Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Syndiotactic Polymerization of Amino-functionalized Styrenes Using (Pentamethylcyclopentadienyl)titanatrane/MMAO Catalyst System

  • Kim, Young-Jo (Performance Polymers Research Institute, LG Chem., Ltd.) ;
  • Park, Sung-Jin (Department of Chemistry, School of Molecular Science-BK21 and Center for Molecular Design and Synthesis, Korea Advanced Institute of Science and Technology) ;
  • Han, Yong-Gyu (Department of Chemistry, School of Molecular Science-BK21 and Center for Molecular Design and Synthesis, Korea Advanced Institute of Science and Technology) ;
  • Do, Young-Kyu (Department of Chemistry, School of Molecular Science-BK21 and Center for Molecular Design and Synthesis, Korea Advanced Institute of Science and Technology)
  • Published : 2004.11.20
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Abstract

A set of unprecedented syndiospecific dimethyl- and diethylamino-functionalized polystyrenes was prepared by catalytically polymerizing the corresponding monomers using (pentamethylcyclopentadienyl)titanatrane/MMAO catalytic system. Dialkylamino-functionalized styrene monomers were synthesized by Wittig reaction from the corresponding aldehyde in high yield. The resulting polymers are soluble in polar organic solvents such as THF and show good thermal stability. The chemical transformation of the syndiospecific poly(4-diethylaminostyrene) also gave new polar polymers, namely syndiotactic poly(4-diethylaminostyrene hydrochloride), which is unattainable by traditional synthetic methods.

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References

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