Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Shock Tube and Modeling Study of the Monomethylamine Oxidation at High Temperature

  • Published : 2004.02.20
Download PDF
⟨ Previous Next ⟩

Abstract

The ignition of monomethylamine was studied in reflected shock waves over the temperature range of 1255- 1579 K and the pressure range of 1.04-1.51 bar. The ignition delay time was measured by the sudden increase of pressure profile and the radiation emitted by OH radicals. The relationship between the ignition delay time and the concentrations of monomethylamine and oxygen was determined in the form of mass-action expressions with an Arrhenius temperature dependence. In contrast to the behavior observed in hydrocarbons, monomethylamine acts to accelerate rather than inhibit its own ignition. And numerical modeling of the ignition of $CH_3NH_2$ has also been carried out to test the several kinetic mechanisms.

Keywords

References

  1. Zeldovich, Y. B. Acta Physicochimica U.R.S.S. 1946, 21, 577.
  2. Fenimore, C. P. Combustion and Flame 1976, 26, 249. https://doi.org/10.1016/0010-2180(76)90075-4
  3. Wolfrum, J. Chemie Ingenieur Technik 1972, 44, 656. https://doi.org/10.1002/cite.330441004
  4. Malte, P. C.; Pratt, D. T. Combust. Sci. Tech. 1974, 9, 221. https://doi.org/10.1080/00102207408960360
  5. Bozzelli, J. W.; Dean, A. M. Int. J. Chem. Kinet. 1995, 27, 1097. https://doi.org/10.1002/kin.550271107
  6. Miller, J. A.; Branch, M. C.; Kee, R. J. Combustion and Flame1981, 43, 81. https://doi.org/10.1016/0010-2180(81)90008-0
  7. Arand, J. K.; Muzio, L. J.; Sotter, J. G. U. S. Patent 4 1982, 208, 386.
  8. Carton, J. A.; Siebers, D. L. ASME J. Fluids Eng. 1989, 111, 387.
  9. Yoshihara, Y.; Ikegami, M.; Mine, N. Trans. Japan Soc. Mech.Eng., Series B 1990, 56, 845.
  10. Yoshihara, Y.; Tanaka, T. Trans. Japan Soc. Mech. Eng. Series B1995, 61, 408.
  11. Miller, J. A.; Bowman, C. T. Prog. Energy Combust. Sci. 1989, 15,287. https://doi.org/10.1016/0360-1285(89)90017-8
  12. Higashihara, T.; Gardiner, W. C., Jr.; Hwang, S. M. J. Phys. Chem.1987, 91, 1900. https://doi.org/10.1021/j100291a044
  13. Klatt, M.; Spindler, B.; Wagner, H. Gg. Z. Phys. Chem. 1995, 191,241. https://doi.org/10.1524/zpch.1995.191.Part_2.241
  14. Votsmeier, M.; Song, S.; Davidson, D. F.; Hanson, R. K. Int. J.Chem. Kinet. 1999, 31, 323. https://doi.org/10.1002/(SICI)1097-4601(1999)31:5<323::AID-KIN1>3.0.CO;2-X
  15. Hwang, S. M.; Higashihara, T.; Shin, K. S.; Gardiner, W. C., Jr. J.Phys. Chem. 1990, 94, 2883. https://doi.org/10.1021/j100370a029
  16. Lifshitz, A.; Bidani, M.; Carroll, H. F.; Hwang, S. M.; Fu, P. Y.;Shin, K. S.; Gardiner, W. C., Jr. Combustion and Flame 1991, 86,229. https://doi.org/10.1016/0010-2180(91)90103-I
  17. Kantak, M. V.; Manrique, K. S. De.; Aglave, R. H.; Hesketh, R. P.Combustion and Flame 1997, 108, 235. https://doi.org/10.1016/S0010-2180(96)00122-8
  18. GRI-Mechanism 3.0 is available by World Wide Web using thehttp://euler.berkeley.edu/gri_mech/version30/text30.html/, 1999.
  19. Coda Zabetta, E.; Kilpinen, P.; Hupa, M.; Stahl, K.; Leppalahti, J.;Cannon, M.; Nieminen, J. Energy & Fuels 2000, 14, 751. https://doi.org/10.1021/ef9901591
  20. Dean, A. M.; Bozzelli, J. W. In Gas-Phase Combustion Chemistry;Gardiner, W. C., Jr., Ed.; Springer-Verlag: New York, 2000; p 125.
  21. Kee, R. J.; Rupley, F. M.; Miller, J. A. The Chemkin ThermodynamicDate base Sandia National Laboratories Report SAND87-8215B;1990.
  22. Kee, R. J.; Rupley, F. M.; Meeks, E.; Miller, J. A. Chemkin-III; AFortran Chemical Kinetics Package for the Analysis of Gas-PhaseChemical and Plasma Kinetics, Sandia National LaboratoriesReport SAND96-8216; 1996.
  23. Lutz, A. E.; Kee, R. J.; Miller, J. A. Sandia National LaboratorisReport NO. SAND87-8248; 1991.
  24. Jee, S. B.; Kim, W. K.; Shin, K. S. J. Korean Chem. Soc. 1999, 43,156.
  25. Jee, S. B.; Kim, K. Y.; Shin, K. S. Bull. Korean Chem. Soc. 2000,21, 1015. https://doi.org/10.1007/BF02705587
  26. Kim, W. K.; Shin, K. S. J. Korean Chem, Soc. 1997, 41, 600.
  27. Tsang, W.; Lifshitz, A. Annual Review of Physical Chemistry1990, 41, 559. https://doi.org/10.1146/annurev.pc.41.100190.003015
  28. Jee, S. B.; Kim, W. K.; Shin, K. S. J. Korean Chem. Soc. 1999, 43,156.
  29. Shim, S. B.; Jeong, S. H.; Shin, K. S. J. Korean Chem. Soc. 1998,42, 575.
  30. Kim, K. Y.; Shin, K. S. Bull. Korean Chem. Soc. 2001, 22, 303.
  31. Lissianski, V. V.; Zamansky, V. M.; Gardiner, W. C., Jr. In Gas-Phase Combustion Chemistry; Gardiner, W. C., Jr., Ed.; Springer-Verlag: New York, 2000; p 1.

Cited by

  1. The Inhibition Effect of Fe(CO)5 on the Ignition of Ethane vol.25, pp.5, 2004, https://doi.org/10.5012/bkcs.2004.25.5.745
  2. Physical Chemistry Research Articles Published in the Bulletin of the Korean Chemical Society: 2003-2007 vol.29, pp.2, 2008, https://doi.org/10.5012/bkcs.2008.29.2.450
  3. An experimental and kinetic modeling study of premixed NH3/CH4/O2/Ar flames at low pressure vol.156, pp.7, 2004, https://doi.org/10.1016/j.combustflame.2009.03.005
  4. Shock-Tube Experiments and Chemical Kinetic Modeling Study of CH4 Sensitized by CH3NHCH3 vol.32, pp.4, 2004, https://doi.org/10.1021/acs.energyfuels.8b00860