Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지

Surface Characteristics and Dyeability of LDPE Film Treated with Fluorine Gas Mixtures

혼합 불소가스 처리에 의한 LDPE 필름의 표면특성과 염색성

  • 박수진 (한국화학연구원 화학소재연구부) ;
  • 신준식 (한국화학연구원 화학소재연구부) ;
  • 최경은 (전주교육대학교 실과교육과) ;
  • 김학용 (전북대학교 섬유공학과) ;
  • 이덕래 (전북대학교 섬유공학과)
  • Published : 2003.08.01
⟨ Previous Next ⟩

Abstract

In this work, the effect of oxyfluorination on dyeability of low-density polyethylene (LDPE) film was studied in terms of surface analysis and contact angle measurements. The compositions of a mixed F$_2$-O$_2$ gas were varied, 80-0, 70-10, 60-20, 40-40, and 10-70, by pressure ratio. Surface characteristics, including the functional groups, and wettability of the LDPE rim were confirmed by FTIR-ATR, XPS, and contact angle analyses. As a result, the oxyfluorinated LDPE film led to a decrease in water and diiodomethane angles, mainly due to the increase in oxygen functional groups and the decrease in C-F groups with the oxygen pressure. From the dyeability test, it was found that the oxyfluorination played an important role in the wettabilty for water and diiodomethane, led to an improvement of dyeability to dispersive and basic dyeing agents. Consequently, mixed fluorine treatment on LDPE was a suitable method for modifying the polymer surfaces.

Keywords

References

  1. Physical Chemistry of Surfaces(5th Ed.) A.W.Adamson
  2. J. Colloid Interface Sci. v.236 Effect of Corona Discharge Treatment on the Dyeability of Low-Density Polyethylene Film S.J.Park;J.S.Jin
  3. J. Appl. Polym Sci. v.71 Chemical Midification of LDPE Film D.S.Bag;V.P.Kumar;S.Maiti
  4. Interfacial Forces and Fields: Theory and Applications S.J.Park;J.P.Hsu(Ed.)
  5. Appl. Surf. Sci. v.189 Adhesion Properties of Aluminiummetallized/Ammonia Plasma-treated Polypropylene Spectroscopic Analysis (XPS, EXES) of the Aluminium/Polypropylene Interface J.Kurdi;H.Ardelean;P.Marcus;P.Jonnard;F.Arefi-Khonsari
  6. J. Appl. Polym. Sci. v.79 Improvement of the Mechanical Properties of on Ultrahigh Molecular Weight Polyethylene Fiber/Epoxy Composite by Corona-Discharge Treatment T.Ogawa;H.Mukai;S.Osawa
  7. J. Polym. Sci. Polym. Chem. Ed. v.26 Surface Modification of Polymers Vapor Phase Photografting with Acrylic Acid K.Allmer;A.Hult;B.Ranby
  8. J. Appl. Polym. Sci. v.72 Surface Grafting of Poly(vinylamine) onto Poly(ethylene) Film by Corona Discharge-Induced Grafting F.Seto;Y.Muraoka;T.Akagi;A.Kishida;M.Akashi
  9. J. Power Sources v.104 Electrochemical Behavior of Plasma-fluorinated Graphite for Lithium Ion Batteries T.Nakajima;V.Gupta;Y.Ohzawa;M.Koh;R.N.Singh;A.Tressaud;E.Durnad
  10. Carbon v.40 Fluorinated Carbon Blacks: Influence of the Morphology of the Starting Material on the Fluorination Mechanism A.Tressaud;T.Shirasaki;G.Nanse;E.Papirer
  11. J. Fluor. Chem. v.98 Surface Fluorination of Polypropylene(Ⅰ)-Characterisation of Surface Properties F.J.Du Toit;R.D.Sanderson
  12. J. Fluor. Chem. v.112 Electrochemical Characteristics and Structures of Surface-fluorinated Graphites with Different Particle Sizes for Lithium Ion Secondary Batteries V.Gupta;T.Nakajima;Y.Ohzawa;H.Iwata
  13. J. Fluor. Chem. v.98 Surface Fluorination of Polypropylene(Ⅱ)-Adhesion Properties F.J.du Toit;R.D.Sanderson
  14. Carbon v.40 Surface Properties of Oxyfluorinated PAN-based Carbon Fibers Y.S.Lee;B.K.Lee
  15. Polym. J. v.31 Roles of Unsaturated Polyester in the Epoxy Matrix System S.J.Park;W.B.Park;J.R.Lee
  16. J. Appl. Polym. Sci. v.72 Surface Grafting of Ploy(vinylamine) onto Poly(ethylene) Film by Corona Discharge-Induced Grafting F.Seto;Y.Muraoka;T.Akagi;A.Kishida;M.Akashi
  17. J. Appl. Polm. Sci. v.74 XPS and Water Contact Angle Measutements on Aged and Corona-Treated PP S.Suzer;A.Argun;O.Vatansever;O.Aral
  18. J. Appl. Polym. Sci. v.13 Estimation of the surface Free Energy of Polymers D.K.Owens;R.C.Wendt
  19. Polymer Interface and Adhension S.Wu
  20. Z. Techn. Phys. v.142 Ein Beitrag Zur Optik der farbanstriche P.Kubelka;F.Munk
  21. J. Fluor. Chem. v.74 The Effect of Surface Fluorination on the Wettability of High Density Polyethylene F.J.du Toit;R.D.Sanderson;W.J.Engelbrecht;J.B.Wagener
  22. Handbook of X-ray Photoelectron Spectroscopy C.D.Wagner;W.M.Riggs;L.E.Davis;J.F.Moulder