Bulletin of the Korean Chemical Society

  • 제25권8호
  • /
  • Pages.1207-1210
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis and Characterization of the Thermally Stable Ho(hfa)3(tme)

  • Kang, Seong-Joo (Department of Chemistry Education, Korea National University of Education)
  • 발행 : 2004.08.20
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초록

Holmium $\beta$ -diketonate complexes, Ho(hfa)$_3$(tme), has been prepared and characterized by IR, TGA, MS, and single-crystal X-ray analyses. This complex is air- and moisture-stable and most importantly has good volatility and thermal stability. Holmium atom binds to nine oxygen atoms, contributed by six oxygen atoms of three hfa ligands and three oxygen atoms of the tme ligand. The coordination polyhedron of Ho can be described as a distorted tricapped trigonal prism. Crystal data for $Ho(hfa)_3(tme)$; orthorhombic $P2_12_12_1$, a = 15.415(4), b = 13.17(2), c = 17.291(3) $\AA$, V = 3496(1) ${\AA}^3$.

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참고문헌

  1. Drake, S. R.; Hursthouse, M. B.; Malik, K. M. A.; Miller, S. A. S.;Otway, D. J. Inorg. Chem. 1993, 32, 4464. https://doi.org/10.1021/ic00072a048
  2. Drake, R.; Lyons, A. L.; Otway, D. J.; Slawin, A. M. Z.; Williams,D. J. J. Chem. Soc., Dalton Trans. 1993, 2379.
  3. Gleizes, A.; Lenain, S.; Medus, D.; Hovnanian, N.; Miele, D.;Foulon, J.-D. Inorg. Chim. Acta 1993, 209, 47. https://doi.org/10.1016/S0020-1693(00)84979-8
  4. Kang, S.-J.; Jung, Y. S.; Sohn, Y. S. Bull. Korean Chem. Soc.1997, 18, 75. https://doi.org/10.1007/BF02707201
  5. Kang, S.-J.; Jung, Y. S.; Suh, I.-L. Bull. Korean Chem. Soc. 1999,20, 95.
  6. Kang, S.-J.; Lee, S. K. Bull. Korean Chem. Soc. 2003, 24, 535. https://doi.org/10.5012/bkcs.2003.24.5.535
  7. Dale, J.; Fredriksen, S. B. Acta Chem. Scand. 1992, 46, 271. https://doi.org/10.3891/acta.chem.scand.46-0271
  8. Sheldrick, G. M. In SHELXS-86, A Program for StructureDetermination; University of Gottingen: Germany, 1986.
  9. Sheldrick, G. M. In SHELXL-93, A Program for StructureRefinement; University of Gottingen: Germany, 1993.
  10. Abrahams, S. C.; Ginsberg, A. P.; Knox, K. Inorg. Chem. 1964, 3,558. https://doi.org/10.1021/ic50014a026
  11. Santos, P. C.; Nogueira, H. I.; Paz, F. A.; Ferreira, R. A.; Carlos,L. D.; Klinowski, J.; Trindade, T. Eur. J. Inorg. Chem. 2003,3609.
  12. Kim, S.-J.; Park, S.; Yim, S. Bull. Korean Chem. Soc. 2004, 25,485. https://doi.org/10.5012/bkcs.2004.25.4.485

피인용 문헌

  1. Syntheses and Characterization of the Thermally Stable Cu(hexafluoroacetylacetonato)2(μ-diethyl 2-allylmalonate) vol.26, pp.11, 2004, https://doi.org/10.5012/bkcs.2005.26.11.1846