Separation of Chromophoric Substance from Madder Plant under Different Extraction and Analytical Conditions

염료추출 및 분석 조건에 따른 꼭두서니의 색소성분 분리 거동

  • ;
  • S. Kay Obendorf (Dept. of Textiles and Apparel, Cornell University)
  • 안춘순 (인천대학교 패션산업학과) ;
  • Published : 2003.11.01

Abstract

This research was aimed to establish the standard extraction and analytical procedures for examining the chromophoric substance in madder root with the ultimate goal of identifying the dyes in badly faded textiles of archaeological origin. The separation temperature of gas chromatography, pH and other extraction conditions were tested. The results were as follows: The suitable separation temperature for the GC cappillary column was 50∼305$^{\circ}C$, and methanol was a good GC solvent for both standard alizarin and madder extraction. The best extraction of madder was achieved by 90 min soaking in room temperature followed by filtration and the actual heat extraction procedure. The best pH for extracting alizarin was pH 3 and above pH 5 alizarin was not detectible. Only alizarin and no purpurin was found in the extraction of the currently used madder plant.

Keywords

References

  1. 천연염색 공개강좌 천연염색의 이론과 실제 남성우
  2. National Institute of Standards and Technology 98 Mass Spectral Libraries, NIST 98, Rev. D.02.00 Agilent Technologies
  3. The merck index Ash,J.E.;O'Neill,M.;Smith,A.;Heckelman,P.;Kinneary,J.
  4. Journal of Anal. Appl. Pyrolysis v.56 Analysis of anthraquinoid and indigoid dyes used in ancient artistic works by thermally assisted hydrolysis and methylation in the presence of tetramethylammonium hydroxide Fabbri,D.;Chiavari,G.;Ling,H. https://doi.org/10.1016/S0165-2370(00)00092-9
  5. Studies in Conservation v.39 The detection of dyes by FTIR microscopy Gillard,R.D.;Hardman,S.M.;Thomas,R.G.;Watkinson,D.E. https://doi.org/10.2307/1506597
  6. Environmental Science and Technology v.21 no.7 Fading of alizarin and related artists' pigments by atmospheric ozone: Reaction products and mechanisms Grosjean,D.;Whitmore,P.M.;De Moor,C.P.;Cass,G.R. https://doi.org/10.1021/es00161a003
  7. Studies in Conservation v.41 An improved dye and lake pigment analysis method for High-Performance Liquid Chromatography and diode-array detector Halpine,Susana,M. https://doi.org/10.2307/1506519
  8. Journal of Chromatography v.347 Identification of natural red dyes in old Indian textiles: Evaluation of thinlayer chromatographic systems Kharbade,B.V.;Agrawal,O.P. https://doi.org/10.1016/S0021-9673(01)95522-0
  9. J. Mol. Struct.(Theochem) v.594 A density functional study of alizarin tow of itsisomers and is transition metals and rare-earth complexes Komiha,N.;Kabbaj,O.K.;Chraibi,M. https://doi.org/10.1016/S0166-1280(02)00140-9
  10. Mikrochim. Acta. Microanalysis of hydroxyquinones in red lakes Masschelein-Kleiner,L.
  11. Interpretation of mass spectra(4th ed.) McLafferty,F.W.;Turecek,F.
  12. Hali v.4 no.3 Dyes in rugs from the Milas area Miller,C.
  13. Journal of Chromatography A v.989 Identification of natural dyes in archaeological Coptic textiles by liquid chromatography with diode array detection Orska-Gawry,J.;Surowiec,I.;Kehl,J.;Rejniak,H.;Urbaniak-Walczak,K.;Trojanowicz,M. https://doi.org/10.1016/S0021-9673(03)00083-9
  14. Ciba Review v.39 The cultivation of madder Schaefer,G.
  15. Historic textile and paper materialsⅡ: Conservation and characterization Identification of red madder and insect dyes by thin-layer chromatography Schweppe,H.;S.H.Zeronian(Eds.);H.L.Needles(Eds.)
  16. Naturally ocurring quinones Thomson,R.H.
  17. Chromatography and Analysis no.June The characterisation of dyes in textiles from archaeological excavations Walton,P.;Taylor,G.
  18. Studies in Conservation v.30 High performance liquid chromatography of anthraquinones: Analysis of plant and insect extracts and dyed textiles Wouter,Jan https://doi.org/10.2307/1505927