DOI QR코드

DOI QR Code

Structure and Conductivity Characteristics of Sandwich Structures with Fullerite Films

  • Berdinsky, A.S. (Novosibirsk State Technical University) ;
  • Shevtsov, Yu. V. (Inst. of Inorgarnic Chemistry) ;
  • Chun, Hui-Gon (ReMM, School of Materials Science and Engineering, University of Ulsan) ;
  • Yoo, Yong-Zoo (ReMM, School of Materials Science and Engineering, University of Ulsan) ;
  • Fink, D. (Hahn-Meitner-Institue) ;
  • Ayupov, B.M. (Inst. of Inorgarnic Chemistry)
  • Published : 2004.09.30

Abstract

We report on the technology of formation of sandwich structures based on fullerite films and on experimental results in research of optical and conductivity properties of these sandwich samples. Single crystals of sapphire (100) or silicon were used as substrates. The sandwich specimens were based on the structure M/$C_{60}$/M (M=Cr, Pd, Ag, Al, Cu). The thickness of the fullerite films was about $0.2{\sim}1.0{\mu}m$. The area of the $C_{60}$ film under the top contact was about $1cm^{2}$. The specimens have been investigated by infrared spectroscopy, spectra-photometry, ellipsometry and X-ray diffraction analysis. Measurements of the current/voltage characteristics and research on the temperature dependence of conductivity were performed as well. It was shown that metals such as Cr, Pd, Ag, Al, and Cu penetrate easily into the fullerite films. It appears that these specimens have a large conductivity. For silver/$C_{60}$ and other sandwich structures the conductivities show a semiconductor-like behaviour.

Keywords

References

  1. A. S. Berdinsky, D. Fink, H. G. Chun, and L. T. Chadderton, 'Influence of axial mechanical stress on the conductivity of fullerite power', J. Korea Sensors Society, vol. 13, no. 4, pp. 161-165, 2004
  2. A. S. Berdinsky, H. G. Chun, J. H. Lee, Y. H. Song, and Y. V. Shevtsov 'Gas-phase technology and microstructure of fullerite films', J. Korea Inst. Surface Engineering, vol. 37, no. 2, pp. 71-75, 2004
  3. W. Maser, S. Roth, J. Anders, and J. Reichenbach, et al., 51, pp. 103-108, 1992
  4. A. S. Berdinsky, Y. V. Shevtsov, A. V. Okotrub, Y. A. Yuanovsky, J. H. Lee, and L. T. Chadderton, Ext. Abstr. 24th Biennial Conference on Carbon, vol. 1, pp.296, 1999
  5. N. Ke, W. Y. Cheung, S. P. Wong, and S. Q. Peng, Carbon, vol. 35, no. 6, pp. 759-762, 1997 https://doi.org/10.1016/S0008-6223(97)00032-8
  6. V. A. Chernov, V. N. Ivanova, and A. N. Kozevnikova, et aI., Nucl. Instr. & Meth. Phys. Res. A 359, pp. 250-253, 1995
  7. A. S. Berdinsky, D. Fink, J. B. Yoo, L. T. Chadderton, and H. G. Chun, 'Electronic conduction properties of Au/C60/p-Si and $C_6_0$/Au/p-Si sandwich structures', J. Solid State Communications, vol. 130, pp. 809-814, 2004 https://doi.org/10.1016/j.ssc.2004.03.051
  8. A. F. Hebard, C. B. Eom, Y. Iwasa, and K. B. Lyons et al., Phys. Rev. B, vol. 50, no. 23, pp. 17740-17743, 1994 https://doi.org/10.1103/PhysRevB.50.17740
  9. S. Nolen and S. T. Ruggiero, Chem. Phys. Lett., vol. 300, pp. 656-660, 1999 https://doi.org/10.1016/S0009-2614(98)01442-0
  10. J. Vacik, S. Yamamoto, H. Naramoto, K. Narumi, and K. Miyashita, 18th Fullerene General Symposium, Okazaki, Japan, 2000
  11. O. A. Gudaev, V. K. Malinovskii, B. D. Sanditov, and A. P. Sedelnikov, et aI., Mol. Mat, vol. 7, pp. 203-208, 1996
  12. B. M. Ayupov, Optik, vol. 109, no. 4, pp. 45-149,1998
  13. Bin Ma, M. Milton Alice, and Ya-Ping Sun, Chem. Phys. Lett. vol. 288, pp. 854-860, 1998 https://doi.org/10.1016/S0009-2614(98)00375-3
  14. A. M. Rao, P. C. Eklund, J. L. Hodeau, and L. Marques, Phys. Rev. B, vol. 55, no. 7, pp. 4766-4773