유동층연소로에서 탈황효율 실험 및 예측에 관한 연구

A Study on the Experiments and Prediction of Desulfurization Efficiency in Fluidized Bed Combustor

  • 발행 : 2002.12.01

초록

We have studied that the prediction of desulfurization efficiency by limestone in fluidized-bed coal combustor. The results were presented as follows : Firstly, the bed temperature had a great deal of effect on the desulfurization and the optimum temperature of limestone was 85$0^{\circ}C$~90$0^{\circ}C$. Secondly, as the velocity and temperature increased, $K_{s}$, K and the desulfurization efficiency increased. So, $k_{s}$, $k_{d}$ highly depended on the air velocity and bed temperature, and $k_{s}$, $k_{d}$ were 82.53 mm/sec, 0.0041/sec at 0.2 m/sec, 85$0^{\circ}C$, $k_{s}$, $k_{d}$ were 125.62 mm/sec. 0.00532/sec at 0.3 m/sec, 80$0^{\circ}C$ respectively. And $k_{s}$, $k_{d}$ were 143.78 mm/sec, 0.00568/sec at 0.3 m/sec, 85$0^{\circ}C$. Thirdly, as a result of desulfurization modeling, there was good agreement between theory and experiments as anthracite fraction increased. At 3.0 of optimum Ca/S molar ratio, there was very good agreement between theory and experiments.riments.riments.s.

키워드

참고문헌

  1. 張正國,2段 旅回流 流動層 燃燒爐의 燃燒特性 및 大氣汚染物筫 制御에 關한 硏究. PhD Thesis, 부산수산대학교,환경공학과,1995. 2
  2. 장현태, 유동층연소로에서 유, 무연탄 혼합연소 및 연소가스 배출특성. PhD Thesis, 고려대학교 화학공학과, 1995. 12
  3. David C. Lee, Fames L. Hodges and Christos Georgakis : Modelling $SO_{2}$ emission from fluidized bed coal combustors. Chemical Engineering Science 35, 302-306, 1980 https://doi.org/10.1016/0009-2509(80)80100-X
  4. J. Zheng, F. G. Yates and P. N. Rowe : A model for desulphurization with limestone in a fluidized coal combustor. Chemical Engineering Science, 37(2), 167-174, 1982 https://doi.org/10.1016/0009-2509(82)80151-6
  5. Fee, D. C., Myles, K. M., Marroquin, G. and Liang-Shin, Fan. : An analytical model for freeboard and inbed limestone sulfation in fluidized-bed coal combustor. Chem. Eng. Sci., 39, 731, 1984 https://doi.org/10.1016/0009-2509(84)80180-3
  6. Tho-Ching Ho, Hom-Ti Lee and J. R. Hopper : Simulation of desulfurization in a fluidized-bed limestone reactor. AIChE Journal, 32(10), 1754-1759, 1986 https://doi.org/10.1002/aic.690321022
  7. D. C. Fee, W. Ira Wilson, K. M. Myles and Irving Johnson : Fluidized-bed coal combustion:In-bed sorbent sulfation model. Chemical Engineering Science. 38(11), 1917-1925, 1983 https://doi.org/10.1016/0009-2509(83)85048-9
  8. Szekely, J., Evans, J. W. and Sohn, H. Y. : Gas solid reactions, Academic Press, New York, 1976
  9. R. H. Borgwardt and K. R. Bruce: Effect of specific surface area on the reactivity of CaO with $SO_{2}$. Aiche Journal. 32(2), 1986. 2 https://doi.org/10.1002/aic.690320210
  10. Simons G. A. : Parameters limiting sulfation by CaO, AIChE J., 34, 167, 1988 https://doi.org/10.1002/aic.690340124
  11. G. A. Simons and A. R. Garman : Small pore closure and the deactivation of the limestone sulfation reaction, AIChE Journal, 32(9), 1491-1499, 1986 https://doi.org/10.1002/aic.690320910
  12. F. Garcia-Labiano and J. Adanez: Characterization of limestones with $SO_{2}$ in a fluidized bed reactor. The Canadian Journal of Chemical Engineering. 70 1992. 8