DOI QR코드

DOI QR Code

Effect of a Laser Ablation on High Voltage Discharge Plasma Area for Carbon Nitride Film Deposition

고전압 방전 플라즈마에 의한 질화탄소 박막 증착 시 플라즈마 영역에 가한 레이저 애블레이션의 효과

  • 김종일 (한국기술교육대학교 정보기술공학부 BK)
  • Published : 2002.06.01

Abstract

Carbon nitride films have been deposited on Si(100) substrate by a high voltage discharge plasma combined with laser ablation in a nitrogen atmosphere. The films were grown both with the without the presence of an assisting focused Nd:YAG laser ablation. The laser ablation of the graphite target leads to vapor plume plasma expending into th ambient nitrogen arc discharge area. X-ray photoelectron spectroscopy and Auger electron spectroscopy were used to identify the binding structure and the content of the nitrogen species in the deposited films. The nitrogen content of the films was found to increase drastically with an increase of nitrogen pressure. The surface morphology of the films was studied using a scanning electron microscopy. Data of infrared spectroscopy and x-ray photoelectron spectroscopy indicate the existence of carbon-nitrogen bonds in the films. The x-ray diffraction measurements have also been taken to characterize the crystal properties of the obtained films.

Keywords

References

  1. Science v.245 Prediction of new low compressibility A.Y.Liu;M.L.Cohen https://doi.org/10.1126/science.245.4920.841
  2. Thin Solid Films v.302 Carbon nitride CNx film deposition assisted by IR laser ablation in a cold remote nitrogen plasma C.Jama;V.Rousseau;O.Dessaux;P.Goudmand https://doi.org/10.1016/S0040-6090(96)09541-7
  3. 전기전자재료학회논문지 v.15 no.2 질화탄소 박막 증착 시 고전압방전 플라즈마에 가한 자장의 영향 김종일;배선기 https://doi.org/10.4313/JKEM.2002.15.6.551
  4. Mat. Res. Soc. Symp. Proc. v.388 Growth and properties of carbon nitride thin films Z.J.Zhang;P.Yang;C.M.Lieber
  5. 전기전자재료학회논문지 v.15 no.2 반응성 스퍼터링으로 성장된 결정성 질화탄소막의 기계적 특성 이성필;강종봉 https://doi.org/10.4313/JKEM.2002.15.2.147
  6. Jpn. J. Appl. Phys. v.32 no.10A Structural properties of amorphous carbon nitride films prepared by reactive RF-magnetron sputtering N.Nakayama;Y.Tsuchiya;S.Tamada;K.Kosuge;S.Nagada;K.Takahiro;S.Yamaguchi https://doi.org/10.1143/JJAP.32.L1465
  7. Phys. Rev. Lett. v.73 no.1 Carbon nitride deposited using energetic species : A two-phase system D.Marton;K.J.Boyd;A.H.Al-Bayati;S.S.Todorov;J.W.Ravalais https://doi.org/10.1103/PhysRevLett.73.118
  8. J. Phys. Conden. Matt. v.6 Carbon nitride films synthesized by NH₃-ion-beam-assisted H.W.Song;F.Z.Cui;X.M.He;W.Z.Li;H.D.Li https://doi.org/10.1088/0953-8984/6/31/011
  9. 전기전자재료학회논문지 v.14 no.10 결정질 질화탄소 박막의 합성과 그 특성해석 김종일;배선기
  10. Chemistry and Industry Carbon Nitride Solids : Potential Alternatives to Diamond? C.M.Lieber;Z.J.Zhang
  11. Appl. Phys. Lett. v.66 no.20 Reactive pulsed laser deposition of CNx films X.A.Zhao;C.W.Ong;Y.C.Tsang;Y.W.Wong;C.L.Choy https://doi.org/10.1063/1.113114
  12. Appl. Phys. Lett. v.66 no.26 Growth and composition of covalent carbon nitride solids Z.J.Zhang;S.Fan;C.M.Lieber https://doi.org/10.1063/1.113794
  13. Thin Solid Films v.303 Si-containing crystalline carbon nitride derived from microwave plasma-enhanced chemical vapor deposition L.C.Chen;D.M.Bhusan;C.Y.Yang;K.H.Chen;T.J.Chuang;M.C.Lin;C.K.Chen;Y.F.Huang https://doi.org/10.1016/S0040-6090(97)00041-2
  14. Phys. Rev. B v.51 no.8 Carbon nitride films sythesized by combined ion-beam and laser-ablation processing Z.M.Ren;Y.C.Du;Y.Qiu;J.D.Wu;Z.F.Ying;X.X.Xiong;F.M.Li https://doi.org/10.1103/PhysRevB.51.5274
  15. Appl. Phys. A v.65 Preparation of carbon nitride film powder by laser induced gas-phase reaction R.Alexandrescu;F.Huisken;A.Crunteanu;S.Petcu;S.Cojocaru;S.Cireasa;I.Morjan https://doi.org/10.1007/s003390050568
  16. Thin Solid Films v.308/309 Preparation of carbon nitride thin films by ion beam assisted deposition and their mecanical properties M.Kohzaki;A.Matsumuro;T.Hayashi;M.Muramatsu;K.Yamaguch https://doi.org/10.1016/S0040-6090(97)00420-3
  17. J. Vac. Sci. Tech. A v.15 no.1 Synthensis of carbon nitride films at low temperature P.Hammer;M.A.Baker;C.Lenardi;W.Gissler https://doi.org/10.1116/1.580481
  18. Science in China v.41 no.4 Synthesis of C₃N₄crystals under high pressure and high temperature D.He;F.Zhang;X.Zhang;M.Zhang;R.Liu;Y.Xu;W.Wang https://doi.org/10.1007/BF02879032
  19. Science v.271 Low compressibility carbon nitride D.M.Teter;R.J.Hemley https://doi.org/10.1126/science.271.5245.53