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Thermodynamic Conditions for Formation of Single Phase in BSCCO Thin Films

BSCCO 박막에서 단일상 형성을 위한 열역학 조건

  • 이동규 (광운대학교 대학원 전기공학과) ;
  • 박용필 (동신대학교 전기전자공학부)
  • Published : 2002.02.01

Abstract

High quality BSCCO thin films have been fabricated by means of an ion beam sputtering at various substrate temperatures, T$\sub$sub/, and ozone gas pressures, pO$_3$. The correlation diagrams of the BSCCOphases with T$\sub$sub/ and pO$_3$ are established in the 2212 and 2223 phases come out as stable phases depending on T$\sub$sub/ and pO$_3$. From these results, the thermodynamic evaluation of ΔH and ΔS, which are related with Gibbs\` free energy change for single Bi2212 or Bi2223 phase, were performed.

Keywords

References

  1. J. of KIEEME v.10 no.5 Characteristics of co-deposition for Bi-superconductor thin film using ion beam spttering method Y.P. Park;J.U. Lee
  2. J. of KIEEME v.13 no.1 Evaluation of sticking coefficient in BSCCO thin film fabricated by co-sputtering Y.P. Park;H.K. Lee;K.W. Lee;J.U. Lee
  3. J. of KIEEME v.13 no.9 Comparison between Bi-superconducting thin films fabricated by co-deposition and layer-by-layer deposition Y.P. Par;S.H. Yang
  4. J. Chem. Phys v.10 X-Ray inter-ference in partially ordered layer lattices S. Hendricks;E. Teller https://doi.org/10.1063/1.1723678
  5. Physica C v.211 Standard enthalpies of formation of member oxides in the Bi-Sr-Ca-Cu-O sys-tem Y. Idemoto;K. Shizuka;Y. Yasuda;K.Fueki https://doi.org/10.1016/0921-4534(93)90726-7
  6. Physica C v.224 Atomic redistribution and mass transport in the formation of Bi1.80Pb0.43-Sr1.71Ca2.14Cu₃O10-x M.G. Smith;D.S. Phillips;D.E. Peterson;J.O. Willis https://doi.org/10.1016/0921-4534(94)90618-1
  7. Physica C v.196 Thermodynamic study of the effects of Pb-addition on the formation of the 2223 phase in the Bi-Based superconductor system S.H. Kim;Y.Y. Kim;S.H. Lee;K.H. Kim https://doi.org/10.1016/0921-4534(92)90133-W
  8. Physica C v.229 Molecular beam epitaxial growth of superconducting Pb₂Sr₂Dy₁-xCaxCu8O8-δ thin films S. Ikegawa;Y. Motoi;T. Miura https://doi.org/10.1016/0921-4534(94)90508-8
  9. Physica C v.217 Phase stability limits and solidstate decomposition of Bi₂Sr₂CaCu₂O8+δ and Bi₂Sr₂CaCu₃O10+δ thin films L.M. Rubin;T.P. Orando;J.B. Vander Sande https://doi.org/10.1016/0921-4534(93)90817-A
  10. American Chemical Society and American Institute of Physics JANAF Thermochemical Tables(3rd ed.)
  11. J. Crystal Growth v.102 Molecular beam epitaxial growth of layered Bi-Sr-Ca-Cu-O compound D.G. Schlom;A.F. Marchall;J.T. Sizemore;Z.J.Eckstein;I. Bozovic;K.E. von Dessonneck https://doi.org/10.1016/0022-0248(90)90393-Y
  12. Physica C v.249 Oxygen stoichiometry, phase stabillity, and thermodynamic behavior of the lead-doped Bi-2223 and Ag/Bi-2223 systems M. Tatenbaum;M. Hash;B.S. Tani;J.S. Luo;V.A. Maroni https://doi.org/10.1016/0921-4534(95)00299-5