Bulletin of the Korean Chemical Society

  • 제23권5호
  • /
  • Pages.683-687
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  • 2002
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Preparation of UV Curable Gel Polymer Electrolytes and Their Electrochemical Properties

  • 발행 : 2002.05.20
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초록

We have investigated the effect of the number of ethylene oxide (EO) units inside poly(ethylene glycol)dimethacrylate (PEGDMA) on the ionic conductivity of its gelled polymer electrolyte, whose content ranges from 50 to 80 wt%. PEGDMA gelled polym er electrolytes, a crosslinked structure, were prepared using simple photo-induced radical polymerization by ultraviolet light. The effect of the number of EO on the ionic conductivity was clearly shown in samples of lower liquid electrolyte content. We have concluded that the ionic conductivity increased in proportion to both the number of EO units and the plasticizer content. We have also studied the electrochemical properties of 13PEGDMA (number of EO units is 13) gelled polymer electrolyte.

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참고문헌

  1. Armand, M. Solid State Ionics 1994, 69, 309. https://doi.org/10.1016/0167-2738(94)90419-7
  2. Huguenin, F.; Cavalcante, M. G.; Torresi, R. M. Solid State Ionics1999, 126, 259. https://doi.org/10.1016/S0167-2738(99)00241-6
  3. Wright, P. V. Br. Polym. J. 1975, 7, 319. https://doi.org/10.1002/pi.4980070505
  4. Gray, F. M. Polymer Electrolytes; The Royal Society of Chemistry: Cambridge, 1997; Chapter 1.
  5. Berthier, C.; Gorecki, W.; Minier, M.; Armand, M.; Chabagno, J.M.; Rigaud, P. Solid State Ionics 1983, 11, 91. https://doi.org/10.1016/0167-2738(83)90068-1
  6. Wolfenson, A. E.; Torresi, R. M.; Bonagamba, T. J.; DePaoli, M.A.; Panepucci, H. Solid State Ionics 1996, 85, 219. https://doi.org/10.1016/0167-2738(96)00062-8
  7. Frech, R.; Manning, J.; Teeters, D.; Black, B. E. Solid State Ionics1988, 28-30, 954. https://doi.org/10.1016/0167-2738(88)90310-4
  8. Wilson, D. J.; Nicholas, C. V.; Mobbs, R. H.; Booth, C. Br. Polym.J. 1990, 22, 129. https://doi.org/10.1002/pi.4980220206
  9. Itoh, T.; Hirata, N.; Moriya, Y.; Kubo, M.; Yamamoto, O. J.Power Sources 1999, 81-82, 824. https://doi.org/10.1016/S0378-7753(98)00235-3
  10. Wang, Z.; Ikeda, M.; Hirata, N.; Kubo, M.; Itoh, T.; Yamamoto, O.J. Electrochem. Soc. 1999, 146(6), 2209.
  11. Best, A. S.; Ferry, A.; MacFarlane, D. R.; Forsyth, M. Solid StateIonics 1999, 126, 269. https://doi.org/10.1016/S0167-2738(99)00239-8
  12. Sun, H. Y.; Sohn, H.-J.; Yamamoto, O.; Takeda, Y.; Imanishi, N. J.Electrochem. Soc. 1999, 146(5), 1672. https://doi.org/10.1149/1.1391824
  13. Croce, F.; Appetecchi, G. B.; Persi, L.; Scrosati, B. Nature 1988,394, 456.
  14. Croce, F.; Brown, S. D.; Greenbaum, S. G.; Slane, S. M.;Salomon, M. Chem. Mater. 1993, 5, 1268. https://doi.org/10.1021/cm00033a014
  15. Kim, J. Y.; Kim, S. H. Solid State Ionics 1999, 124, 91. https://doi.org/10.1016/S0167-2738(99)00104-6
  16. Huq, R.; Koksbang, R.; Tonder, P. E.; Farrington, G. C. ElectrochimicaActa 1992, 37(9), 1681. https://doi.org/10.1016/0013-4686(92)80137-B
  17. Sander, B.; Steurich, T.; Wiesner, K.; Bischoff, H. Polym. Bulletin1992, 28, 355. https://doi.org/10.1007/BF00294835
  18. Sun, X. G.; Lin, Y. Q.; Ding, L. M.; Jing, X. B. ElectrochimicaActa 1996, 41(9), 1573. https://doi.org/10.1016/0013-4686(95)00397-5
  19. Appetecchi, G. B.; Dautzenberg, G.; Scrosati, B. J. Electrochem.Soc. 1996, 143(1), 6. https://doi.org/10.1149/1.1836379
  20. Abbrent, S.; Lindgren J.; Tegenfeldt J.; Wendsjo A. ElectrochimicaActa 1998, 43(10-11), 1185. https://doi.org/10.1016/S0013-4686(97)10018-4
  21. Sander, B.; Weinkauf, A.; Reiche, A.; Siury, K.; Tubke, J.;Wartewig, S.; Shashkov, S. Electrochimica Acta 1998, 43(10-11),1263. https://doi.org/10.1016/S0013-4686(97)10028-7
  22. Reiche, A.; Sander, R.; Weinkauf, A.; Sander, B.; Fleischer, G.;Rittig, F. Polymer 2000, 41, 3821 https://doi.org/10.1016/S0032-3861(99)00555-8
  23. Lee, K.; Kim, K.; Lim, H. S. J. Electrochem. Soc. 2001, 148(10),A1148. https://doi.org/10.1149/1.1402979
  24. Watanabe, M.; Itoh, M.; Sanui, K.; Ogata, N. Macromolecules1987, 20, 569. https://doi.org/10.1021/ma00169a017
  25. Oh, B.; Kim, Y. R. Solid State Ionics 1999, 124, 83. https://doi.org/10.1016/S0167-2738(99)00129-0
  26. Kim, D. W.; Kim, Y. R.; Sun, Y. K.; Oh, B.; Moon, S. I.; Jin, B. S.Polymer(Korea) 1997, 21(5), 861.
  27. Lithium ion secondary battery (Japanese Ed.) Materials & Application; THE NIKKAN KOGYO SHIMBUN: Japan, 1996; p. 86.
  28. Sung, H.-Y.; Wang, Y.-Y.; Wan, C.-C. J. Electrochem. Soc. 1998,145(4), 1207. https://doi.org/10.1149/1.1838440

피인용 문헌

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  3. Development of gel-polymer electrolytes and nano-structured electrodes for Li-ion polymer batteries vol.38, pp.7, 2008, https://doi.org/10.1007/s10800-008-9511-9
  4. Evaluation of macromonomer-based gel polymer electrolyte for high-power applications vol.175, pp.1, 2002, https://doi.org/10.1016/j.ssi.2003.11.040
  5. Improved lithium ion dynamics in crosslinked PMMA gel polymer electrolyte vol.9, pp.47, 2002, https://doi.org/10.1039/c9ra05917b
  6. Influence of chain length of prepolymers in permanent memory effect of PDLC assessed by solid-state NMR vol.47, pp.4, 2002, https://doi.org/10.1080/02678292.2019.1662105
  7. Rational Design of Ion Transport Paths at the Interface of Metal-Organic Framework Modified Solid Electrolyte vol.12, pp.20, 2020, https://doi.org/10.1021/acsami.0c04387
  8. UV-Cured Poly(Siloxane-Urethane)-Based Polymer Composite Materials for Lithium Ion Batteries—The Effect of Modification with Ionic Liquids vol.13, pp.21, 2002, https://doi.org/10.3390/ma13214978