Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Low Temperature Synthesis of BaCeO3 Nano Powders by the Citrate Process

Citrate Process를 이용한 BaCeO3 나노 분말의 저온 합성

  • Published : 2002.06.01
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Abstract

Nanosized $BaCeO_3$ powders with the stoichiometric composition of a molecular level were synthesized by the citrate process based on the Pechini method. Polymeric precursor was formed by use of citric acid and ethylen glycol, as chelating agent of metal ions and reaction medium, respectively. Single phase orthorhombic structured $BaCeO_3$powders, about 100 nm sized and uniform shaped were obtained through the calcination of the polymeric precursor at $900^{\circ}C$ for 4 h. Extremely small quantities of carbonate ions($CO_^{2-}$) were completely decomposed at over $1100^{\circ}C$. The mean size of the powders was increased twice, however, it has very uniform distribution in its size and shape.

분자 단위의 균일한 조성을 가지는 $BaCeO_3$ 나노 분말을 Pechini법에 기초한 citrate 공정을 통하여 합성하였다. 금속 이온의 chelating제로서 citric acid를, 반응 촉매로서는 ethylen glycol을 각각 사용하여 고분자 전구체를 형성시켰고, 이를 기반으로 $900^{\circ}C$의 온도에서 4시간동안 열처리하여 약 100nm의 균일한 크기와 형상을 가진, 사방정 구조의 단일상 $BaCeO_3$ 분말을 합성하는데 성공하였다. 잔존하는 미량의 $CO_3^{2-}$는 $1100^{\circ}C$ 이상의 온도에서 완전히 분해되었고, 이 때 평균 입도 는 약 2배 증가하였으나 매우 균일한 분포를 나타내었다.

Keywords

References

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