Journal of the Korean Society of Tobacco Science (한국연초학회지)

The Korean Society of Tobacco Science (한국연초학회)
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Enzymatic Synthesis of Maltol-$\alpha$-Glucoside and Ethyl Maltol-$\alpha$-Glucoside

Maltol-$\alpha$-Glucoside 및 Ethyl Maltol-$\alpha$-Glucoside의 효소적 합성

  • Published : 2002.12.01
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Abstract

Cyclodextrin glucanotransferase from Bacillus stearothemophilus and Bacillus macerans synthesized maltol and ethyl maltol monoglucoside, with a series of its maltooligo-glucosides by transglycosylation with dextrin as a donor, and maltol or ethyl maltol as an acceptor. The monoglucoside formed from reaction mixture of maltol or ethyl maltol by the successive actions of Bacillus stearothemophilus cyclodextrin glucanotransferase and Rhizopus glucoamylase was isolated by Diaion HP-20 column and silica gel column chromatography. The structure of the isolated monoglucoside was identified as maltol-$\alpha$-D-glucoside and ethyl maltol-$\alpha$-D-glucoside, respectively, by FAB-MS, UV, $^1$H-NMR, $^{13}$ C-NMR spectra and products by hydrolysis with acid, $\alpha$ - and $\beta$ -glucosidases.

Keywords

References

  1. J. Jpn. Oil Chem. Soc. (Yukagaku) v.44 Sythesis of sugar and glycerophospholipid derivatives of sulfurol and maltol Baba,N.;N.Maeda;A.Ito;Y.Kishida;S.Nakajima;J.Iwasa;H.Miyawaki
  2. U.S. Patent 4,804,002 Tobacco product containing side stream smoke flavorant Herron,B.N.C.
  3. Koryo v.102 Flavors of maltol and its related compounds Ito,Y.
  4. J. Agric. Food Chem. v.44 On the role of 2,3-dihydro-3,5-dihydroxy-6-methyl-4(H)-pyran-4-one in the Maillard reaction Kim,M.O.;W.Baltes
  5. Biosci. Biotech. Biochem. v.65 Transglycosylation to ginseng saponins by cyclodextrin glucanotransferases Kim,Y.H.;Y.G.Lee;G.J.Choi;K.Uchida;Y.Suzuki
  6. Denpun Kagaku v.37 Synthesis of oligosaccharides using microbial enzymes Kitahata,S.
  7. Food Technol. no.April Maltol and ethyl maltol. From the larch tree to successful food additive Leblanc,D.T.;H.A.Akers
  8. Nippon Nogeigakaku Kaishi v.75 Formation of stable ascorbate derivative by α-glucosidase-catalyzed transglucosylation Muto, N.
  9. Denpun Kagaku v.38 Application of cyclodextrin glucanotransferase Okada,S.;S.Kitahata;M.Shiosaka;H.Bunya;M.Kubota;S.Sakai;Y.Tsujisaka
  10. Agric. Biol. Chem. v.55 Enzymatic formation of 4^G-α-D-glucopyranosyl-rutin Suzuki,Y.;K.Suzuki
  11. J. Agric. Food Chem. v.42 Stereochemical control of maltol formation in Maillard reaction Yaylayan,V.A.;S.Mandeville
  12. Kagaku to Seibutsu v.29 A stable form of ascorbate, 2-O-α-glucopyeanosyl-L-ascorbic acid Yamamoto,I.
  13. 日本特開平 4-300889 モノテルルペン配糖休 藤田智之;中山允
  14. 日本特願平 4-57192 たばこ香喫味改良劑 二官正紀;鈴木博司;蓚崎靖宏;松崎敏明
  15. 科學と工業 v.65 生理活性物質の配糖化とその有用性 鈴木辛雄;內田絅