Skaergaard 암체의 감람석의 성분변화

Compositional Variation in Olivine in the Skaergaard Intrusion

  • 발행 : 2003.09.01

초록

Skaergaard 암체의 감람석의 성분변화를 연구하기 위하여 Layered Series(LS), Upper Border Series (UBS), 및 Marginal Border Series(MBS)에서 산출되는 감람석의 성분을 분석하였다. 분화에 따른 원소조성변 화는 일반적으로 암체 전체에서 유사한 원소조성변화를 보여주는데 감람석의 FeO*, Ti $O_2$, 및 MnO는 증가하고, MgO와 $SiO_2$는 감소하고, $Na_2$O, $K_2$O, A1$_2$ $O_3$, CaO, 및 P$_2$ $O_{5}$는 분화에 따른 주목할 만한 변화를 보이지 않는다. 분화과정의 전반에 걸쳐 Skaergaard 감람석은 어떠한 급격한 원소 변화 또한 보여주지 않는다. 따라서 마그마 분화에 따라 Skaergaard의 감람석이 체계적인 원소조성변화를 보이는 것으로 Skaergaard 마그마 분화 도중에 새로운 마그마의 주입의 가능성은 배제된다. 주목할 만한 급격한 원소변화가 MnO에서 관찰된다. Layered Series(LS) 감람석의 MnO 성분은 분화가 진행됨에 따라 꾸준히 증가하다가 UZc에서 급격히 감소하는데, 유사한 경향이 UBS, 및 MBS에서도 관찰된다. 이와 같이 Skaergaard 마그마 분화 말기에 관찰되는 감람석의 MnO 성분의 급격한 변화는 liquidus상으로 갑자기 출현하는 ferrobustamite에 기인한다.

Olivine from the Layered Series (LS), Upper Border Series (UBS), and Marginal Border Series (MBS) of the Skaergaard intrusion was analyzed to examine compositional variation. In general, olivine from all three series shows similar trends in major elements with differentiation: FeO* (total iron as FeO*), Ti $O_2$, and MnO in the olivine, progressively increase, MgO and $SiO_2$progressively decrease, and Na$_2$O, K$_2$O, A1$_2$ $O_3$, CaO, and P$_2$O$\_$5/ remain unchanged at low abundances. No abrupt changes in the trends of major components in Skaergaard olivine are observed. The systematic compositional variations in Skaergaard olivine during differentiation preclude the possibility of any injection of new magma into the chamber during differentiation. Abrupt change in MnO, however, is observed in Skaergaard olivine during differentiation. MnO in Skaergaard olivine steadily increases with differentiation from LZ to UZc and then decreases in UZc of the LS and its equivalents of the MBS and UBS. The decrease of MnO in Skaergaard olivine during the final stage of differentiation is attributable to the abrupt and extensive appearance of ferrobustamite as a liquidus phase.

