Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Turbidimetric Measurement for On-line Monitoring of SiO2 Particles

  • Kim, In-Sook (Department of Chemistry and NSBT, Dankook University) ;
  • Kim, Yang-Sun (Proteonik, Inc., Gyeonggi Technopark) ;
  • Lim, H.B. (Department of Chemistry and NSBT, Dankook University)
  • Published : 2004.06.20
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Abstract

In this work, the fundamental study of on-line monitoring of $SiO_2$ particles in the size range of 40 nm to 725 nm was carried out using turbidimetry. The size of particle was measured using a field emission scanning electron microscope (FE-SEM). The factors affecting on the turbidity were discussed, for example, wavelength, size, and concentration. In order to observe the dependence of turbidity on the wavelength, a turbidimetric system equipped with charged coupled detector (CCD) was built. The shape of the transmitted peak was changed and the peak maximum was shifted to the red when the concentration of particle was increased. This result indicates that the turbidity is related to the wavelength, which corresponds to the characteristic of the Mie extinction coefficient, Q, that is a function of not only particle diameter and refractive index but also wavelength. It is clear that a linear calibration curve for each particle in different size can be obtained at an optimized wavelength.

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