Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Noncovalently Linked Zinc Porphyrin-Ru(bpy)3 Dyad Assembled via Axial Coordination

  • Kim, Dol (Department of Chemistry, Sunchon National University) ;
  • Shin, Eun-Ju (Department of Chemistry, Sunchon National University)
  • Published : 2003.10.20
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Abstract

Noncovalently linked electron donor-acceptor dyad consisting of zinc tetratolylporphyrin and pyridine appended ruthenium trisbipyridine comlex was prepared, via axial coordination of pyridine moiety in ruthenium trisbipyridine complex on zinc tetratolylporphyrin. For the purpose of comparison, axial coordination of pyridine-appended 2,2'-bipyridine on zinc tetratolylporphyrin was also investigated. The Kvalues were detemined based on absorption of fluorescence studies. The fluorescence of zinc teratolylporphrin was efficiently quenched upon axial coordination of pyridine moiety, prbably due to the photoinduced electron transfer from zinc tetrtolylporphyrin to ruthenium trisbipyridine, supported by free enegy estimation.

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References

  1. Wasielewski, M. R. Chem. Rev. 1992, 92, 435. https://doi.org/10.1021/cr00011a005
  2. Gust, D.; Moore, T. A. Acc. Chem. Res. 1993, 26, 198. https://doi.org/10.1021/ar00028a010
  3. Harriman, A.; Sauvage, J.-P. Chem. Soc. Rev. 1996, 25, 41. https://doi.org/10.1039/cs9962500041
  4. Hayashi, T.; Ogoshi, H. Chem. Soc. Rev. 1997, 26, 355. https://doi.org/10.1039/cs9972600355
  5. Sauvage, J.-P.; Collin, J.-P.; Chambron, J.-C.; Guillerez, S.;Coudret, C.; Balzani, V.; Barigelletti, F.; de Cola, L.; Flamigni, L.Chem. Rev. 1994, 94, 993. https://doi.org/10.1021/cr00028a006
  6. Balzani, V.; Juris, A.; Venturi, M.; Campagna, S.; Serroni, S.Chem. Rev. 1996, 96, 759. https://doi.org/10.1021/cr941154y
  7. Meyer, T. J. Acc. Chem. Res. 1989, 22, 163. https://doi.org/10.1021/ar00161a001
  8. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.;von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85. https://doi.org/10.1016/0010-8545(88)80032-8
  9. Kalyanasundaram, K. Photochemistry of Polypyridine andPorphyrin Complexes; Academic Press: London, 1992.
  10. Harriman, A.; Hissler, M.; Trompete, O.; Ziessel, R. J. Am. Chem.Soc. 1999, 121, 2516. https://doi.org/10.1021/ja982300a
  11. Flamigni, L.; Barigelletti, F.; Armaroli, N.; Ventura, B.; Collin, J.-P.; Sauvage, J.-P.; Williams, J. A. G. Inorg. Chem. 1999, 38, 661. https://doi.org/10.1021/ic980847k
  12. Flamigni, L.; Armaroli, N.; Barigelletti, F.; Balzani, V.; Collin, J.-P.; Dalbavie, J.-O.; Heitz, V.; Sauvage, J.-P. J. Phys. Chem. B1997, 101, 5936. https://doi.org/10.1021/jp963773b
  13. Harriman, A.; Odobel, F.; Sauvage, J.-P. J. Am. Chem. Soc. 1995,117, 9461. https://doi.org/10.1021/ja00142a012
  14. Collin, J.-P.; Harriman, A.; Heitz, V.; Odobel, F.; Sauvage, J.-P. J.Am. Chem. Soc. 1994, 116, 5679. https://doi.org/10.1021/ja00092a020
  15. Harriman, A.; Odobel, F.; Sauvage, J.-P. J. Am. Chem. Soc. 1994,116, 5481. https://doi.org/10.1021/ja00091a067
  16. Steiger, B.; Anson, F. C. Inorg. Chem. 1995, 34, 3355. https://doi.org/10.1021/ic00116a031
  17. LeGourriérec, D.; Andersson, M.; Davidsson, J.; Mukhtar, E.;Sun, L.; Hammarström, L. J. Phys. Chem. A 1999, 103, 557. https://doi.org/10.1021/jp984150w
  18. Shin, E. J.; Kim, I. S.; Ahn, S. Y. Bull. Korean Chem. Soc. 2000,21, 328.
  19. Larsen, R. W.; Jasuja, R.; Niu, S.-L.; Dwivedi, K. J. Photochem.Photobiol. A:Chem. 1997, 107, 71. https://doi.org/10.1016/S1010-6030(96)04589-3
  20. Sessler, J. L.; Brown, C. T.; OConnor, D.; Springs, S. L.; Wang,R.; Sathiosatham, M.; Hirose, T. J. Org. Chem. 1998, 63, 7370. https://doi.org/10.1021/jo9810112
  21. Hunter, C. A.; Sarson, L. D. Angew. Chem. Int. Ed. Engl. 1994,33, 2313. https://doi.org/10.1002/anie.199423131
  22. Ward, M. W. Chem. Soc. Rev. 1997, 26, 365. https://doi.org/10.1039/cs9972600365
  23. Sessler, J. L.; Wang, B.; Springs, S. L.; Brown, C. T. ComprehensiveSupramolecular Chemistry; Pergamon: London, 1996.
  24. Lehn, J.-M. Science 2002, 295, 2400. https://doi.org/10.1126/science.1071063
  25. Kercher, M.; Konig, M. B.; Zieg, H.; de Cola, L. J. Am. Chem.Soc. 2002, 124, 11541. https://doi.org/10.1021/ja026695g
  26. Ciana, L. D.; Hamachi, I.; Meyer, T. J. J. Org. Chem. 1989, 54,1731. https://doi.org/10.1021/jo00268a042
  27. Peek, B. M.; Ross, G. T.; Edwards, S. W.; Meyer, G. J.; Meyer, T.J.; Erickson, B. W. Int. J. Peptide Protein Res. 1991, 38, 114.
  28. Strouse, F.; Schoonover, J. R.; Duesing, R.; Boyde Jr., S.; Jones,W. E.; Meyer, T. J. Inorg. Chem. 1995, 34, 473. https://doi.org/10.1021/ic00106a009
  29. Benesi, A.; Hildebrand, J. H. J. Am. Chem. Soc. 1949, 71, 2703. https://doi.org/10.1021/ja01176a030
  30. Shin, E. J.; Kim, D. J. Photochem. Photobiol. A : Chemistry 2002,152, 25. https://doi.org/10.1016/S1010-6030(02)00189-2
  31. Lee, J.-C.; Kim, T.-Y.; Kang, S. H.; Shim, Y. K. Bull. KoreanChem. Soc. 2001, 22, 257.
  32. Kim, J.; Rhee, S. W.; Na, Y. H.; Lee, K. P.; Do, Y.; Jeoung, S. C.Bull. Korean Chem. Soc. 2001, 22, 1316.
  33. Ha, J.-H.; Jung, G. Y.; Kim, M.-S.; Lee, Y. H.; Shin, K.; Kim, Y.-R. Bull. Korean Chem. Soc. 2001, 22, 63.

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