The Effect of Acrylic Acid Graft on the Hemoglobin Removal Rate of Nylon Fabric(II) - Detergency Mechanism of Grafted Nylon Fabric-

아크릴산을 그라프트 중합한 나일론 직물의 혈액 단백질 호구 세척성에 관한 연구(II) -그라프트 나일론 직물의 헤모글로빈 세척기구-

  • 오수민 (숙명여자대학교 의류학과) ;
  • 송화순 (숙명여자대학교 의류학과)
  • Published : 2002.10.01

Abstract

Nylon fabric was grafted to improve detergency against hemoglobin, a protein soil. With free-radical chemical initiator systems, the grafting of acrylic acid(AA) as a hydrophilic vinyl monomer was performed to change surface free energies. Ammonium persulfate(APS) was used as an initiator and acrylic acid grafted nylon was treated with NaOH solution. The properties of the nylon, such as water uptake and the hemoglobin removal rate, were investigated. The water uptake of nylon increased after grafting and alkaline treatment. Hemoglobin was easily removed from grafted nylon, while it was difficult to remove hemoglobin from ungrafted nylon. The detergency of hemoglobin for grafted nylon decreased when the graft ratio exceeded 15%. The detergency of hemoglobin increased markedly with increasing washing time and washing temperature. The removal of hemoglobin was found to fit well to a first order reaction of time. The rate constant of hemoglobin removal for 5% nylon-g-NaAA is larger than that for ungrafted nylon. It means that the detergency of hemoglobin was improved due to grafting and alkaline treatment.

Keywords

References

  1. J. Korean Fiber Soc. v.33 Physical of Properties of Nylon 6 Fabric Grafted with Acrylic Acid(I) W. S. Song
  2. Sook-Myung Journal of Science for Better Living Physical of Properties of Nylon 6 Fabric Grafted with Acrylic Acid(II) W. S. Song;I. Y. Kim;S. M. Oh
  3. J. Korean Fiber Soc. v.26 Ultravilolet Irradiation Graft Polymerization of Acrylic Acid onto Nylon 6 Film S. S. Shin;S. Y. Kim;S. K. Song
  4. Polymer International v.38 Direct Radiation Grafting of Acrylic Acid to Nylon-6 Fabric and the Behaviour of the Resulting Graft Copolymer A. M. El-Naggar;K. El-Salmawi;S. M. Ibraheim;A. H. Zaharan
  5. J. Korean Fiber Soc. v.29 Surface Modification of Nylon 6 Films by Plasma Polymerization of Acrylic Acid K. P. Lee;S. K. Song
  6. Journal of the Research Institute of Industrial Sciences(Hanyang University) v.29 Improvement of Hydrophile Property of Nylon Film by the Plasma Polymerization S. K. Song;K. P. Lee
  7. Sen-i Gakkaishi v.20 Graft Polymerization of Styrene and Vinyl Acetate onto Nylon Fabric Imbibing Catalysts I. Sakurada;Y. Sakaguchi;Y. Sakai
  8. J. Korean Fiber Soc. v.36 The Effect of Acrylic Acid Graft on the Hemoglobin Removing Rate for the Nylon Fabric S. M. Oh;W. S. Song
  9. J. Appl. Polym. Sci. v.39 Radiation-Initiated Graft Copolymerization of Individual Monomer and Comonomer onto Polyethylene and Polytetrafluoroethylene Films E. A. Hegazy;N. H. Taher;A. R. Ebraid
  10. 大阪市立大學 家政學部紀要 v.20 皆川基
  11. Sen-i Gakkaishi v.44 Interfacial Electrical Properties of Grafted Nylon 6 Fivers T. Suzawa;M. Sasaki
  12. J. Korean Fiber Soc. v.26 Ultraviolet Irradation Graft Polymerization of Acrylic Acid onto Nylon 6 Film S. C. Shin;S. Y. Kim;S. K. Song
  13. 세제와 세탁의 과학 김성련
  14. Elsevier Textile Processing and Properties T. L. Vigo
  15. Jpn. Res. Assn. Text. End-Uses v.26 Studies on Removal of Blood Protein Stains from Fabrics Y. Tokoro;M. Minagawa
  16. Ind. Eng. Chem. v.33 T. H. Vaughn;A. Vittone;L. R. Bacon
  17. Jpn. Res. Assn. Text. End-Uses v.25 Studies on Removal of Blood Protein Stains from Fabrics Y. Tokoro;T. Fujii;M. Minagawa
  18. J. Korean Soc. of Clothing and Textiles v.20 Protease(Subtilisim Carilsperg) on the Removal of Blood Protein Soil(II) J. S. Lee;S. R. Kim
  19. 蛋白質化學 2 水島三一郞;赤堀四郞