Korean Journal of Soil Science and Fertilizer (한국토양비료학회지)

Korean Society of Soil Science and Fertilizer (한국토양비료학회)
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Effects of pH and the Existence of CO2 Gas on the Silica Surface Characteristics at Silica/Pb(II) Solution Interface

CO2 가스의 존재 여부와 용액의 pH가 Silica/Pb(II) 용액 계면에서 Silica 표면의 특성에 미치는 영향

  • Lee, Sang-Eun (Department of Plant Resources Science, Hankyong National University)
  • 이상은 (한경대학교 식물자원과학과)
  • Received : 2003.08.18
  • Accepted : 2003.10.07
  • Published : 2003.10.30
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Abstract

Effects of the existence of $CO_2$ gas and pH on the silica surface characteristics at silica/Pb(II) and sodium dodecyl sulfonate (SDS, $C_{12}H_{25}SO_3Na$) solution interface were studied. The hydrophobic characteristics of silica surface was delineated by contact angle measurement and surface force measurement using atomic force microscopy (AFM). In $CO_2$ free condition provided by purging $N_2$ gas, the contact angle of fused silica surface in $10^{-4}M$ Pb(II) and SDS solution increased greatly up to $90^{\circ}$ compared with $40^{\circ}$ in atmospheric condition. It was due to the precipitation of $PbCO_3$ in atmospheric condition. In $CO_2$ free condition the change of contact angle and adhesion force ($F_{ad}$) in AFM, affected by pH change, was similar to the distribution of $PbOH^+$ ion in speciation diagram corresponding to $10^{-4}M$ total Pb(II). Therefore, it was convinced that the $PbOH^+$ ion among Pb(II) species would be the main adsorbing type on silica surface. Both of contact angle measurement and surface force measurement using AFM showed that the Pb only treatment made the silica surface hydrophobic. However, it could not be explained theoretically by current knowledge, and required further study in atomic level to solve the problem.

$CO_2$ 가스 존재여부와 pH가 Pb(II)와 sodium dodecyl sulfonate(SDS, $C_{12}H_{25}SO_3Na$) 흡착에 따른 silca 표면의 특성 변화에 미치는 영향을 contact angle 과 AFM을 이용한 힘 측정을 통하여 살펴보았다. 대기와 접촉하여 $CO_2$가 용해되는 조건에서 Pb와 SDS가 $10^{-4}M$ 씩 들어 있는 혼합용액을 처리하였을 때, fused silica 표면의 contact angle은 $PbCO_3$의 침전 때문에 최대 $46^{\circ}$로 낮았다. 반면에 $N_2$ 개스를 불어넣는 $CO_2$ 부재조건에서는 $PbCO_3$의 침전이 없었기 때문에 contact angle이 최대 $90^{\circ}$로 크게 증가되었다. $CO_2$ 부재조건에서 pH에 따른 contact angle과 AFM에서 측정한 점착력($F_{ad}$) 변화 양상은 $PbOH^+$ 화학종 분포와 유사하였으므로, Pb(II)의 silica 표면 흡착형태는 $PbOH^+$ 로 판단되었다. 한편 contact angle 과 AFM 측정결과 모두 Pb 단독처리에서 소수성을 발현하였다. 이 결과는 현재까지의 알려진 이론으로 설명할 수 없었으며 이를 위하여 원자수준에서의 심도 깊은 연구가 필요하다고 판단되었다.

Keywords

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