Bulletin of the Korean Chemical Society

  • 제25권8호
  • /
  • Pages.1130-1132
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Photodissociation Dynamics of tert-Butyl Isocyanide at 193 nm

  • Kang, Tae-Yeon (Department of Chemistry and Basic Science Research Institute, Kangwon National University) ;
  • Shin, Seung-Keun (Department of Chemistry and Basic Science Research Institute, Kangwon National University) ;
  • Kim, Hong-Lae (Department of Chemistry and Basic Science Research Institute, Kangwon National University)
  • 발행 : 2004.08.20
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초록

Photodissociation dynamics of tert-butyl isocyanide at 193 nm has been investigated by measuring rotationally resolved laser induced fluorescence spectra of CN fragments that were exclusively produced in the ground electronic state. From the spectra, internal energies of CN and translational energy releases in the products were obtained. The dissociation takes place in the excited triplet states which are strongly repulsive along the dissociation coordinate via curve crossing from the initially prepared state.

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참고문헌

  1. Robinson, P. J.; Holbrook, K. A. Unimolecular Reactions; Wiley:New York, U.S.A., 1972.
  2. Ashfold, M. N. R.; Simons, J. P. J. Chem. Soc. Faraday Trans. II1978, 174, 1263.
  3. Kang, T. Y.; Choi, H. S.; Shin, S. K.; Kim, H. L. J. Phys. Chem. Asubmitted for publication.
  4. Park, J.; Yu, C.-F.; Bersohn, R. Chem. Phys. 1989, 134, 421. https://doi.org/10.1016/0301-0104(89)87172-1
  5. Engleman, Jr. R. J. Mol. Spectrosc. 1974, 49, 206.
  6. Earls, L. T. Phys. Rev. 1935, 48, 423. https://doi.org/10.1103/PhysRev.48.423
  7. Nicholls, R. W. J. Res. Natl. Bur. Stand. 1964, 684, 75.
  8. Ha, T.-K. J. Mol. Struct. 1972, 11, 185. https://doi.org/10.1016/0022-2860(72)80003-6
  9. Seakins, P. W.; Pilling, M. J.; Niiranen, J. T.; Gutman, D.;Krasnoperov, L. N. J. Phys. Chem. 1992, 96, 9847. https://doi.org/10.1021/j100203a050
  10. Berkowitz,J.; Ellison, G. B.; Gutman, D. J. Phys. Chem. 1994, 98, 2744. https://doi.org/10.1021/j100062a009
  11. Halpern, J. B.; Jackson, W. M. J. Phys. Chem. 1982, 86, 3528. https://doi.org/10.1021/j100215a009
  12. Lu, R.; McCray, V.; Halpern, J. B.; Jackson, W. M. J. Phys. Chem.1984, 88, 3419. https://doi.org/10.1021/j150660a011
  13. Barts, S. A.; Halpern, J. B. J. Phys. Chem. 1989, 93, 7346. https://doi.org/10.1021/j100358a018

피인용 문헌

  1. Photodissociation Dynamics of Formic Acid at 206 nm vol.27, pp.12, 2004, https://doi.org/10.5012/bkcs.2006.27.12.1997
  2. Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007 vol.29, pp.2, 2008, https://doi.org/10.5012/bkcs.2008.29.2.450