Modification of Paving Asphalt Binders', Rubber Chem. Technol., 67, 447 (1994)
  9. Z. Liang and S. A. M. Hesp, 'In Situ Steric Stabilization of Polyethylene Emulsions in Asphalt Binders for Hot-Mix Pavement Applications', Colloids and Surfaces A: Physicochemical and Engineering Aspects, 81, 239 (1993) https://doi.org/10.1016/0927-7757(93)80251-9
  10. 김 제훈, 'LDPE를 이용한 아스팔트 실란트의 성능개선', Thesis, Kunsan National University, 2001
  11. S. Hinislioglu and E. Agar, 'Use of Waste High Density Polyethylene as Bitumen Modifier in Asphalt Concrete Mix', Materials Letters, 58, 267 (2004) https://doi.org/10.1016/S0167-577X(03)00458-0
  12. C. Giavarini, F. De Fillipis, M. L. Santarelli, and M. Scarsella, 'Production of Stable Polypropylene Modified Bitumens', Fuel, 75, 681 (1996) https://doi.org/10.1016/0016-2361(95)00312-6
  13. A. Kellomaki and M. Korhonen, 'Dispersion of Polyolefins in Bitumen by Means of Tall Oil Pitch, and Microscopic Characterization of Mixes', Fuel, 75, 896 (1996) https://doi.org/10.1016/0016-2361(96)00007-5
  14. M. Korhonen and A. Kellomaki, 'Miscibilities of Polymers in Bitumen and Tall Oil Pitch under Different Mixing Conditions', Fuel, 75, 1727 (1996) https://doi.org/10.1016/S0016-2361(96)00160-3
  15. G. Biegenzein, US Patent 4314921 (1982)
  16. J. Stastana, L. Zanzotto, and O. J. Vacin, 'Viscosity Function in Polymer-Modified Asphalts', Journal of Colloid and Interface Science, 259, 200 (2003) https://doi.org/10.1016/S0021-9797(02)00197-2
  17. M. Garcia-Morales, P. Partal, F. J. Navarro, F. Martinez-Boza, C. Gallegos, N. Gonzalez, and M. E. Munoz, 'Viscous Properties and Microstructure of Recycled EVA Modified Bitumen, Fuel, 83, 31 (2004) https://doi.org/10.1016/S0016-2361(03)00217-5
  18. H. Jin, G. Gao, Y. Zhang, Y. Zhang, K. Sun, and Y. Fan, 'Improved Properties of Polystyrene-Modified Asphalt Through Dynamic Vulcanization', Polymer Testing, 21, 633 (2002) https://doi.org/10.1016/S0142-9418(01)00135-0
  19. Y. Ruan, R. R. Davison, and C. J. Glover, 'The Effect of Long-term Oxidation on the Rheological Properties of Polymer Modified Asphalts', Fuel, 82, 1763 (2003) https://doi.org/10.1016/S0016-2361(03)00144-3
  20. U. Isacsson and H. Zeng, 'Relationships Between Bitumen Chemistry and Low Temperature Behaviour of Asphalt', Construction and Building Materials, 11, 83 (1997) https://doi.org/10.1016/S0950-0618(97)00008-1
  21. R. Varma, H. Takeichi, J. E. Hall, Y. F. Ozawa, and T. Kyu, 'Miscibility Studies on Blends of Kraton Block Copolymer and Asphalt', Polymer, 43, 4667 (2002) https://doi.org/10.1016/S0032-3861(02)00303-8
  22. A. A. Yousefi, A. Ait-Kadi, and C. Roy, 'Effect of Used-Tire-Derived Pyrolytic Oil Residue on the Properties of Polymer-Modified Asphalts', Fuel, 79, 975 (2000) https://doi.org/10.1016/S0016-2361(99)00216-1
  23. G. Wen, Y. Zhang, Y. Zhang, K. Sun, and Y. Fan, 'Rheological Characterization of Storage-Stable SBS Modified Asphalts', Polymer Testing, 21, 295 (2002) https://doi.org/10.1016/S0142-9418(01)00086-1
  24. A, Jimenez, L. Torre, and J. M. Kenny, 'Thermal Degradation of Poly(vinyl chloride) Plastisols Based on Low-migration Polymeric Plasticizers', Polymer Degradation and Stability, 73, 447 (2001) https://doi.org/10.1016/S0141-3910(01)00128-8
  25. N. I. Sax and R. J. Lewis, Sr., 'Hawley's Condensed Chemical Dictionary', 11th ed., p. 393, Van Nostrand Reinhold, New York, 1987