DOI QR코드

DOI QR Code

Photoluminescence Characteristics Y2O3:Eu3+ Thin Film Grown on Al2O3(0001) Substrate by PLD

PLD 방법으로 Al2O3(0001) 기판 위에 증착한 Y2O3:Eu3+ 박막의 형광 특성

  • 이성수 (신라대학교 광전자공학과)
  • Published : 2004.05.31

Abstract

$Y_{2}O_{3}:Eu^{3+}$ thin films have been grown on $Al_{2}O_{3}$(0001) substrates by a pulsed laser deposition (PLD) method. The phosphor thin films were deposited at a substrate temperature of 500, 600, and $700^{\circ}C$ under the oxygen pressure of 100, 200, and 300 mTorr. The crystallinity, surface roughness and photoluminescence of the films are highly dependent on the substrate temperature and oxygen pressure. The films grown on $Al_{2}O_{3}$(0001) substrate even under the different substrate temperatures and oxygen pressures exhibited (222) preferred orientation. The luminescent spectra exhibited strong luminescence of ${^{5}D_{0}}-{^{7}F_{2}}$ transition within $Eu^{+3}$ peaking at 612 nm. The crystallinity and luminescence intensity of the films have been improved as the substrate temperature increasing. With increase of oxygen pressure from 50 to 300 mTorr, the crystallinity of the films has been uniformly decreased. The photoluminescence intensity and surface roughness have similar behaviors as a function of oxygen pressure. At 200 mTorr, both photoluminescence intensity and surface roughness show a maximum.

Keywords

References

  1. I. K. Jeong, H. L. Park, and S. I. Mho, 'Photoluminescence of $ZnGa_2O_4$ mixed with $InGaZnO_4$', Solid State Comm., vol. 108, pp. 823, 1998 https://doi.org/10.1016/S0038-1098(98)00456-6
  2. G. A. Hirata, J. Mckillrick, M. Avalos-Borja, J. M.Siqueiros, and D. Devlin, 'Physical properties of $Y_2O_3$:Eu luminescent films grown by MOCVD and laser ablation', Appl. Surf. Sci., vol. 113/114, pp.509, 1997 https://doi.org/10.1016/S0169-4332(96)00829-X
  3. R. N. Shaarma and A. C. Rastogi, 'Compositional and electronic properties of chemical-vapor-depos-ited $Y_2O_2$, thin film-Si(100) interfaces', J. Appl. Phys., vol. 74, pp. 6691, 1993 https://doi.org/10.1063/1.355112
  4. A. Polman, 'Erbium implanted thin film photonic materials', J. Appl. Phys., vol. 82, pp. 1, 1997 https://doi.org/10.1063/1.366265
  5. A. Wickersheim and R. A. Leferver, 'Luminescent Behavior of the Rare Earths in Yttrium Oxide and Related Hosts', J. Etectrochem. Soc., vol. 111, pp.47, 1964 https://doi.org/10.1149/1.2426061
  6. Ravi P. Rao, 'Growth and characterization of $Y_2O_3$:Eu3+ phosphor films by sol-gel process', Solid State Commun., vol. 99, pp. 439, 1996 https://doi.org/10.1016/0038-1098(96)00249-9
  7. R. N. Sharma, S. T. Lakshami, and A. C. Rastogi, 'Electrical behavior of electron-beam-evaporated yttrium oxide thin films on silicon', Thin Solid Films, vol. 199, pp. 1, 1991 https://doi.org/10.1016/0040-6090(91)90045-Y
  8. A. F. Jankowski, L. R. Schrawyer, and J. P. Hayes, 'Sputter deposition of yttrium-oxides', J. Vac. Sci. Technol., vol. A 11, pp. 1548, 1993
  9. K. Onisawa, M. Fuyana, K. Tamura, K. Taguchi, T.Nakayama, and Y. Ono, 'Dielectric properties of rf-sputtered YUO] thin film', J. Appl. Phys., vol. 66, pp. 719, 1990
  10. W. M. Crantom, D. M. Spink, R. Stevens, and C.B. Thomas, 'Growth and dielectric characterization of yttrium oxide thin films deposited on Si by r.f.-magnetron sputtering', Thin Solid Films, vol. 226, pp. 156, 1993 https://doi.org/10.1016/0040-6090(93)90222-B
  11. S. L. Jones, D. Kumar, Rajiv K. Singh, and P. H.Holloway, 'Luminescence of pulsed laser deposited Eu doped yttrium oxide films', Appl. Phys. Lett., vol. 71, pp. 21, 1997
  12. S. S. Yi, J. S. Bae, B. K. Moon, J. H. Jeong, J. C.Park, and I. W. Kim, 'Enhanced luminescence of pulsed-laser-deposited $Y_2O_3$:Eu3+ thin-film phos-phors by Li doping', Appl. Phys. Lett., vol. 18, pp.3344, 2002
  13. Shaoqiang Zhang and Rongfu Xial, 'Yttrium oxided films prepared by pulsed laser deposition', J. Appl. Phys., vol. 83, pp. 3842, 1997
  14. S. Shinoya and W. M. Yen, Phosphor Handbook, CRC Press, New York, 1999

Cited by

  1. Crystal Growth and Luminescence Properties of KCl Doped with Eu2+Ions vol.20, pp.1, 2011, https://doi.org/10.5369/JSST.2011.20.1.30