Korean Journal of Environmental Agriculture (한국환경농학회지)

The Korean Society of Environmental Agriculture (한국환경농학회)
권호 표지
DOI QR코드

DOI QR Code

Residual Pattern of Procymidone and Chlorothalonil in Grape During the Period of Cultivation and Storage

포도의 재배 및 저장기간 중의 Procymidone 및 Chlorothalonil의 잔류량변화

  • Ko, Kwang-Yong (Dept. of Agriculture Chemistry, Chungnam National University) ;
  • Kim, Kum-Hee (Micro Pollutant Research Division, National Institute of Environmental Research, Environmental Research Complex) ;
  • Lee, Kyu-Seung (Dept. of Agriculture Chemistry, Chungnam National University)
  • 고광용 (충남대학교 농업생명과학대학 농화학과) ;
  • 김금희 (국립환경연구원 미량물질과) ;
  • 이규승 (충남대학교 농업생명과학대학 농화학과)
  • Published : 2004.03.31
Download PDF
⟨ Previous Next ⟩

Abstract

In order to know the residual pattern of pesticides and predict to the degradation period until below MRL we experimented procymidone and chlorothalonil for grape which were the most detected pesticide in grape by NAQS(National Agricultural product Quality management Service) survey. In this experiment we sprayed those pesticides 10 days before harvest and analyzed 0, 1, 2, 3, 5, 7, 10 day sample to establish logical equation and to calculate $DT_{50}$. Also the same day samples stored at $4^{\circ}C$ and $20^{\circ}C$, which were compared their degradation patterns. During the cultivating period, the residue amount of procymidone was changed from 1.85 mg/kg (0 day) to 0.33 mg/kg (10 day), $DT_{50}$ was 3.5 days, and chlorothalonil was changed from 5.5 mg/kg (0 day) to 3.49 mg/kg (10 day), $DT_{50}$ was 4.4 days. During the storage period, $DT_{50}$ of procymidone and chlorothalonil at $4^{\circ}C$ were 10.5 and 7.6 days, and 6.3 and 6.1 days at $20^{\circ}C$, respectively.

