DOI QR코드

DOI QR Code

Ionic Conductivity of Solid Solution Ceramics in The System of Stabilized ZrO2 Prepared by Self-Propagating High-Temperature Synthesis

  • Soh, Deawha (School of Electronics, Information& Communication Engineering, Myongji University) ;
  • Korobova, N. (Combustion Problems Institute, Kazakstan)
  • Published : 2002.04.01

Abstract

The ionic conductivity of cubic solid solutions in the systems of CaO-$ZrO_2$, $Y_2O_3-ZrO_2$ prepared by SHS was examined. The higher conductivity appears to be related to a lower activation energy rather than to the number of oxygen vacancies dictated by composition. Conductivity-temperature data was obtained at 1000 $^{\circ}C$ in atmosphere of low oxygen partial pressure (~$10^{-40}$ atm) for $Y_2O_3-ZrO_2$ cubic solid solutions. The data indicated that these materials could be reduced, and the decree of reduction would be related with the measuring electric field.

Keywords

References

  1. Electronic Ceramics I. Levinson;M. Lionel
  2. Progress in Energy and Combustion Science v.27 Fundamental aspects of the heterogeneous flame in the self-propagating high-temperature synthesis (SHS) process A. Makino https://doi.org/10.1016/S0360-1285(00)00004-6
  3. Proc. 2001 Autumn. Conf. KIEEME v.14 no.1 The rapid synthesis of MoSi₂ for high-temperature furnace heating elements D. Soh;N. Korobova
  4. Proc. 2001 Summer Conf. KIEEME v.2 no.2 Electronic conductivity of LaCrO₃ceramics prepared by SHS D. Soh;N. Korobova
  5. J. Mater. Sci. v.17 Effect of impurities on sintering and conductivity of yttria-stabilized zirconia M.J. Verkerk;A.J.A. Winnubst;A.J. Burggraaf https://doi.org/10.1007/BF01203473
  6. Proc. International Symposium on Performance of Ceramics under Extreme Conditions Zirconium oxide construction ceramics at the hydrocarbon pyrolysis N. Korobova;Y. Antipov;M. Korulkin
  7. Proc. 2001 Summer Conf. of KIEEME v.2 no.1 Ionic conduction in the stabilized ZrO₂base solid solut ions prepared by SHS Deawha Soh;N. Korobova
  8. J. Electrochem. Soc. v.98 no.9 Zirconia-yttria system P. Duwez;F.H. Brown;F. Odell https://doi.org/10.1149/1.2778219