Bulletin of the Korean Chemical Society

  • 제24권4호
  • /
  • Pages.421-425
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  • 2003
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Thallium(Ⅰ)-Selective Membrane Potentiometric Sensor Based on Dibenzyldiaza-18-Crown-6

  • 발행 : 2003.04.20
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초록

A new thallium(Ⅰ) selective electrode based on dibenzylidaza-18-crown-6 as mambrane carrier was successfully prpared. The electrode exhibitis a near-Nernstian response for $ T1^+$ ions over a wide concentration range from $1.0×10^{15}-1.0×10^{-1}$M at 25℃, and was found to be selective, precise and useable within the pH range 4.0-11.0. The electrode was successfully used as an indicator electrode in potentiometric titration of thallium ions.

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