한국의류학회지 (Journal of the Korean Society of Clothing and Textiles)

  • 제27권5호
  • /
  • Pages.523-523
  • /
  • 2003
  • /
  • 1225-1151(pISSN)
  • /
  • 2234-0793(eISSN)
한국의류학회 (The Korean Society of Clothing and Textiles)
권호 표지

전해질 첨가에 따른 키토산/Sodium Dodecyl Sulfate 상호작용의 변화

The Change of Interactions of Chitosan/Sodium Dodecyl Sulfate in the Presence of Electrolytes

  • 발행 : 2003.05.01
⟨ 이전 논문 다음 논문 ⟩

초록

The change of interactions of anionic surfactants, sodium dodecyl sulfate(SDS) and sodium tetradecyl sulfate(575) in the presence of electrolytes, to the chitosan-based polyelectrolyte(sol＇n and gel phase) were studied. The chitosan gel used in this study were crosslinked with epichlorohydrin(ECH). Binding isotherms were determined by potentiometric technique using a surfactant ion selective solid-state electrode and the results were represented by using the sequence generating function(SGF) method. The results of binding isotherm were shown comparatively high cooperativity. The addition of electrolytes in the chitosan/SDS system resulted in a shift of the binding to higher free surfactant concentration because of screen effect by the electrolytes. Degree of binding of chitosan gel was higher than that of chitosan sol＇n. And also a conformational phase transition of the chitosan gel in the presence of electrolytes has been investigated.

키워드

참고문헌

  1. The polysaccharides v.1 Aspinall,G.O.
  2. J. Polym. Sci., Part A, Polym. Chem v.35 The Cooperative Binding Behavior of Sodium Dodecyl Sulfate to Crooslinked Chitosan Films Bae,H.S.;Hudson,S.M.
  3. J. Korean Fiber Soc. v.36 Interactions between Polyelectrolyte Based on Crosslinked Chitosan and Amphoteric Surfactant Bae,H.S.
  4. J. Chem. Phys. v.9 Thermodynamics of High Polymer Solutions Flory,P.J.
  5. Makromol. Chem. v.186 Studies on Chitosan-induced Metachromasy. 1. Metachromatic behavior of Sodium 2`-hydroxy-1,1`azo-naphthalene-4-sulfonate in the presence of Chitosan Gummow,B.D.;Robert,G.A.F.
  6. Surfactant Science Series v.37 Cationic Surfactants in Physical Chemistry Hayakawa,K.;Kwak,J.C.T.;D.N.Rubingh(ed.);P.M.Holland(ed.)
  7. J. Phys. Chem. v.86 Surfactant-Polyelectrolyte Interactions. 1. Binding of DodecyItrimethylammonium ions by Sodium Dextran Sulfate and Sodium Poly(styrenesulfonate) in Aqueous Solution in the Presence of Sodium Chloride Hayakawa,K.;Kwak,J.C.T.
  8. Macromolecules v.16 Study of Surfactant-Polyelectrolyte Interactions. Binding of Dodecyl-and Tetradecy Itrimethy lammonium Bromide by Some carboxylic Polyelectrolytes Hayakawa,K.;Santerre,J.P;Kwak,J.C.T.
  9. Macromolecules v.25 Collapse of Polyelectrolyte Networks Induced by Their Interaction with Oppositely Charged Surfactants Khokhlov,A.R.;Kramarenko,E.;Yu. Makhaeva,E.E;Starodubtzev,S.G.
  10. Makromol. Chem v.178 Evidence for Formation of Block and Random Copolymers of N-Acetyl-D-Glucosamine an D-Glucosamine by Hetero and Homogeneous Hydrolyses Kurita,K.;Sannan,T.;Iwakura,Y.
  11. J. Appl. Polym. Sci. v.73 Synthesis and Characteristics of Interpenetrating Polymer Network Hydrogel Composed of Chitosan and Poly(acrylic acid.) Lee,J.W.;Kim,S.Y.;Kim,S.S.;Lee,Y.M.;Lee,K.H.;Kim,S.J.
  12. J. Chem. Phys. v.40 Partition Functions of Linear-Chain Molecules Lifson,S.
  13. J. Phys. Chem. v.88 Surfactant-Polyelectrolyte Interactions. 4. Surfactant Chain Length Dependence of the Binding of Alkylpyridinium Cations to Dextran Sulfate Malovikova,A.;Hayakawak.;Kwak,J.C.T.
  14. J. Chem. Phys. v.51 Limiting Laws and Counterion Condensation in Polyelectrolyte Solution. Ⅲ. An Analysis Based on the Ionic Solution Theory Manning,G.S.
  15. U.S. Patent, 5,015,293 Method of Forming a Crosslinked Chitosan polymer and Product Thereof Mayer,J.;Kaplan,D.
  16. J. Phys. Chem. v.65 PolycationPolya ion Complexes: Preparation and Properties of Poly-(Vinylben-zyltrimethylammonium) Poly-(Styrenesulfonate) Michaels,A.S.;Miekka,R.G.
  17. J. Appl. Polym. Sci v.28 Highly Deacetylated Chitosan and Its Properties Mima,S.;Miya,M.;Iwamoto,R.;Yoshikawa,S.
  18. Polymer/Surfactant Interactions v.11 Anionic Surfactants in Physical Chemistry of Surfactant Action: Surfactant Science Series Robb,I.D.;Lucassen-Reynders,E.H(ed.)
  19. J. Colloid Interface Sci v.24 Solubilization Properties of Polymer-Surfactant Complexes Saito,S.
  20. Eur. J. Biochem v.12 Cooperative Binding to Linear Biopolymers. 2. Thermodynamic Analysis of the Proflavine-Poly(L-Glutamic Acid) System Schwarz,G.;Klose,S.;Balthasar,W.
  21. Phys. Rev. Lett. v.40 no.12 Collapse of Gels and the Critical Endpoint Tanaka,T.
  22. Phys. Rev. Lett. v.45 no.20 Phase Transition in Ionic Gels Tananka,T.;Fillmore,D.;Sun,S.;Nishio,I.;Swislow,G.;Shah,A.
  23. J. Phys. Chem v.95 Thalberg,K.;Stam,J.;van,Lindblad,C.;Almgern,M.;Lindbman,B.
  24. Marcromolecules v.26 Binding of Sodium Dodecyl Surfate to a Polyelectrolytes Based on Chitosan Wei,Y.C.;Hudson,S.M.
  25. J. Macromol. Sci., Rev. Macromol. Chem. Phys. v.C35 no.1 The Interaction Between Polyelectrolytes and Surfactants of Opposite Charge Wei,Y.C.;Hudson,S.M.
  26. Polymer Communications v.31 Crosslinking Chitosan Membranes for Pervaporation of Alcohol-Water Mixture Yisong,Y.;Wenjun,L.;Tongyin,Y.
  27. J. Chem. Phys. v.31 Theory of the Phase Transition between Helix and Random Coil in Polypeptide Chains Zimm,B.H.;Bragg,J.K.