Keywords

References

  1. 국립농산물품질관리원 (2001) 2001 농산물 안정성조사 추진계획
  2. 국립농산물품질관리원 (2000) 2000 농산물 안정성조사 추진계획
  3. Kim, Y. S., Park, J. H , Park, J. W., Lee, Y. D., Lee, K. S. and Kim, J. E. (2002) Persistence and dislodgeabIe of chlorpyrifos and procymidone in lettuce leaves under greenhouse condition, Kor. J. Environ. Agric. 21(2), 149-155 https://doi.org/10.5338/KJEA.2002.21.2.149
  4. 보건복지부 (1998) 국내 농산물 중 잔류 허용기준
  5. 농약 공업 협회 (2000) 농약사용지침서
  6. 식품의약품안전청 (2001) 식품의 기분 및 규격중개정
  7. The pesticide manual 12th edition (1999) British crop protection council
  8. 식품의약품안전청 (2000) 식품공전
  9. 농촌진흥청 농약연구소 (1992) 농약 준류성 시험법
  10. Goto, S and Kato, S. (1987) 殘留農藥分析法.
  11. Lee, k. b., Cho, I. K., Shim, Y. T. (1990) Residue determination of chlorothalonil in sesame and soil, Kor. J. Environ. Agric. 9(1), 15-22
  12. U.S. F.D.A. (1995) Pesticide analytical manual volume 1
  13. 農藥 殘殘分析法 硏究會 (1995) 農藥の 殘溜分析法
  14. Ko, K. Y., Lee, Y. J., Won, D. J., Park, H. J. and Lee, K. S. (2003) Residual pattern of procymidone and bifenthrin in perilla leaf during the period of cultivation and storage, Kor. J. Environ. Agric. 22(1), 47-52 https://doi.org/10.5338/KJEA.2003.22.1.047
  15. Brouwer. D. H. (1997) Half-lives of pesticides on green-house crops， Bulletin of Environmen Contamination Toxicology 58, 976-984 https://doi.org/10.1007/s001289900430
  16. Cabras P. (2000) Pesticide in grapes, wine, and their processing products, J. of Agric. Food Chem. 48, 967- 973 https://doi.org/10.1021/jf990727a
  17. Walter J. Krol, (2000) Reduction of pesticide residues on produce by rinsing J. of Agric. Food Chem. 48, 4666-4670 https://doi.org/10.1021/jf0002894
  18. Cabras P. (2000) Distribution of Folpet on the Grape Surface after Treatment, J. of Agric. Food Chem. 48, 915-916 https://doi.org/10.1021/jf990069u
  19. Cabras P. (1997) Residues of some pesticides in fresh and dried apricots, J. of Agric. Food Chem. 45, 3221-3222 https://doi.org/10.1021/jf970101p
  20. Jose, C (2000) Residue level, decline curves, and plantation distribution of procymidone in green beans grown in greenhouse, J. of Agric. Food Chem. 48, 2991-2994 https://doi.org/10.1021/jf990770y
  21. Lee, Y. J., Ko, K. Y., Won, D. J., Gil, G. H. and Lee, K. S. (2003) Residual patterns of procymidone, chlorpyrifos and cypermethrin in peaches during cultivation and storage period, Kor. J. Environ. Agric. 22(3), 220-226 https://doi.org/10.5338/KJEA.2003.22.3.220
  22. Lee, K. S. (1997) Evaluation on the effects of pesticide residues to agroecosystem in Korea, Kor. J. Environ. Agric. 16(1), 80-83
  23. Ko, K. Y. (2002) Residual pattern of some pesticides in perilla leaf and grape during the period of cultivation and storage, Degree of master thesis, Chungnam National University
  24. Cabras P. (1998) Pesticide residues in raisin processing, J. of Agric. Food Chem. 46, 2309-2311 https://doi.org/10.1021/jf980058l
  25. Moon, J. K, Park, H. W., Choi, H, Hang Y. S., Liu, K. H, Lee, Y. H , Lee, K. S. and Kim, J. H (2003) Residue pattern of fenitrothion in grapes, J. Kor. Soc. Hart. Sci. 44(4), 497-502

Cited by

  1. Establishment of Pre-Harvest Residue Limit of Fungicides Pyrimethanil and Trifloxystrobin during Cultivation of Persimmon vol.31, pp.1, 2012, https://doi.org/10.5338/KJEA.2012.31.1.45
  2. Dissipation Pattern of Amisulbrom in Cucumber under Greenhouse Condition for Establishing Pre-harvest Residue Limit vol.16, pp.4, 2012, https://doi.org/10.7585/kjps.2012.16.4.288
  3. Dissipation Patterns of Triazole Fungicides Estimated from Kinetic Models in Apple vol.55, pp.4, 2012, https://doi.org/10.3839/jabc.2012.037
  4. Residual Characteristics of Bistrifluron and Fluopicolide in Korean Cabbage for Establishing Pre-Harvest Residue Limit vol.19, pp.4, 2015, https://doi.org/10.7585/kjps.2015.19.4.361
  5. Establishment of Pre-Harvest Residue Limits of Clothianidin and Thiacloprid in Ginseng vol.17, pp.3, 2013, https://doi.org/10.7585/kjps.2013.17.3.155
  6. Residual Characteristics of Insecticides Used for Oriental Tobacco Budworm Control of Paprika vol.32, pp.1, 2013, https://doi.org/10.5338/KJEA.2013.32.1.84
  7. Establishment of Pre-Harvest Residue Limit (PHRL) of Fungicides Azoxystrobin and Difenoconazole on Prunus mume fruits vol.17, pp.4, 2013, https://doi.org/10.7585/kjps.2013.17.4.307
  8. Monitoring and Risk Assessment of Pesticide Residues in Commercial Environment-Friendly Agricultural Products Distributed Using LC-MS/MS in Seoul Metropolitan Area vol.47, pp.3, 2015, https://doi.org/10.9721/KJFST.2015.47.3.306
  9. Translocation of Residual Azoxystrobin from Soil to Korean Cabbage vol.21, pp.4, 2017, https://doi.org/10.7585/kjps.2017.21.4.427