Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Two Dimensional Electronic Spectroscopy

  • Fleming, Graham R. (Department of Chemistry, University of California, Berkeley and the Physical Biosciences Division, Lawrence Berkeley National Laboratory) ;
  • Yang, Min-O (Dept. of Chemistry and Institute of Basic Sciences Research, Chungbuk National University) ;
  • Agarwal, Ritesh (Dept. of Chemistry and Chemical Biology, Harvard University) ;
  • Prall, Bradley S. (Department of Chemistry, University of California, Berkeley and the Physical Biosciences Division, Lawrence Berkeley National Laboratory) ;
  • Kaufman, Laura J. (Present Addresses: Dept. of Chemistry and Chemical Biology, Harvard University) ;
  • Neuwahl, Fred (European Laboratory for Non-Linear, Spectroscopy(LENS), University of Florence)
  • Published : 2003.08.20
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Abstract

Two different electronically resonant two-dimensional spectroscopies are described. The first, two-color photon echo peak shift spectroscopy, is sensitive to correlations in transition frequency between the initial and probed (final) states. It provides new insight into the mechanism of ultrafast solvation and should prove useful for characterizing dynamics in inhomogeneous systems in general. The second technique, fifth order threepulse scattering, contains two coherence periods whose durations are controlled. The entire two-dimensional surface was recorded for a dye molecule in dilute solution and a photosynthetic light-harvesting complex. The data provide insight into the short-time dynamics of solvation and exciton relaxation, respectively.

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References

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