Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Chelating Resin Containing 2-(2-Thiazolylazo)-5-dimethylaminophenol as the Functional Group: Synthesis and Sorption Behavior for Some Trace Metal Ions

  • Published : 2002.08.20
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Abstract

A new polystyrene-divinylbenzene resin containing 2-(2-thiazolylazo)-5-dimethylamino-phenol (TAM) functional groups has been synthesized and its sorption behavior for nineteen metal ions, including Zr(Ⅳ),Hf(Ⅳ) and U(Ⅵ) has been investigated by batch and column methods. The chelating resin showed high sorption affinity for Zr(Ⅳ) at pH 1-5 and U(Ⅵ) at pH 4. Some parameters affecting the sorption of the metal ions have been detailed. The breakthrough and overall capacities were measured under optimized conditions. The overall capacities of Zr(Ⅳ), Th(Ⅳ) and U(Ⅵ), which showed higher than the other metal ions, were 0.90,0.84 and 0.80 mmol/g, respectively. The elution order of metal ions at pH 4 was evaluated as Zr(Ⅳ) > Th(Ⅳ) > U(Ⅵ) > Cu(Ⅱ) > Hf(Ⅳ) > W(Ⅵ) > Mo(Ⅵ) > In(Ⅲ) > Sn(Ⅳ) > Cr(Ⅲ) > V(Ⅴ) > Fe(Ⅲ). Quantitative recovery of most metal ions except Zr(Ⅳ) was achieved using 2M HNO3. Desorption and recovery of Zr(Ⅳ) was successfully performed with 2 M HClO4 and 2 M HCl.

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References

  1. Schmuckler, D. Talanta 1963, 10, 745. https://doi.org/10.1016/0039-9140(63)80103-4
  2. Degetto, S.; Faguin, M.; Moresco, A.; Baracco, L. Bull. Chem.Soc. Jpn. 1983, 56, 904. https://doi.org/10.1246/bcsj.56.904
  3. de Moraes, S.; Abrao, A. Anal. Chem. 1974, 46, 1812. https://doi.org/10.1021/ac60348a028
  4. Lee, C. H.; Suh, M. Y.; Joe, K. S.; Eom, T. Y.; Lee, W. Anal. Chim.Acta 1997, 351, 57. https://doi.org/10.1016/S0003-2670(97)00342-5
  5. Chwastowska, J.; Mozer, M. Talanta 1985, 32, 7. https://doi.org/10.1016/0039-9140(85)80004-7
  6. Carlberg, G. E.; Boren, H.; Grimvall, A.; Lundgren, B. V. J. ofChromatography 1987, 391, 169. https://doi.org/10.1016/S0021-9673(01)94314-6
  7. Lee, C. H.; Kim, J. S.; Suh, M. Y.; Lee, W. Anal. Chim. Acta 1997,339, 303. https://doi.org/10.1016/S0003-2670(96)00461-8
  8. Lee, W.; Lee, S. E.; Lee, C. H.; Kim, Y. S.; Lee, Y. I. Microchem.J. 2001, 35, 195.
  9. Salters, V. J. M. Anal. Chem. 1994, 66, 4186. https://doi.org/10.1021/ac00095a012
  10. Yang, X. J.; Pin, C. Anal. Chem. 1999, 71, 1706. https://doi.org/10.1021/ac980833w
  11. Chang, R. C.; Fritz, J. S. Talanta 1978, 25, 659. https://doi.org/10.1016/0039-9140(78)80167-2
  12. Saxena, R.; Singh, A. K.; Sambi, S. S. Anal. Chim. Acta 1994,295, 199. https://doi.org/10.1016/0003-2670(94)80351-X
  13. Wada, H.; Nakagawa, G. Anal. Lett. 1968, 1, 687.
  14. Eshwar, M. C.; Sharma, C. D. Microchem. J. 1987, 35, 27. https://doi.org/10.1016/0026-265X(87)90196-2
  15. Ying, L. L.; De, G. M.; Qiu, Z. Y. Talanta 1995, 42, 1. https://doi.org/10.1016/0039-9140(95)90013-6
  16. Irving, H.; Williams, R. Nature 1948, 162, 746. https://doi.org/10.1038/162746a0
  17. Anderson, R. G.; Nickless, G. Analyst 1967, 92, 1093.
  18. Rawat, J. P.; Thind, P. S. J. Phys. Chem. 1976, 80, 1384. https://doi.org/10.1021/j100553a026
  19. Nachod, F. C.; Wood, W. J. Am. Chem. Soc. 1944, 66, 1380. https://doi.org/10.1021/ja01236a050
  20. Nachod, F. C.; Wood, W. J. Am. Chem. Soc. 1945, 67, 629. https://doi.org/10.1021/ja01220a036
  21. Turse, R.; Rieman, W. J. Phys. Chem. 1961, 65, 1821. https://doi.org/10.1021/j100827a031
  22. Boyd, G. E.; Adamson, A. W.; Myers, L. S. J. Am. Chem. Soc.1947, 69, 2836. https://doi.org/10.1021/ja01203a066
  23. Reichenberg, D. J. Am. Chem. Soc. 1953, 75, 589. https://doi.org/10.1021/ja01099a022
  24. Svodova, L.; Jandera, P.; Churacek, J. Collet. Czech. Chem.Commun. 1991, 56, 317. https://doi.org/10.1135/cccc19910317

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