Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Concomitant Addition and Acetalization of α,β-Unsaturated Aldehydes with Diols

  • Jeon, Kyu-Ok (Department of Chemistry, Kangwon National University) ;
  • Yu, Ji-Sook (Department of Chemistry, Kangwon National University) ;
  • Lee, Chang-Kiu (Department of Chemistry, Kangwon National University)
  • Published : 2004.11.20
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Abstract

${\alpha},{\beta}$-Unsaturated aldehydes such as acrolein and crotonaldehyde were reacted with diols in the presence of conc. sulfuric acid to give products of which concomitant addition to C-C double bond and acetalization took place. Boron trifluoride etherate and titanium tetrachloride gave only acetalization products.

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References

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  1. Concomitant Addition and Acetalization of ?,?-Unsaturated Aldehydes with Diols. vol.36, pp.13, 2005, https://doi.org/10.1002/chin.200513065