Bulletin of the Korean Chemical Society

  • 제25권8호
  • /
  • Pages.1151-1155
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Visual Detection of Di-and Tri-phosphates in Aqueous Solution of Neutral pH

  • Han, Min-Su (Center for Integrated Molecular Systems and Department of Chemistry, Divisioin of Molecular and Life Sciences, Pohang University of Science and Technology) ;
  • Kim, Dong H. (Center for Integrated Molecular Systems and Department of Chemistry, Divisioin of Molecular and Life Sciences, Pohang University of Science and Technology)
  • 발행 : 2004.08.20
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초록

The chemosenssor that consists of [$Zn_2$(1,3-bis[bis(2-pyridylmethyl)aminomethyl]benzene)]$^{4+}$ (receptor) and pyrecatechol violet (signaling unit) detects with naked eyes di- and tri-phosphates conjugated to nucleosides or in free forms. The blue color of the aqueous solution (pH 7.0) of the sensor turns to yellow upon exposing to the analytes.

키워드

참고문헌

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  4. The selectivity of water-based pyrophosphate recognition is tuned by metal substitution in dimetallic receptors vol.44, pp.26, 2015, https://doi.org/10.1039/C5DT00729A
  5. Metal complexation chemistry used for phosphate and nucleotide determination: an investigation of the Yb3+–pyrocatechol violet sensor vol.13, pp.8, 2008, https://doi.org/10.1007/s00775-008-0415-2
  6. Reversible Coordinative Bonds in Molecular Recognition vol.106, pp.9, 2004, https://doi.org/10.1021/cr010206y
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  8. Complexation of bisphosphonates with ytterbium(III): Application of phosphate and ATP detection assay based on Yb3+–pyrocatechol violet vol.103, pp.12, 2004, https://doi.org/10.1016/j.jinorgbio.2009.09.006
  9. Selective sensing of ATP by hydroxide-bridged dizinc(II) complexes offering a hydrogen bonding cavity vol.48, pp.39, 2004, https://doi.org/10.1039/c9dt02404b