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Effect of Cooling Rate on DC Accelerated Aging Characteristics of ZPCCY-Based Varistor Ceramics

ZPCCY계 바리스터 세라믹스의 DC 가속열화 특성에 미치는 냉각속도의 영향

  • 남춘우 (동의대학교 전기공학과) ;
  • 김향숙 (동의대학교 전기공학과)
  • Published : 2002.09.01

Abstract

The microstructure, V-Ι characteristics, and stability of ZnO-P $r_{6}$ $O_{11}$ CoO-C $r_2$ $O_3$- $Y_2$ $O_3$-based varistor ceramics were investigated with cooling rate in the range of 2~8$^{\circ}C$/min. The cooling rate relatively weakly affected the microstructure, the varistor voltage, and the leakage current in the V-Ι characteristics. But the nonlinear exponent relatively strongly affected by cooling rate. The cooling rate also greatly affected the stability of V-Ιand dielectric characteristics for DC accelerated aging stress. On the whole, the varistors cooled with 4$^{\circ}C$/fin exhibited the highest performance in the densification, nonlinearity, and stability. Especially, they exhibited a high stability, in which the variation rate of the varistor voltage( $V_{1㎃}$), the nonlinear exponent($\alpha$), and the dissipation factor(tan $\delta$) is -1.4%, -4.9%, and +60.0%, respectively, under DC accelerated aging stress such as 0.95 $V_{1㎃}$15$0^{\circ}C$/12 h)

Keywords

References

  1. T. K. Gupta, 'Application of zinc oxide varistor', J. Amer. Ceram. Soc., Vol. 73, No. 7, p. 1817, 1990 https://doi.org/10.1111/j.1151-2916.1990.tb05232.x
  2. ニュ-ケラスシ-リズ 編集委員會, '半導体 セラミ クスと その應用', 學獻社, p. 149, 1990
  3. 電氣學會, '酸化亞鉛避雷器の特性と評價試驗法', 電氣學會技術報告, 第474号, 1993
  4. S.-Y. Chun, K. Shizoaki, and N, Mizutani, 'Formation of varistor characteristics by the grain-boundary penetration of ZnO PrOx liquid into ZnO ceramics', J. Amer. ceram. Soc., Vol. 82, No. 11, p. 3065, 1999 https://doi.org/10.1111/j.1151-2916.1999.tb02203.x
  5. N. Ohashi, S. Mitarai, and O. Fukunaga, 'Magnatization and electric properties of Pr-doped ZnO', J. Electroceram., Vol. 4, No. S1, p. 61, 1999 https://doi.org/10.1023/A:1009938106039
  6. S.-Y. Chun and N. Mizutani, 'Mass transport via grain boundary in Pr-based ZnO varistors and reiated electrical effects', Mater. Sci., and Engin., Vol. B79, No. 1, p. 1, 2001 https://doi.org/10.1016/S0921-5107(00)00552-3
  7. H. H. Hng and K. M. Knowles, 'Microstructure and current-voltage characteristics of praseodymium-doped zinc oxide varistors containing Mn$O_2$, $Sb_2O_3$ and $Co_3O_4$', J. Mater. Sci., Vol. 37, No. 6, p. 1143, 2002 https://doi.org/10.1023/A:1014359204034
  8. 남춘우, 윤한수, 류정선, 'ZPCCE계 바리스터의 미세구조와 전기적 성질 및 안정성', 전기전자재료학회논문지, 13권, 9호, p. 735, 2001
  9. 남춘우, 류정선, 'Zn-Pr-Co-Cr-Er 산화물계 바리스터의 전기적 성질', 전기전자재료학회 논문지, 14권, 5호, p. 362, 2001
  10. 남춘우, 정영철, 김향숙, '$Pr_6O_{11}$계 ZnO 바리스터의 전기적, 유전적 특성에 DC 가속열화 거동에 미치는 소결온도의 영향', 전기전자재료학회논문지, 15권, 3호, p. 244, 2002
  11. 남춘우, 류정선, 김향숙, 정영철, '$Pr_6O_{11}$계 ZnO 바리스터의 DC 가속열화특성', 전기전자재료학회논문지, 14권, 10호, p. 808, 2001
  12. C.-W. Nahm, "The nonlinear properties and stability of $ZnO-Pr_6O_{11}-CoO-Cr_2O_3-Er_2O_3$ ceramic varistors", Mater. Lett., Vol. 47, No. 3, p. 182. 2001 https://doi.org/10.1016/S0167-577X(00)00262-7
  13. C.-W. Nahm, H.-S. Yoon, and J.-S. Ryu, 'The nonlinear properties and d.c degradation characteristics of ZPCCE based varistors', J. Mater. Sci. Lett., Vol. 20, No. 5, p. 393, 2001 https://doi.org/10.1023/A:1010969506901
  14. C.-W. Nahm and C.-H. Park, 'Effect of $Er_2O_3$ addition on the microstructure, electrical properties, and stability of $Pr_6O_{11}$-based ZnO ceramic varistors', J. Mater. Sci., Vol. 36, No. 7, p. 1671, 2001 https://doi.org/10.1023/A:1017552020433
  15. C.-W. Nahm and J.-S. Ryu, 'Influence of sintering temperature on varistor characteristics of ZPCCE-based ceramics', Mater. Lett, Vol. 53, No. 1-2, p. 110, 2002 https://doi.org/10.1016/S0167-577X(01)00464-5
  16. J. Fan and R. Freer, 'The roles played by Ag and Al dopants in controlling the electrical properties of ZnO varistors', J. Appl. Phys., Vol. 77, No. 9, p. 4795, 1995 https://doi.org/10.1063/1.359398
  17. J. C. Wurst and J. A. Nelson, 'Lineal intercept technique for measuring grain size in two-phase polycrystalline ceramics', J. Amer. Ceram. Soc., Vol. 55, No. 97-12, p. 109, 1972 https://doi.org/10.1111/j.1151-2916.1972.tb11224.x
  18. C.-W. Nahm, C.-H. Park, and H.-S. Yoon, "Highly stable nonohmic characteristics of $ZnO-Pr_{6}O_{11}-CoO-Dy_{2}O_{3}$ based varistors", J. Mater. Sci. Lett., Vol. 19, No. 9, p. 725, 2000 https://doi.org/10.1023/A:1006739421559
  19. C.-W. Nahm, 'The electrical properties and d.c. degradation characteristics of $Dy_2O_3$ doped $Pr_6O_{11}$-Based ZnO varistors', J. Eur. Ceram. Soc., Vol. 21, No. 4, p. 545, 2001 https://doi.org/10.1016/S0955-2219(00)00233-8