Fibers and Polymers

  • 제4권3호
  • /
  • Pages.97-101
  • /
  • 2003
  • /
  • 1229-9197(pISSN)
  • /
  • 1875-0052(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

Preparation of SAN/Silicate Nanocomposites Using PMMA as a Compatibilizer

  • Kim, Ki-Hong (Hyperstructured Organic Materials Research Center and School of Materials Science and Engineering, Seoul National University) ;
  • Jo, Won-Ho (Hypersttructured Organic Materials Research Center and School of Materials Science and Engineering, Seoul National University) ;
  • Jho, Jae-Young (Hypersttructured Organic Materials Research Center and School of Chemical Engineering, Seoul National University) ;
  • Lee, Moo-Sung (Faculty of Applied Chemistry, Chonnam National University) ;
  • Lim, Gyun-Taek (Faculty of Applied Chemistry, Chonnam National University)
  • 발행 : 2003.09.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Polymer/silicate nanocomposites were prepared via two-step manufacturing process: a master batch preparation and then mixing with matrix polymer. A hybrid of PMMA and Na-MMT with exfoliated structure was first prepared by emulsion polymerization of MMA in the presence of Na-MMT. For the case that SAN24, miscible with PMMA, is used as matrix, we could prepare a nanocomposite with exfoliated structure. However, SAN31 nanocomposite shows the aggregation and/or reordering of the silicate layers due to the immiscibility between SAN31 and PMMA.

키워드

참고문헌

  1. E. P. Giannelis, R. Krishnamoorit., and E. Manias, Adv. Polym. Sci., 138, 107 (1999) https://doi.org/10.1007/3-540-69711-X_3
  2. M. B. Ko and J. Kim, Polym. Sci. Technol (Korea), 10, 451 (1999)
  3. M. Alexandre and Ph. Dubois, Mater. Sci. Eng., 28, 1 (2000) https://doi.org/10.1016/S0927-796X(00)00012-7
  4. P. C. LeBaron, Z. Wang, and T. J. Pinnavaia, Appl. Clay Sci., 15, 11 (1999) https://doi.org/10.1016/S0169-1317(99)00017-4
  5. Y. Kojima, A. Usuki, M. Kawasurni, A. Okada, T. Kurau-chi, and O. Kamigaito, J. Polym. Sci., Part A, Polym. Chem., 31, 1755 (1993) https://doi.org/10.1002/pola.1993.080310714
  6. K. Yano, A. Usuki, and A. Okada, J. Polym. Sci., Part A, Polym. Chem., 35, 2289 (1997) https://doi.org/10.1002/(SICI)1099-0518(199708)35:11<2289::AID-POLA20>3.0.CO;2-9
  7. R. A. Vaia and E. P. Giannelis, Macromolecules, 30, 7990(1997) https://doi.org/10.1021/ma9514333
  8. R. A. Vaia, K. D. Jandt, E. J. Kramer, and E. P. Giannelis, Macromolecules, 28, 8080 (1995) https://doi.org/10.1021/ma00128a016
  9. M. B. Ko, J. Y. Jho, W.H. Jo, and M. S. Lee, Fiber Polym., 3, 103 (2002) https://doi.org/10.1007/BF02892625
  10. S. W. Kim, W. H. Jo, M. S. Lee, M. B. Ko, and J. Y. Jho, Polymer J., 34, 103 (2002) https://doi.org/10.1295/polymj.34.103
  11. N. Hasegawa, M. Kawasurni, M. Kato, A. Usuki, and A. Okada, J. Appl. Polym. Sci., 67,87 (1998) https://doi.org/10.1002/(SICI)1097-4628(19980103)67:1<87::AID-APP10>3.0.CO;2-2
  12. M. Kawasumi, N. Hasegawa. M. Kato, A. Usuki, and A. Okada, Macromolecules, 30, 6333 (1997) https://doi.org/10.1021/ma961786h
  13. N. Hasegawa, H. Okada, M. Kawasurni, and A. Usuki, J. Appl. Polym. Sci., 74, 3359 (1999) https://doi.org/10.1002/(SICI)1097-4628(19991227)74:14<3359::AID-APP9>3.0.CO;2-2
  14. S. W. Kim, W. H. Jo, M. S. Lee, M. B. Ko, and J. Y. Jho, Polymer, 42, 9837 (2001) https://doi.org/10.1016/S0032-3861(01)00506-7
  15. M. Suess, J. Kressler, and H. W. Krammer, Polymer, 28, 957 (1987) https://doi.org/10.1016/0032-3861(87)90169-8