ETRI Journal

  • 제26권6호
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  • Pages.647-652
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  • 2004
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  • 1225-6463(pISSN)
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  • 2233-7326(eISSN)
한국전자통신연구원 (Electronics and Telecommunications Research Institute)
권호 표지

A New Ionic Liquid for a Redox Electrolyte of Dye-Sensitized Solar Cells

  • 투고 : 2003.12.29
  • 발행 : 2004.12.31
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초록

A new ionic liquid, 1-vinyl-3-heptylimidazolium iodide (VHpII), was synthesized and applied as a redox electrolyte for dye-sensitized solar cells. The chemical structure of the synthesized VHpII was confirmed using $^1H$ NMR. Thermogravimetric analysis showed that the VHpII was stable for thermal stress of up to $250^{\circ}C$. The energy conversion efficiencies of the VHpII-based dye-sensitized solar cells were investigated in terms of the effect of a lithium iodide addition. A solar cell containing the redox couple of VHpII and iodine showed a conversion efficiency of 2.63% under 1 sun light intensity at AM 1.5. Adding 0.4 M LiI results in a conversion efficiency of 3.63%, which was an improvement of about 40%. The increased conversion efficiency was ascribed to an increase in external quantum efficiency.

키워드

참고문헌

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