대한화학회지 (Journal of the Korean Chemical Society)

  • 제47권2호
  • /
  • Pages.104-108
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  • 2003
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  • 1017-2548(pISSN)
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  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
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수소 결합에 의한 삼차원의 Copper(II) 거대고리 착물과 2,5-Pyridinedicarboxylate와의 자기조립

Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond

  • 최기영 (공주대학교 사범대학 화학교육과) ;
  • 류해일 (공주대학교 사범대학 화학교육과) ;
  • 김용선 (공주대학교 사범대학 화학교육과)
  • Ki-Young Choi (Department of Chemistry Education, Kongju National University) ;
  • Haiil Ryu (Department of Chemistry Education, Kongju National University) ;
  • Yong-Son Kim (Department of Chemistry Education, Kongju National University)
  • 발행 : 2003.04.20
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초록

$[Cu(L)]Cl_2{\cdot}2H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$과 2,5-pyridinedicarboxylate(pdc)의 반응으로부터 $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$가 합성되었다. 화합물 1의 구조가 X-ray 회절법 및 분광학적 방법으로 규명되었다. 중심 copper 원자는 거대고리 리간드로부터 4개의 이차 아민과 축방향 위치의 물분자로 결합된 약간 일그러진 사각뿔 구조를 갖는다. 또한 분자간 수소결합은 삼차원의 분자구조를 형성한다.

The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.

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참고문헌

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피인용 문헌

  1. Synthesis, crystal structure, spectroscopic and thermal characterization of (Hampy)2[Ni(pydc)2(H2O)2] · 2 H2O vol.224, pp.4, 2009, https://doi.org/10.1524/zkri.2009.1112
  2. Separation of Lithium Isotopes by Tetraazamacrocycles Tethered to Merrifield Peptide Resin vol.28, pp.3, 2003, https://doi.org/10.5012/bkcs.2007.28.3.451