Characteristics of Atmospheric Concentrations of Toxic Volatile Organic Compounds in Korea (II) - Seasonal and Locational Variations

국내 대기 중 독성 휘발성 유기화합물의 오염 특성(II) -계절 및 지역적 변동

  • 백성옥 (영남대학교 토목도시환경공학부 대기환경연구실) ;
  • 김배갑 (영남대학교 토목도시환경공학부 대기환경연구실) ;
  • 박상곤 (혜천대학 환경관리과)
  • Published : 2002.09.01

Abstract

This study was designed to investigate the characteristics of atmospheric concentrations of toxic volatile organic compounds (VOCs) in Korea. Target compounds included 1,3-butadiene, aromatics such as BTEX, and a number of carbonyl compounds. In this paper, as the second part of the study, the seasonal and locational concentrations of atmospheric VOCs were evaluated. Sampling was conducted seasonally at seven sampling sites. each of them representing a large urban area (commercial and residential), a small urban area (commercial and residential), an industrial area (a site within the complex and a residential), and a background place in Korea. In general, higher concentrations were found in the petro-chemical industrial site than other sites, while VOCs measured in commercial (heavy -traffic) sites were higher than residential sites. Seasonality of VOCs concentrations were not so much clear as other combustion related pollutants such as sulfur dioxide, indicating that the VOCs are emitted from a variety of sources, not only vehicle exhaust and point sources but fugitive emissions. Except the industrial site, the concentrations of VOCs measured in this study do not reveal any serious pollution status, since the levels did not exceed any existing ambient standards in the U.K. and/or Japan. However, the increasing number of petrol -powered vehicles and the rapid industrialization in Korea may result in the increased levels of VOCs concentrations in many large urban areas in the near future, if there is no appropriate programme implemented for the control of these compounds.

Keywords

References

  1. 김용표, 나광삼, 문걸주. 울산공단지역의 휘발성 유기화합 물 농도 : 1998 년 6월 측정 결과,한국대기환경학회 1999년도 춘계학술대회 논문집, 1999; 48-49
  2. 나광삼, 김용표, 문길주, 서울 대기에서 방향족 탄화수소의 계절적 농도특성, 한국대기환경학회 1999년도 춘계학술대회 논문집. 1999;214-215
  3. 나광삼,김용표, 김영성. 서울 대기 중에서 $C_{2}$-$C_{9}$휘발성 유기화합물의 농도, 한국대기보전학회지.1998; 14(2):95-105
  4. 나광삼, 김용표 진현철, 문걸주. 울산 대기 중 입자상, 기체상물질의 수용성 이온성분과 휘발성유기화함물의 농도, 한국대기보전학회지.1998; 14(4): 281-292
  5. 백성옥, 김미현, 김배갑, 박상곤. 국내 대기 중 독성 휘발성 유기화합물의 오염 특성 (I) - 측정방법론 평가, 한국환경독성학회지 .2002; 17(2): 95-107
  6. 송희봉, 민경섭, 홍성희 김종우. 대구지역 공중이용시설의 실내 . 외 공기 중 기준성오염물질과 영향인자, 대한환경공학회지. 1996; 18(9): 1027-1044
  7. 이용근, 정태우. 액체크로마토그래프법에 의한 대기시료중 미량 알데히드류의 정량, 한국대기보전학회지. 1995; 11 (4) : 339-349
  8. 홍민선, 김순태, 허귀석. 여름철 휘발성 유기물질 배경농도 측정, 한국대기환경학회 1999년도 추계학술대회 논문집. 1999; 87-88
  9. 황윤정, 박상곤, 백성옥. DNPH 카트리지와 HPLC를 이용한 대기 중 carbonyl 화합물의 농도 측정. 한국대기보전학회지. 1996; 12(2): 199-209
  10. 日本大氣環境學會. 最近の 大氣環境行政に 關する 資料. 日本大氣環境學誌. 特輯號. 1997; 32 (4) : 1778
  11. Duffy BL and Nelson PF. Exposure to emission of I, 3butadiene and benzene in the cabins of moving motor vehicles and buses in Sydney, Australia. Atmos. Environ. 1997; 31 (23): 3877-3885 https://doi.org/10.1016/S1352-2310(97)00255-0
  12. Evans GF, Lumpkin TA, Smith DL and Somerville MC. Measurements of VOCs from the TAMS network. JAWMA, 1992;42: 1319-1323
  13. Patrick DR. Toxic Air Pollution Handbook. Van Norstrand Reinhold, New York. 1994; 287
  14. Singh HB, Salas L, Viezee W, Sitton B and Ferek R. Measurement of volatile organic chemicals at selected sites in California, Atmos. Environ. 1996; 26A : 2929-2946
  15. UK DOE. Expert Panel on air quality standards: Benzene, London, HMSO, 1994; 20
  16. UK DOE. Expert Panel on air quality standards: 1,3-Butadiene, London, HMSO, 1994; 24
  17. USEPA. Definition and procedure for the determination of the method detection limit, Code of Federal Leung PL and Harrison RM Roadside and in vehicle concentration of monoaromatic hydrocarbons. Atmos. Environ. 1999; 33: 191-204. Regulations, Part 136, Appendix B, 1990; 537 https://doi.org/10.1016/S1352-2310(98)00147-2
  18. USEPA. Compendium method TO-17: Determination of volatile organic compounds in ambient air using active sampling onto sorbent tubes (2nd ed.), 1997; EPAI 625/R -96/0l0b
  19. WHO. Guidelines for Air Quality, WHO, Geneva, 2000; 190
  20. Zhang J, He Q and Lioy PJ. Characteristics of aldehydes: concentrations, sources, and exposure for indoor and outdoor residential microenvironments. Environ. Sci. Technol. 1994; 28: 146-152 https://doi.org/10.1021/es00050a020