Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Fabrication of Nano-sized Titanate Powder via a Polymeric Steric Entrapment Route and Planetary Milling Process

  • Lee, Sang-Jin (Department of Advanced Materials Science and Engineering, Mokpo National University) ;
  • Lee, Chung-Hyo (Department of Advanced Materials Science and Engineering, Mokpo National University)
  • Published : 2002.01.01
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Abstract

Pure and nano-sized $TiO_2$ and $CaTiO_3$ powders were fabricated by a polymeric steric entrapment route and planetary milling process. An ethylene glycol was used as a polymeric carrier for the preparation of organic-inorganic precursors. Titanium isopropoxide and calcium nitrate were dissolved in liquid-type ethylene glycol without any precipitation. At the optimum amount of the polymer, the metal cations were dispersed in solution and a homogeneous polymeric network was formed. The dried precursor ceramic gels were turned to porous powders through calcination process. The porous powders were crystallized at low temperatures and the crystalline powders were planetary milled to nano size.

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References

  1. M. A. Gulgun and W. M. Kriven, 'A Simple Solution-poly-merization Route for Oxide Powder Synthesis,' pp. 57-66 in Ceramic Transactions, Vol. 62. Ed. by J. J. Kingsley, C. H. Schilling and J. H. Adair, American Ceramics Society, Westerville, 1995
  2. M. A. Gulgun, M. H. Nguyen and W. M. Kriven, 'Polymer-ized Organic-inorganic Synthesis of Mixed Oxides,' J. Am. Ceram. Soc., 82 [3] 556-60 (1999) https://doi.org/10.1111/j.1151-2916.1999.tb01800.x
  3. M. H. Nguyen, S. J. Lee and W. M. Kriven, 'Synthesis via aPolymeric Steric Entrapment Precursor Route' J. Mater. Res., 14 [8] 3417-26 (1999) https://doi.org/10.1557/JMR.1999.0462
  4. M. H. Nguyen, 'A New Polymer Route to the Synthesis of Mixed Oxide Ceramics,' in M.S. Thesis, University of Illi-nois at UrBana-champaign, Urbana, 1997
  5. S. J. Lee and W. M. Kriven, 'Crystallization and Densifica-tion of Nano-size, Amorphous Cordierite Powder Prepared by a PVA Solution-polymerization Route,' J. Am. Ceram. Soc., 81 [10] 2605-12 (1998) https://doi.org/10.1111/j.1151-2916.1998.tb02667.x
  6. I. NettleshiP, J. L. Shull and W. M. Kriven, 'Chemical Preparation and Phase Stability of $Ca_2$$SiO_4$ and $Sr_2$$SiO_4$
  7. M. A. Gulgun, O. O. Popoola and W. M. Kriven, 'Chemical Synthesis and Characterization of Calcium Aluminate Powders,' J. Am. Ceram. Soc., 77 [2] 531-39 (1994) https://doi.org/10.1111/j.1151-2916.1994.tb07026.x
  8. S. J. Lee, E. A. Benson and W. M. Kriven, 'Preparation of Portland Cement Components by Poly (vinyl alcohol) Solu-tion Polymerization,' J. Am. Ceram. Soc., 82 [8] 2049-55 (1999) https://doi.org/10.1111/j.1151-2916.1999.tb02039.x
  9. S. J. Lee and W. M. Kriven, 'A Submicron Scale Duplex Zirconia and Alumina Composite by Polymer Complexation Processing,' Ceram. Eng. Sci. Proc., 20 [3] 69-76 (1999) https://doi.org/10.1002/9780470294567.ch9
  10. P. Praminik and A. Pathak, 'A New Chemical Route for the Preparation of Fine Particles of Mixed Oxide Systems,'Mater. Sci. Bull., 17 [6] 967-75 (1994) https://doi.org/10.1007/BF02757573
  11. D. A. Fumo, M. R. Morelli and A. M. Segadaes, 'Combus-tion Synthesis of Calcium Aluminates,' Mater. Res. Bull., 31 [10] 1243-55 (1996) https://doi.org/10.1016/0025-5408(96)00112-2
  12. S. J. Lee, M. D. Biegalski and W. M, Kriven, 'Powder Syn thesis of Barium Titanate and Barium Orthotitanate via an Ethylene Glycol Complexation Polymerization Route,' J. Mater. Sci., 14 [7] 3001-06 (1999)
  13. C. H. Jung, J. Y. Park, M. Y. Lee, S. J. Oh, H. Y. Kim and G. W. Hong, 'Synthesis of Lanthanides Doped CaTi$O_3$ Pow-der by the Combustion Process,' Kor. J. Ceram., 6 [1] 47-52 (2000)
  14. M. Pechini, 'Method of Preparing Lead and Alkaline-earth Titanates and Niobates and Coating Method Using the Same to Form a Capacitor,' U.S. Pat., No., 3 330 697, July 11,1967
  15. L. W. Tai, H. U. Anderson and P. A. Lessing, 'Mixed-cation Oxide Powders via Resin Intermediates Derived from a Water-soluble Polymer,' J. Am. Ceram. Soc., 75 [12] 3490-94 (1992) https://doi.org/10.1111/j.1151-2916.1992.tb04458.x
  16. K. Kiss, J. Madger, M. S. Vukasovich and R. J. Lockhart, 'Ferroelectric of Ultrafine Particle Size: I. Synthesis of Titanate Powders of Ultrafine Particle Size,' J. Am. Ceram. Soc., 49 [6] 291-94 (1996)
  17. M. J. Lee, H. Kim, C. T. Lee and B. H. Choi, 'Studies on Preparation of Ti$O_2$, Powder with High Purity and Fine Particle A Study of High Purifying (I)(in Kor.),' J. Kor. Ceram. Soc., 37 [10] 933-37 (2000)
  18. B. M. Lee, D. Y. Shin and S. M. Han, 'Synthesis of Hydrous Ti$O_2$ Powder by Dropping Precipitant Method and Photo-catalytic Properties(in Kor.),' J. Kor. Ceram. Soc., 37 [4] 308-13 (2000)