Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Tin-Free Three-Component Coupling Reaction of Aryl Halides, Norbornadiene (or Norbornene), and Alkynols Using a Palladium Catalyst

  • Choi, Cheol-Kyu (Institute of Photonics and Surface Treatment, Q-sys Co.) ;
  • Hong, Jin-Who (Department of Polymer Science and Engineering, Chosun University) ;
  • Tomita, Ikuyoshi (Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology) ;
  • Endo, Takeshi (Department of Polymer Science and Engineering Faculty of Engineering Yamagata University)
  • Published : 2002.01.20
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Abstract

Good-to-excellent yields of 2,3-Disubstituted norbornenes (or norbornanes) were obtained using a Pd/Cu catalyzed three-component ternary coupling reaction of aryl halides, norbornadiene (or norbornene), and alkynols in toluene at $100{\circ}C$ in the presence of 5.5 M NaOH as a base and benzyltriethylammonium chloride as a phase transfer catalyst. The results of experiments using various aromatic halides suggest that the ternary coupling reaction is promoted by bromide.

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