The Korean Journal of Pesticide Science (농약과학회지)

The Korean Society of Pesticide Science (한국농약과학회)
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Synthesis and herbicidal activity of new benzenesulfonylurea derivatives possessing bicyclic ketal subgroup

Bicyclic ketal subgroup을 갖는 새로운 벤젠술포닐우레아 유도체의 합성과 제초활성

  • Published : 2002.03.30
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Abstract

New benzenesulfonylurea derivatives possessing bicyclic ketal subgroup were synthesized and shown to have interesting herbicidal activities under upland greenhouse screening.

Bicyclic ketal subgroup을 갖는 새로운 벤젠술포닐우레아 유도체들을 합성하여 제초활성을 온실에서 시험하였다. 그중에서 화합물 6b는 표준물질 thifensulfuron methyl과 비교 실험한 결과 처리약량 $6{\sim}100g/ha$의 밭조건 발아후 처리에서 밀에 대해서 보다 좋은 선택성을 나타내었으며 밭잡초들에 대한 제초활성은 비슷하거나 약간 떨어지는 결과를 나타내었다.

Keywords

References

  1. Brown, H. M., F. T. Lichtner, J. M. Hutchison and J. A. Saladini (1995) The impact of sulfonylurea herbicides in cereal crops. Brighton Crop Protection Conference-Weeds, 3:1143-115
  2. Brown, H. M and J. C. Cotterman (1994) Recent advances in sulfonylurea herbicides. pp.47-81, In Chemistry of Plant Protection: Herbicides inhibiting branched chain amino acid biosynthesis-recent developments (ed. J. Stetter), Springer-Verlag, Germany
  3. Bryant, R. and M. Bite (2001) Ag. Chem. New Compound Review, Agranova, U.K.
  4. Elliott, W. J. and J. Fried (1976) Stereocontrolled synthesis of $\alpha$-multistriatin, an ssential component of the aggregation pheromone for the european elm bark beetle. J. Org. Chem., 41:2475-2476
  5. Gee, S. K. and J. V. Hay (1994) Recent development in the chemistry of sulfonylurea herbicide. pp15~46, In Chemistry of Plant Protection: Herbicides inhibiting branched chain amino acid biosynthesis - recent developments (ed. J. Stetter), Springer-Verlag, Germany
  6. Hwang, I. T., K. S. Hong, J. S. Choi, J-S. Kim, J. H. Yu, Y. K. Ko, J. W. Ryu, H. S. Chang, D-W. Kim and K. Y. Cho (1999) Herbicidal and biological characteristics of a new benzenesulfonylurea compound K-11451 under submerged paddy conditions. Pesticide Science 55:578-580 https://doi.org/10.1002/(SICI)1096-9063(199905)55:5<578::AID-PS954>3.0.CO;2-O
  7. Hwang, I. T., Y. K. Ko., T. J. Kim., D-W. Kim and K. Y. Cho (2000) Structure-activity relationships of acetolactate synthase inhibition among new benzenesulfonylureas in rice (Oryza sativa) and barnyardgrass (Echinochloa and crus-galli var. oryzicola). Pesticide Biochemistry and Physiology 68:166-172 https://doi.org/10.1006/pest.2000.2503
  8. Kim, D. W., Y. K. KO and S-H. Kim (1992) A new and facile synthesis of sulfonyl chlorides. Synthesis 1203-1204
  9. Kinzer, G. W., A. F. Jr. Fentimen, T. F. Jr. Page, R. L. Foltz, J. P. Vite and G. B. Pitman (1969) Bark beetle attractants: identification, synthesis and field bioassay of a new compound isolated from Dendroctonus. Nature 2211:477-478
  10. Ko, Y. K., H. S. Chang, J. W. Ryu, J. C. Woo, D. W. Koo, J-S, Kim and D-W. Kim(1998) Synthesis and herbicidal activity of new benzenesulfonylurea derivatives possessing $\alpha$-diketone or $\alpha$-keto ester moiety. The Korean Journal of Pesticide Science 3:147-150
  11. Ko, Y. K., H. S. Chang, J. W. Ryu, J. C. Woo, D. W. Koo, I. T. Hwang and D-W. Kim (2001) New benzenesulfonylurea derivatives possessing $\beta$-hydroxyalkyl subgroup : Synthesis and herbicidal activity. The Korean Journal of Pesticide Science 5:58-61
  12. Ko, Y. K., D. W. Koo, H. S. Chang, J. W. Ryu, J. C. Woo, I. T. Hwang, K. S. Hong, J-S. Kim, K. Y. Cho and D-W. Kim (1999) Synthesis and herbicidal activity of new benzenesulfonylureas. Pesticide Science 55:576-577 https://doi.org/10.1002/(SICI)1096-9063(199905)55:5<576::AID-PS953>3.0.CO;2-T
  13. Silverstein, R. M., R. G. Brownlee, T. E. Bellas, D. L. Wood and L. E. Browne (1968) Brevicomin. Principal sex attractant in the frass of the female western pine beetle. Science 159:889-891 https://doi.org/10.1126/science.159.3817.889