PECVD법에 의한 DLC 박막의 증착

Deposition of Diamond Like Carbon Thin Films by PECVD

  • 김상호 (한국기술교육대학교 신소재공학과) ;
  • 김동원 (경기대학교 재료공학과)
  • 발행 : 2002.04.01

초록

This study was conducted to synthesize the diamond like carbon films by plasma enhanced chemical vapor deposition (PECVD). The effects of gas composition on growth and mechanical properties of the films were investigated. A little amount of hydrogen or oxygen were added to base gas mixture of methane and argon. Methane dissociation and diamond like carbon nucleation were enhanced by installing negatively bias grid near substrate. The deposited films were indentified as hard diamond like carbon films by micro-Raman spectroscopy. The surface and fractured cross section of the films which were observed by scanning electron microscopy showed that film growth is very slow as about 0.3$\mu\textrm{m}$/hour, and relatively uniform with hydrogen addition. Vickers hardness of tungsten carbide (WC) cutting tool increased from about 1000 to 1600~1800 by deposition of DLC film, that of commercial TiN coated tool was about 1270. In cutting test of aluminum 6061 alloy, DLC coated cutting tool showed 1/3 or lower crater and flank wear than TiN coated or non-coated WC cutting tools.

키워드

참고문헌

  1. Y. Lifshitz, Diamond Relat. Mater., 8 (1999) 1659
  2. A. Gangopadhyay, Tribology Letters 5 (1998) 25 https://doi.org/10.1023/A:1019152515982
  3. M.S. Kang, W.S Lee, Y.J. Baik, K.WChae and D. S. Lim, J. of Korean Ceramic Society, 1 (2001) 34
  4. S.H. Kim, Y.S Park and J.W. Lee, J. of Korean Association of Crystal Growth, 1 (1994) 92
  5. S.H. Lee and D.C. Lee, J. of Korean Institute of Electrical and Electronic Material Engineers. 7 (1998) 552
  6. S. Amirhaghi, H.S. Reehal, R.J.K. Wood and D. W. Wheeler, Surface and Coating Technology 135 (2001) 126 https://doi.org/10.1016/S0257-8972(00)01083-5
  7. T. Sharda, D.S. Misra and D.K. Avasthi, Vacuum 11 (1996) 1259
  8. K.M. McNamara, K.K. Gleason and C.J. Robin-son.J.Vac.Sci.Technol., 10 (1992) 3143 https://doi.org/10.1116/1.577834
  9. J.H. Hyeong, H.S. Cho, S.H. Hong, Y.J. Kim, S. D. Kim and H.J. Kim, Korean J. Cryst, 1 (1995) 14
  10. N. Ali, W. Ahmed, C.A. Rego, Q.H. Fan, Dia-mond and Related Materials 9 (2000) 1464 https://doi.org/10.1016/S0925-9635(00)00266-1
  11. S.A. Catledge and Y.K. Vohra, J. Appl. Phys. 11 (1998) 6469
  12. S. Buhlmann E. Blank, R. Haubner and B. Lux, DiamondRe1at.Mater.,8 (1999) 194
  13. Y.L.Su.W.H.Kao.J.Mater.Sci., 1 (2001) 189
  14. R.F. Huang, C.Y. Chan, C.H. Lee, J. Gong, K.H. Lai, C.S. Lee, K.Y. Li, L.S. Wen, C. Sun, Diamond Relat,Mater.,9(2001) 1850