Pyrazoline 유도체의 합성과 분광특성

Synthesis and Photoluminescence of Pyrazoline Derivative

  • 이문학 (부경대학교 대학원 인쇄공학과) ;
  • 강동은 (부경대학교 대학원 인쇄공학과) ;
  • 유정이 (부경대학교 대학원 인쇄공학과) ;
  • 이태훈 (부경대학교 대학원 인쇄공학과) ;
  • 김성빈 (부경대학교 공과대학 화상정보공학부) ;
  • 손세모 (부경대학교 공과대학 화상정보공학부)
  • Lee, Mun-Hag (Dept. of Graphic Arts Engineering, Graduate School of Pukyong National University) ;
  • Kang, Dong-Eun (Dept. of Graphic Arts Engineering, Graduate School of Pukyong National University) ;
  • Yu, Jung-Yi (Dept. of Graphic Arts Engineering, Graduate School of Pukyong National University) ;
  • Lee, Tae-Hoon (Dept. of Graphic Arts Engineering, Graduate School of Pukyong National University) ;
  • Kim, Sung-Bin (Division of Image & Information, Collage of Engineering, Pukyong National University) ;
  • Son, Se-Mo (Division of Image & Information, Collage of Engineering, Pukyong National University)
  • 발행 : 2003.07.01

초록

We synthesised 1,3-Diphenyl-5-pyren-2-yl-4,5-dihydro-1H-pyrazole(DPP) and investigated its optical properties. The structure of DPP was confirmed by GC-Mass and elemental analysis. The absorption and photoluminescent spectra of DPP were measured at both hydrophobic and hydrophilic solvents and by the stokes shifts of DPP Lippert's equation could be applied. The results showed linear relation between $[{\varepsilon}-1/2{\varepsilon}+1)-(n^2-1/2n^2+1)]$ and $({\mu}_g\;-\;{\mu}_2)^2$.

키워드