키워드

참고문헌

  1. J. Geol. v.76 Empirical correction factors for the electron microanalysis of silicate oxides Bence,A.E.;Albee,A.L.
  2. Lithos v.11 Early stages in the differentiation of the Skaergaard magma as revealed by a closely related suite of dike rocks Brooks,C.K.;Nielson,T.F.D.
  3. Contrib. Mineral. Petrol. v.104 The differentiation of the Skaergaard intrusion Brooks,C.K.;Nielson,T.F.D.
  4. J. Petrol. v.5 Iron-Titanium oxide minerals and synthetic equivalents Buddington,A.F.;Lindsley,D.H.
  5. Am. Mineral. v.24 Olivines from the Skaergaard intrusion, Kangerdlugssuaq, East Greenland Deer,W.A.;Wager,L.R.
  6. Ph.D. Thesis, University of Oxford A Further Petrological and Chemical Investigation of the Upper Part of the Skaergaard Intrusion, East Greenland Douglas,J.A.V.
  7. Earth Planet. Sci. Let. v.146 $^{40}Ar/^{39}Ar$ Ar dating of the Skaergaard intrusion Hirschmann,M.M.;Renne,P.R.;McBimey,A.R.
  8. J. Petrol. v.30 Petrology of the Marginal Border Series of the Skaergaard intrusion Hoover,J.D.
  9. J. Petrol. v.30 The chilled marginal gabbro and other contact rocks of the Skaergaard intrusion Hoover,J.D.
  10. Mineral. Petrol. v.95 The differentiation of the Skaergaard intrusion Hunter,R.H.;Sparks,R.S.J.
  11. Contrib. Mineral. Petrol. v.104 A reply to comments on The differentiation of the Skaergaard intrusion Hunter,R.H.;Sparks,R.S.J.
  12. Ann. Rev. Earth Planet. Sci. v.12 Double-diffusive convection due to crystallization in magmas Huppert,H.E.;Sparks,R.S.J.
  13. Ph.D. Thesis, State University of New York at Binghamton Petrological, Geochemical, and Mineralogical Cariations in the Skaergaard Intrusion, East Greenland Jang,Y.D.
  14. Contrib. Mineral. Petrol. v.140 Major and trace element composition of Skaergaard plagioclase; Geochemical evidence for changes in magma dynamics during the final stage of crystallization of the Skaergaard intrusion Jang,Y.D.;Naslund,H.R.
  15. Earth Planet. v.189 The differentiation trend of Skaergaard intrusion and the timing of magnetite crystallization: Iron enrichment revisited Jang,Y.D.;Naslund,H.R.;McBimey,A.R.
  16. Am. Mineral. v.69 Pyroxene thermometry Lindsley,D.H.
  17. East Greenland, Mineral. Soc. Am. Spec. Paper 2 Conditions of the ferrowollastonite-ferrohedenbergite inversion in the Skaergaard intrusion Lindsley,D.H.;Brown,G.M.;Muir,I.D.
  18. Contrib. Mineral. Petrol. v.124 Restoration of the elemental and stableisotopic compositions of diffusionally altered minerals in slowly cooled rocks Loucks,P.R.
  19. Geol. Soc. Am. Bull. v.100 Crystal capture, sorting, and retention in convecting magma Marsh,B.D.
  20. Ann. Rev. Earth Planet. Sci. v.17 Magma chambers Marsh,B.D.
  21. Nature v.253 Differentiation of the Skaergaard intrusion McBirney,A.R.
  22. J. Petrol. v.30 The Skaergaard layered series: Part I. Structure and average compositions McBimey,A.R.
  23. J. Geol. Soc. London v.152 Mechanisms of differentiation of layered intrusions: Evidence from the Skaergaard intrusion McBimey,A.R.
  24. Layered Intrusion The Skaergaard intrusion McBimey,A.R.;R.G.Cawthorn(ed.)
  25. J. Petrol. v.44 The Skaergaard layered series: Part VII. Sr and Nd isotopes McBimey,A.R.;Creaser,R.A.
  26. Contrib. Mineral. Petrol. v.104 The differentiation of the Skaergaard intrusion McBirney,A.R.;Naslund,H.R.
  27. Contrib. Mineral. Petrol. v.104 The differentiation of the Skaergaard intrusion Morse,S.A.
  28. Am. J. Sci. v.280A Concerning intensive parameters in the Skaergaard intrusion Morse,S.A.;Lindsley,D.H.;Williams,R.J.
  29. East Greenland Carnegie Inst. Wash. Yb. v.76 Mineralogical variations in the upper part of the Skaergaard intrusion Naslund,H.R.
  30. Ph.D. Thesis, University of Oregon Part I. Petrology of the Upper Border Group of the Skaergaard intrusion, East Greenland; and Part II. An experimental study of liquid immiscibility in iron-bearing silicate melts Naslund,H.R.
  31. J. Petrol. v.25 Petrology of the Upper Border Series of the Skaergaard intrusion Naslund,H.R.
  32. Am. Mineral. v.68 Ilvaite, an alteration product replacing olivine in the Skaergaard intrusion Naslund,H.R.;Hughes,J.M.;Birnie,R.W.
  33. Contrib. Mineral. Petrol. v.55 Electron-probe studies of the earlier pyroxenes and olivines from the Skaergaard intrusion East Greenland New,Y.Y.
  34. East Creenland, Contrib. Mineral. Petrol. v.110 Isotopic studies of processes in mafic magma chambers: Part 2. The Skaergaard intrusion Stewart,B.W.;DePaolo,D.J.
  35. Contrib. Mineral. Petrol. v.128 Iron in plagioclase as a monitor of the differentiation of the Skaergaard intrusion Tegner,C.
  36. J. Petrol. The differentiation trends of iron and manganese-rich olivine and pyroxene in the Skaergaard intrusion Tegner,C.
  37. J. Petrol. v.36 An experimental study of the influence of Oxygen fugacity on Fe-Ti oxide stability, phase relations, and mineral-melt equilibria in ferro-basaltic systems Toplis,M.J.;Carrol,M.R.
  38. J. Petrol. v.37 Differentiation of ferrobasaltic magmas under conditions open and close to Oxygen: Implications for the Skaergaard intrusion and other natural systems Toplis,M.J.;Carrol,M.R.
  39. East Greenland: Part I. Chemistry and ore-microscopy. Geochim. Cosmochim. Acta v.6 Iron-Titanium oxide minerals in layered gabbros of the Skaergaard intrusion Vincent,E.A.;Phillips,R.
  40. East Greenland, Medd. Om. Groenland v.105 Geological investigations in East Greenland; Part III. The petrology of the Skaergaard intrusion Wager,L.R.;Deer,W.A.
  41. Layered Igneous Rocks Wager,L.R.;Brown,G.M.
  42. Geochim. Cosmochim. Acta v.1 The distribution of trace elements during strong fractionation of basic magma-A further study of the Skaergaard intrusion East Greenland Wager,L.R.;Mitchell,R.L.
  43. East Greenland, Am. J. Sci. v.271 Reaction constants in the system Fe-MgO-SiO₂-O₂: Intensive parameters in the Skaergaard intrusion Williams,R.J.